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1.
Characterization of the non-stoichiometric and isomorphic hydration and solvation in FK041 clathrate
Hisashi Mimura Satoshi Kitamura Teruyuki Kitagawa Shigetaka Kohda 《Colloids and surfaces. B, Biointerfaces》2002,26(4):397-406
FK041 crystallizes as a non-stoichiometric hydrate or as solvated hydrates which were characterized as isomorphic clathrates by powder X-ray diffractometry. Moisture and organic solvent vapor sorption studies, differential scanning calorimetry and thermogravimetric analysis revealed that FK041 monohydrate forms a physically stable host crystal, which has lattice channels for guest water and/or organic solvent molecules. The hydration state varies non-stoichiometrically between dihydrate and tetrahydrate depending on the relative humidity and the mol content of the co-existing organic solvent, that is 2-propanol, ethanol, or acetone. These organic solvents are thought to replace a part of originally present water with a mol ratio of 1:3. 2-Propanol exhibited the most stable solvation, indicating that the size and shape of 2-propanol are the most preferable to the lattice channels. 相似文献
2.
Balakin V Alexandrov VA Mikhailichenko A Flöttmann K Peters F Voss G Bharadwaj V Halling M Holt JA Buon J Jeanjean J LeDiberder F Lepeltier V Puzo P Heimlinger G Settles R Stierlin U Hayano H Ishihara N Nakayama H Oide K Shintake T Takeuchi Y Yamamoto N Bulos F Burke D Field R Hartman S Helm R Irwin J Iverson R Rokni S Roy G Spence W Tenenbaum P Wagner SR Walz D Williams S 《Physical review letters》1995,74(13):2479-2482
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4.
Akiba Y Beavis D Beery P Britt HC Budick B Chasman C Chen Z Chi CY Chu YY Cianciolo V Cole BA Costales JB Crawford HJ Cumming JB Debbe R Engelage J Fung SY Gonin M Gushue S Hamagaki H Hansen O Hayano RS Hayashi S Homma S Kaneko H Kang J Kaufman S Kehoe WL Kurita K Ledoux RJ Levine MJ Miake Y Morrison DP Morse RJ Moskowitz B Nagamiya S Namboodiri MN Nayak TK Olness J Parsons CG Remsberg LP Roehrich D Rothschild P Sakurai H Sangster TC Seto R Soltz R Stankus P Steadman SG Stephans GS Sung T 《Physical review letters》1996,76(12):2021-2024
5.
Yoshio Iwakura Fusakazu Hayano 《Journal of polymer science. Part A, Polymer chemistry》1969,7(2):597-607
Polyimides having pendant hydroxy groups were prepared by addition of pyromellitimide with bisepoxides. Tertiary amines and quaternary ammonium halides were effective as a catalyst. The polyimides were soluble in dichloroacetic acid and had inherent viscosities in the range 0.16–0.19 dl/g. Thermogravimetric analysis showed that a rapid weight loss of the polymers occurred at about 400°C. The pendant hydroxy groups were easily acetylated by treating the polymers with a mixture of acetic anhydride and pyridine. The acetylated polyimides were soluble in dimethylformamide, dimethylacetamide, and dioxane and melted at 120–150°C. 相似文献
6.
Masao Hirano Shigetaka Yakabe James H. Clark Hiroyuki Kudo Takashi Morimoto 《合成通讯》2013,43(10):1875-1886
A wide variety of sulphides can be readily converted to the corresponding sulphoxides in good to excellent yields by treatment with a combination of sodium chlorite, (salen)manganese(III) complex, and chromatographic alumina in dichloromethane under mild and neutral conditions. 相似文献
7.
