全文获取类型
收费全文 | 1951篇 |
免费 | 87篇 |
国内免费 | 5篇 |
专业分类
化学 | 1437篇 |
晶体学 | 10篇 |
力学 | 50篇 |
数学 | 113篇 |
物理学 | 433篇 |
出版年
2023年 | 13篇 |
2021年 | 35篇 |
2020年 | 26篇 |
2019年 | 33篇 |
2018年 | 19篇 |
2017年 | 18篇 |
2016年 | 55篇 |
2015年 | 56篇 |
2014年 | 60篇 |
2013年 | 99篇 |
2012年 | 153篇 |
2011年 | 133篇 |
2010年 | 60篇 |
2009年 | 68篇 |
2008年 | 86篇 |
2007年 | 67篇 |
2006年 | 77篇 |
2005年 | 77篇 |
2004年 | 65篇 |
2003年 | 69篇 |
2002年 | 40篇 |
2001年 | 45篇 |
2000年 | 30篇 |
1999年 | 22篇 |
1998年 | 18篇 |
1997年 | 27篇 |
1996年 | 34篇 |
1995年 | 17篇 |
1994年 | 31篇 |
1993年 | 20篇 |
1992年 | 28篇 |
1991年 | 25篇 |
1990年 | 16篇 |
1989年 | 14篇 |
1988年 | 16篇 |
1987年 | 11篇 |
1986年 | 11篇 |
1985年 | 22篇 |
1984年 | 23篇 |
1982年 | 21篇 |
1981年 | 32篇 |
1980年 | 15篇 |
1979年 | 19篇 |
1978年 | 27篇 |
1977年 | 23篇 |
1976年 | 19篇 |
1975年 | 22篇 |
1974年 | 11篇 |
1970年 | 13篇 |
1969年 | 13篇 |
排序方式: 共有2043条查询结果,搜索用时 34 毫秒
1.
2.
We have recently demonstrated that polarization transfer using an adiabatic passage through the Hartmann-Hahn condition (APHH-CP) by a variation of the radio-frequency amplitude can substantially improve the transfer efficiency over Hartmann-Hahn cross polarization. Here we show that APHH-CP can be combined with fast magic angle sample spinning (MAS). The heteronuclear dipolar order, established in the course of the transfer, can indeed be created and preserved. 相似文献
3.
An intermolecular aldol reaction of 20S-camptothecin-7-aldehyde in the presence of strong bases affords an unusual dimeric compound, the structure and stereochemistry of which was assigned on the basis of NMR analysis and MM2 calculations. 相似文献
4.
T. Engel M. Würtz S. Borneis St. Becker I. Klaft A. Kohl T. Kühl F. Laeri D. Marx K. Meier R. Neumann F. Schmitt P. Seelig L. Völker 《Hyperfine Interactions》1997,108(1-3):251-258
Laser spectroscopy at storage rings often suffers from a limited resolution due to Doppler-broadened resonances. Broadening
is caused by the velocity spread of the ions stored in the beam. In the following, the present status of our work on laser
systems specialized on the specific needs of laser spectroscopy at storage rings is reported.
Two pulsed laser systems were developed. One is a dye laser whose spectral bandwidth can be switched by inserting different
Littrow-prisms into the resonator. An increase in bandwidth up to a factor of 45 was achieved. This laser was used for fast
qualitative scans and high resolution measurements. The other laser system is a Nd : YAG laser pumped optical parametric oscillator.
It is a tunable laser system covering the spectral range from 410 to 4000 nm. Furthermore, a continuous wave laser with a
frequency shifted feedback cavity is described. It shows broadband emission with an adjustable bandwidth of up to 4.5 GHz.
This laser can be advantageous for laser cooling of ion beams.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
5.
Normal human dermal fibroblasts: proteomic analysis of cell layer and culture medium. 总被引:7,自引:0,他引:7
Federica Boraldi Luca Bini Sabrina Liberatori Alessandro Armini Vitaliano Pallini Roberta Tiozzo Ivonne Pasquali Ronchetti Daniela Quaglino 《Electrophoresis》2003,24(7-8):1292-1310
Proteins present within the cell layer and those released in the cell medium from in vitro cultured normal human dermal fibroblasts were separated and characterized in terms of their isoelectric point and molecular weight, by two-dimensional (2-D) gel electrophoresis. All spots in the synthetic gel were firstly analyzed by the Melanie 3 software and compared with those of breast cancer cells, colorectal epithelial cells, HL60, lymphoma cells, and platelets, already available on-line. From the identification of 144 spots from both the cell layer and the medium, we were able to recognize 89 different proteins, since a certain number of spots represented different isoforms of the same molecule. Identifications were performed by matching with on-line 2-D databases, and by matrix assisted laser-desorption/ionization-time of flight-mass spectrometry (MALDI-TOF-MS), in order to confirm the identification by matching, or to identify new proteins. The procedure we used allows (i) to design a highly reproducible reference map of the proteome of adult human normal fibroblasts in culture, (ii) to evaluate protein species produced in the cell layer as well as those released in the culture medium, and (iii) to compare data from gel matching with those obtained by MS. This work represents an essential step for a better knowledge of mesenchymal cells, given the widespread use of this cell type in both clinical and experimental investigations. 相似文献
6.
O. Wibbelhoff C. Meier A. Lorke P. Schafmeister A. D. Wieck 《Physica E: Low-dimensional Systems and Nanostructures》2004,21(2-4):516
We use frequency-dependent capacitance–voltage spectroscopy to study the dynamic charging of self-assembled InAs quantum dots. With increasing frequency, the AC charging becomes suppressed, beginning with the low-energy states. By applying an in-plane magnetic field, we generate an additional magnetic confinement that alters the tunneling barrier and hence the charging dynamics. In traveling through the potential barrier, the electrons acquire an additional momentum k0, proportional to the magnetic field B. As the tunneling is enhanced, when k0 matches the maximum of the electronic wave function Ψ (in momentum representation), we are able to map out the shape of Ψ by varying B. 相似文献
7.
The analysis of barbiturates in human serum (or plasma) and urine by high-performance capillary electrophoresis-electrokinetic capillary chromatography with on-column fast-scanning multi-wavelength detection is discussed. The use of a buffer of ca. pH 8 and containing sodium dodecyl sulphate provides a medium suitable for fast and high-resolution separations of barbiturates. Seven barbiturates are characterized by their retention and absorption spectra between 195 and 320 nm. Comparison of these computer-stored data with those of unknown samples is shown to allow the identification of barbiturates in samples of patients undergoing pharmacotherapy and in toxicological urine and serum specimens. Three-dimensional electropherograms provide reliable information on the requirement and suitability of sample pretreatment procedures. With urine, extraction of barbiturates prior to analysis is necessary. With human serum several barbiturates, including phenobarbital, are shown to elute in an interference-free window in front of uric acid and the proteins, allowing these substances to be determined by direct sample injection. The need for multi-wavelength detection over a relatively wide wavelength range as a means of peak confirmation in electrokinetic capillary analyses is demonstrated and limitations of this technique for compounds with similar retention behaviour and absorption spectra are discussed. 相似文献
8.
We report on calculations of the electric field gradient at the site of the Al nucleus in the Si-H-Al complex in silicon. As a model for the surroundings of the complex we used a cluster consisting of 43 silicon and one aluminum atoms. The geometry of this cluster was fully optimized at the Hartree-Fock level. To discuss the dependence of our results on the level of theory, we studied a subcluster of four silicon and one aluminum atoms at the Hartree-Fock and CASSCF level. 相似文献
9.
10.