Silica Gel Supported Ferric Perchlorate: A New and Efficient Reagent for One Pot Synthesis of Amides from Benzylic Alcohols

Benzylic alcohols react efficiently with nitriles in the presence of silica gel supported ferric perchlorate to produce amides in high yields.     

On the uniformization of the solutions of the porous medium equation inR N

The asymptotics of the solution of the porous medium equation are related to the size of the initial data measured in an optimal way. The universality of the separable solutions is established. Finally an interesting difference with the heat equation is pointed out. Supported in part by the National Science Foundation under Grant MCS-800L540.     

Proton NMR probing of stoichiometry and thermodynamic data for the complexation of Na and Li ions with 15-Crown-5 in acetonitrile-nitrobenzene mixtures

Proton NMR was used to study the complexation reaction of Li⁺ and Na⁺ ions with 15-Crown-5 (15C5) in a number of binary acetonitrile (AN)-nitrobenzene (NB) mixtures at different temperatures. In all cases, the exchange between free and complexed 15C5 was fast on the NMR timescale and only a single population average ¹H signal was observed. The formation constants of the resulting 1:1 complexes in different solvent mixtures were determined by computer fitting of the chemical shift mole ratio data. There is an inverse relationship between the complex stability and the amount of AN in the solvent mixtures. The enthalpy and entropy values for the complexation reaction were evaluated from the temperature dependence of the formation constants. In all the solvent mixtures studied, the resulting complex is enthalpy stabilized but entropy destabilized. Finally, the experimental results were compared with theoretical ones that were obtained from molecular modeling methods. Based on our results, it is most probable that Li⁺-15C5 in solvent stays in a rather nesting complex form with greater LogK_f values, but Na⁺-15C5 forms a complete perching complex form with lower LogK_f values.     

Analytical solution of time‐fractional Navier–Stokes equation in polar coordinate by homotopy perturbation method

In this letter, we implement a relatively new analytical technique, the homotopy perturbation method (HPM), for solving linear partial differential equations of fractional order arising in fluid mechanics. The fractional derivatives are described in Caputo derivatives. This method can be used as an alternative to obtain analytic and approximate solutions of different types of fractional differential equations applied in engineering mathematics. The corresponding solutions of the integer order equations are found to follow as special cases of those of fractional order equations. Some numerical examples are presented to illustrate the efficiency and reliability of HPM. He's HPM, which does not need small parameter is implemented for solving the differential equations. In this method, a homotopy is introduced to be constructed for the equation. The initial approximations can be freely chosen with possible unknown constants that can be determined by imposing the boundary and initial conditions. It is predicted that HPM can be found widely applicable in engineering. © 2009 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 2010     

Effect of C60-SiO2 hybrid nanoparticles on thermophysical and tribological properties of a multigrade engine oil: an experimental study

Journal of Thermal Analysis and Calorimetry - In this study, the thermophysical and tribological properties of a hybrid nanofluid containing fullerene-silica nanoparticles in a multigrade engine...     

ISFET immunosensor improvement using amine-modified polystyrene nanobeads

Antigen-based sensing is recognized as a rapid and sensitive analysis among bioresearch groups. The potential of “on-site” analysis in such devices has been accompanied by some problems. Fabrication of silicon compatible and highly sensitive biosensors has been the center of excessive research within the past few years. In this paper, we report fabrication of two types of sensitive liquid oxide semiconductor (LOS) biosensors using nanostructures. These devices have been manufactured and characterized as immunosensors. These two types of sensors have been produced using different platforms for immobilization of proteins; one based on a functionalized silicon dioxide surface by 3-aminopropyltriethoxysilane (APTES) and another on the basis of using 50-nm amine-modified polystyrene nanobeads. The polystyrene platform not only benefits from its nanosize and high surface to volume ratio but also does not need any new protocol than what is already used for traditional immunosensing system. These sensors measure the change of threshold voltage of the semiconductor inversion inside the capacitor due to the bonding of antibodies to the linked peptides on the surface. Measurements showed that the sensitivity of 50-nm polystyrene-based sensor is much more than the oxide-based one. The nanobeads were then chosen to cover the gate of the ISFET for the amplified sensing. The ISFET devices were biased in a subthreshold region to demonstrate the maximum sensitivity to the accumulated charge on the gate. Repeatable results after different stress tests were obtained, which proves the suitability and reliability of the polystyrene nanobead platform for this application. Finally, a calibration curve has been derived that can be used for real sample measurements. The detection limit of 1.0152 μg/ml was calculated for the fabricated sensor.

Open image in new window

Graphical abstract

     

Preparation of forcespun γ-irradiated chitin from shrimp shell wastes and its evaluation as uranyl ion adsorbent

Journal of Radioanalytical and Nuclear Chemistry - Chitosan (CS) was synthesized by gamma irradiation of chitin extracted from shrimp shell wastes. CS nanofibers (CS-NFs) with a diameter of...