Sako M Kihara T Tanisaki M Maki Y Miyamae A Azuma T Kohda S Masugi T 《The Journal of organic chemistry》2002,67(3):668-673
The UV irradiation of pyrrolnitrin (1a), which is an antibiotic clinically useful against dermatophytosis and possesses a unique 2-(pyrrol-3-yl)nitrobenzene moiety in the molecule, in an anhydrous aprotic solvent resulted in the exclusive formation of transient 7,4'-dichlorospiro[1,3-dihydrobenzo(c)isoxazole-3,3'-pyrrolin-2'-one] (2a) via the intramolecular oxidation of the juxtaposed pyrrole ring by the triplet-excited nitro group. The irradiation in an aqueous aprotic solvent, however, allowed the concurrent occurrence of intramolecular cyclization by the singlet-excited nitro group in 1a and the hydroxylation at the 2-position of the pyrrole ring by water to afford 3,7-dichloro-8-hydroxy-8,8a-dihydropyrrolo[2,3-b]indol-2-one (3a), accompanied by the formation of 2a. Elongation of the irradiation time in these photoreactions caused a rapid consumption of the products, 2a and 3a, to give undetermined polar polymeric products. The present results indicate that the photodegradation of 1a is significantly influenced by the presence of water in the reaction media and by the nature of its excited state. Thus, the loss of the antifungal activities by the photosensitive antibiotic 1a was chemically proved. 相似文献
8.
Widmann E Eades J Ishikawa T Sakaguchi J Tasaki T Yamaguchi H Hayano RS Hori M Torii HA Juhász B Horváth D Yamazaki T 《Physical review letters》2002,89(24):243402
Using a newly developed laser-microwave-laser resonance method, we observed a pair of microwave transitions between hyperfine levels of the (n,L)=(37,35) state of antiprotonic helium. This experiment confirms the quadruplet hyperfine structure arising from the interaction of the antiproton orbital angular momentum, the electron spin and the antiproton spin as predicted by Bakalov and Korobov. The measured frequencies of nu(+)(HF)=12.895 96+/-0.000 34 GHz and nu(-)(HF)=12.924 67+/-0.000 29 GHz agree with recent theoretical calculations on a level of 6x10(-5). 相似文献
9.
Hori M Eades J Hayano RS Ishikawa T Sakaguchi J Tasaki T Widmann E Yamaguchi H Torii HA Juhász B Horváth D Yamazaki T 《Physical review letters》2002,89(9):093401
Initial distributions of metastable antiprotonic (4)He and (3)He atoms over principal (n) and angular momentum (l) quantum numbers have been deduced using laser spectroscopy experiments. The regions n = 37-40 and n = 35-38 in the two atoms account for almost all of the observed fractions [(3.0 +/- 0.1)% and (2.4 +/- 0.1)%] of antiprotons captured into metastable states. 相似文献
10.
Kubo K Akemoto M Anderson S Aoki T Araki S Bane KL Blum P Corlett J Dobashi K Emma P Frisch J Fukuda M Guo Z Hasegawa K Hayano H Higo T Higurashi A Honda Y Iimura T Imai T Jobe K Kamada S Karataev P Kashiwagi S Kim E Kobuki T Kotseroglou T Kurihara Y Kuriki M Kuroda R Kuroda S Lee T Luo X McCormick DJ McKee B Mimashi T Minty M Muto T Naito T Naumenko G Nelson J Nguyen MN Oide K Okugi T Omori T Oshima T Pei G Potylitsyn A Qin Q Raubenheimer T Ross M Sakai H Sakai I Schmidt F Slaton T Smith H 《Physical review letters》2002,88(19):194801
Electron beams with the lowest, normalized transverse emittance recorded so far were produced and confirmed in single-bunch-mode operation of the Accelerator Test Facility at KEK. We established a tuning method of the damping ring which achieves a small vertical dispersion and small x-y orbit coupling. The vertical emittance was less than 1% of the horizontal emittance. At the zero-intensity limit, the vertical normalized emittance was less than 2.8 x 10(-8) rad m at beam energy 1.3 GeV. At high intensity, strong effects of intrabeam scattering were observed, which had been expected in view of the extremely high particle density due to the small transverse emittance. 相似文献