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G. I. Sarapulova G. K. Balakhchi L. L. Dmitrieva N. A. Nedolya 《Russian Journal of Organic Chemistry》2001,37(12):1714-1718
A prototropic rearrangement of N-prop-2-enylbenzocarbothioamide afforded two stereoisomeric N-prop-1-enylbenzocarbothioamides (IIa, b) isolated as individual compounds. The stereoisomerism is due to hindered rotation around thioamide bond C(S)-N and also to -diastereoisomerism. The configuration of the isolated isomers was investigated by IR spectroscopy, AM1 and PM3 methods. In the molecules occurs the p,-conjugation with participation of nitrogen atom and multiple bonds resulting in formation of a united delocalized MO in the planar fragment C(S)-NC = C. 相似文献
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N. N. Chipanina G. N. Sarapulova D. A. Bravo-Zhivotovskii S. D. Pigarev O. A. Byazankina Yu. I. Frolov N. S. Vyazankin 《Russian Chemical Bulletin》1984,33(2):310-313
Conclusions The values of C=0 in the IR spectra and the position of the band from the n * electronic transition in the UV spectra of the amides R1CONR2R3 vary linearly with the inductive effect of the R1 substituent (for R2=R3=H, Alk). This may indicate the absence of the intramolecular coordination Ge 0, where or. The substituent R1=Ge(C2H5)2 exhibits electron-acceptor properties besides a +I-effect.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 349–352, February, 1984. 相似文献
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G. I. Sarapulova M. V. Andreev L. P. Safronova A. S. Medvedeva 《Russian Journal of Organic Chemistry》2001,37(12):1688-1692
The specific features of molecular and electronic structure of trimethylsilylpropiolic acid amides were studied by means of IR spectroscopy and quantum chemistry (AM1). The competition between p,-conjugation in the amide fragment and ,-conjugation in the ethynylcarbonyl group CC-C=O was established. The prevailing conformers were revealed, their geometrical parameters were established, the barriers to internal rotation around the amide C-N bond were calculated for acyclic (13 kcal mol-1) and heterocyclic (8.12 kcal mol-1) amides. 相似文献
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B. G. Bazarov R. F. Klevtsova A. E. Sarapulova K. N. Fedorov L. A. Glinskaya Zh. G. Bazarova 《Journal of Structural Chemistry》2005,46(4):756-760
Single crystals of triple molybdate of composition 5:1:3 K5Pb0.5Hf1.5(MoO4)6 have been grown and their crystal structure has been solved from X-ray diffraction data (an automated diffractometer X8 APEX, MoK α -radiation, 2173 F(hkl), R = 0.0321). Trigonal unit cell parameters are: a = b = 10.739(2) Å, c = 37.933(9) Å; V = 3789(1) Å3, Z = 6, ρcalc = 4.014 g/cm3, space group \(R\bar 3\). Three-dimensional mixed framework of the structure is formed by two types of MoO4 tetrahedra and Pb and Hf octahedra linking via common O-vertices. Potassium atoms of three types occupy large vacancies in the framework. 相似文献
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Sarapulova G. I. Safronova L. P. Andreev M. V. Medvedeva A. S. 《Russian Journal of Organic Chemistry》2004,40(3):329-333
Analysis of the IR spectral parameters and the results of AM1 quantum-chemical calculations indicated distortion of the planar structure of the amide fragment and destabilization of the nitrogen configuration in new N-functionalized 3-trimethylsilylpropynamides Me3SiCCC(O)NHR. This effect is most pronounced in N-hydroxy-3-trimethylsilylpropynamide upon formation of intramolecular hydrogen bond C=O···H-O. 相似文献
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T. N. Khamaganova A. E. Sarapulova K. N. Fedorov 《Russian Journal of Applied Chemistry》2007,80(3):492-494
Polycrystalline samples of double barium borates of the composition Ba3R(BO3)3, R = Ho, Yb, Sc, were synthesized by the method of solid-phase reactions. The temperature dependence of the electrical conductivity of the compounds obtained was studied at 200–500°C. 相似文献
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A. S. Medvedeva M. V. Andreev L. P. Safronova G. I. Sarapulova D. V. Pavlov A. V. Afonin 《Russian Journal of Organic Chemistry》2002,38(1):10-14
A number of previously unknown N-(2-hydroxyethyl)trimethylsilylpropynamides were synthesized by reactions of 2-aminoethyl trimethylsilyl ethers with trimethylsilylpropynoyl chloride. 2-Hydroxyethylamine reacts with trimethylsilylpropynoyl chloride at both nitrogen and oxygen atoms to afford 2-(3-trimethylsilylpropynoylamino)ethyl trimethylsilylpropynoate. 相似文献
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