Determining co-combustion characteristics,kinetics and synergy behaviors of raw and torrefied forms of two distinct types of biomass and their blends with lignite

Journal of Thermal Analysis and Calorimetry - In this study, the combustion characteristics and kinetics of various mixtures of both raw and torrefied rose pulp and red pine sawdust with each other...     

Extraction-ability and -selectivity of tetra-aza-crown ethers for transition metal cations

In order to investigate the relative effects of the differences between the structures and lipophilicities of 1, 10-dioxa-4, 7, 13, 16-tetra-azacyclo-octadecane (TA-18-crown-6) and the tetrabenzyl derivative of 1,10-dioxa-4, 7, 13, 16-tetra-azacyclo-octadecane (TBTA-18-crown-6) on their extraction-abilities and -selectivities for transition metal cations, constants of the overall extraction (logK _ex) of 1:1 (M:L) complexes, the distribution (K _D) for two diluents (CH₂Cl₂ and CHCl₃) with different dielectric constants have been determined at 25 ± 0.1 °C. The magnitude of logK _ex is largely determined by that of K _D. The equilibrium constants of TA-18-crown-6 have been compared with those of TBTA-18-crown-6. It is found that:(i) logK _ex sequences of TA-18-crown-6 and TBTA-18-crown-6 for transition metals in CH₂Cl₂ lie in order: Fe³⁺ > Cu²⁺ > Mn²⁺ > Co²⁺ > Cd²⁺ > Ni²⁺ > Zn²⁺ and Fe³⁺ > Cu²⁺ > Co²⁺ > Mn²⁺ > Ni²⁺ > Cd²⁺ > Zn²⁺ respectively; (ii) the stability sequences of two types of tetra-aza-crown ethers with the transition metal cations in CHCl₃ are the same as follows: Fe³⁺ > Ni²⁺ > Cu²⁺ > Co²⁺ > Zn²⁺ > Cd²⁺ > Mn²⁺, and (iii) unusual selectivities are observed for transition metal-tetra-aza-crowns, e.g. the high Fe³⁺/M ⁿ⁺ selectivity factors (S_f) of TA-18-crown-6, except for the competitive-extractions for the special case in CHCl₃ of TBTA-18-crown-6, it was found that the Mn²⁺/M ⁿ⁺ values were relatively higher according to the other transition metal cations. A systematic sequence in these two types of solvents is not found for a given transition metal cation in terms of the variation of selectivity with the tetra-aza-crown ethers. The results provide alternatives for the rational design of other specific ligands on the transition metal cations.     

Decay-mode independent searches for new scalar bosons with the OPAL detector at LEP

This paper describes topological searches for neutral scalar bosons S⁰ produced in association with a Z⁰ boson via the Bjorken process at centre-of-mass energies of 91 GeV and 183-209 GeV. These searches are based on studies of the recoil mass spectrum of and events and on a search for with and S or photons. They cover the decays of the S⁰ into an arbitrary combination of hadrons, leptons, photons and invisible particles as well as the possibility that it might be stable. No indication for a signal is found in the data and upper limits on the cross section of the Bjorken process are calculated. Cross-section limits are given in terms of a scale factor k with respect to the Standart Model cross section for the Higgs-strahlung process . These results can be interpreted in general scenarios independently of the decay modes of the S⁰. The examples considered here are the production of a single new scalar particle with a decay width smaller than the detector mass resolution, and for the first time, two scenarios with continuous mass distributions, due to a single very broad state or several states close in mass. Received: 13 March 2002 / Published online: 19 February 2003     

Inclusive production of neutral vector mesons in hadronic Z decays

A data sample of about 3.0 million hadronicZ decays collected by the ALEPH experiment at LEP in the years 1991 through 1994 is used to make an inclusive selection of B hadron events. In this event sample 4227±140±252B* mesons in the decayB*→Bγ and 1944±108±161B** _u,d mesons decaying into a B meson and a charged pion are reconstructed. Here and in the followingB** _u,d denotes the eightL=1(bū) and (bd) states and their charge conjugate. For the well establishedB* meson the following quantities are obtained:ΔM=M _B*−M_B=(45.30±0.35±0.87) MeV/c² andN _B*/(N _B+N _B*)=(77.1±2.6±7.0)%. The angular distribution of the photons in theB* rest frame is used to measure the relative contribution of longitudinalB* polarization states to beσ _L/(σ _L+σ _T)=(33±6±5)%.     

Erratum: Synthesis and characterization of diorganotin(IV) complexes of Schiff bases with ONO‐type donors and crystal structure of [N‐(2‐hydroxy‐4‐nitrophenyl)‐3‐ethoxysalicylideneiminato]diphenyltin(IV)

The article referenced above was first published online on 30 August 2007 with incorrect pagination; the pagination has now been corrected online and in print. Copyright © 2007 John Wiley & Sons, Ltd.     

Search for supersymmetric particles in light gravitino scenarios and sleptons NLSP

A search for sleptons, neutralinos, charginos, sgoldstinos and heavy stable charged sleptons in the context of scenarios where the lightest supersymmetric particle is the gravitino, is presented. Data collected during 2000 with the DELPHI detector at centre-of-mass energies from 204 to 208 GeV were analysed and combined with all the data collected from 1995 to 1999 at lower energies. No evidence for the production of sleptons, neutralinos and charginos has been found, therefore new limits on the mass of these supersymmetric particles and on the model parameter space are set. The search for heavy stable charged sleptons also updates the stable sleptons mass limit. The absence of evidence for sgoldstino production allows limits to be set on its mass and on the scale of supersymmetry breaking. Received: 6 November 2002 / Published online: 14 February 2003     

Improved search for $B_{s}^{0} - \overline{B}_{s}^{0}$ oscillations

An improved search for B _s ⁰ oscillations is performed in the ALEPH data sample collected during the first phase of LEP, and reprocessed in 1998. Three analyses based on complementary event selections are presented. First, decays of B _s ⁰ mesons into hadronic flavour eigenstates are fully reconstructed. This selection yields a small sample of candidates with excellent decay length and momentum resolution and hi gh average B _s ⁰ purity. Semileptonic decays with a reconstructed D _s ^- meson provide a second sample with larger statistics, high average B _s ⁰ purity, but a poorer momentum and decay length resolution due to the partial decay reconstruction. Finally, semileptonic b-hadron decays are inclusively selected and yield the data sample with the highest sensitivity to B _s ⁰ oscillations, as the much higher statistics compensate for the low average B _s ⁰ purity and poorer time resolution. A lower limit is set atps^-1 at 95% C.L., significantly lower than the expected limit of 15.2 ps^-1. Received: 21 February 2003 / Published online: 11 June 2003     

Measurement of the $b\overline{b}$ production cross section in 920 GeV fixed-target proton-nucleus collisions

Using the HERA - B detector, the production cross section has been measured in 920 GeV proton collisions on carbon and titanium targets. The production was tagged via inclusive bottom quark decays into by exploiting the longitudinal separation of decay vertices from the primary proton-nucleus interaction. Both e ⁺ e ^- and channels have been reconstructed and the combined analysis yields the cross section . Received: 6 June 2002 / Revised version: 2 September 2002 / Published online: 8 November 2002     

Portfolio optimization in stochastic markets

We consider a multiperiod mean-variance model where the model parameters change according to a stochastic market. The mean vector and covariance matrix of the random returns of risky assets all depend on the state of the market during any period where the market process is assumed to follow a Markov chain. Dynamic programming is used to solve an auxiliary problem which, in turn, gives the efficient frontier of the mean-variance formulation. An explicit expression is obtained for the efficient frontier and an illustrative example is given to demonstrate the application of the procedure.     

Eigenvalues of Two Parameter Polynomial Operator Pencils of Waveguide Type

The spectral structure of two parameter unbounded operator pencils of waveguide type is studied. Theorems on discreteness of the spectrum for a fixed parameter are proved. Variational principles for real eigenvalues in some parts of the root zones are established. In the case of n = 1 (quadratic pencils) domains containing the spectrum are described (see Fig. 1–3). Conditions in the definition of the pencils of waveguide type arise naturally from physical problems and each of them has a physical meaning. In particular a connection between the energetic stability condition and a perturbation problem for the coefficients is given.