Diffusion von chemisor biertem H2 an einem Ni-Katalysator

Ohne Zusammenfassung     

Copper and iron interactions with angiotensin-converting enzyme inhibitors. A study by fast-atom bombardment tandem mass spectrometry

Fast atom bombardment, combined with high-energy collision-induced tandem mass spectrometry, has been used to investigate gas-phase metal-ion interactions with captopril, enalaprilat and lisinopril, all angiotensin-converting enzyme inhibitors.Suggestions for the location of metal-binding sites are presented. For captopril, metal binding occurs most likely at both the sulphur and the nitrogen atom. For enalaprilat and lisinopril, binding preferably occurs at the amine nitrogen. Copyright 1999 John Wiley & Sons, Ltd.     

Chemisorption of water on nickel surfaces

Magnetic and volumetric measurements associated with neutron inelastic spectroscopy demonstrate that water is dissociatively adsorbed on nickel. In the case of Raney nickel, for low coverages, the oxygen is fixed on surface aluminium atoms and hydrogen occupies two nickel sites. At high coverage, the water molecule is fixed via oxygen bonding to the hydrogen covered nickel. On nickel prepared from its hydroxide, adsorption is reversible, the water molecule occupying six metal sites.     

Determination of loads applied perpendicularly to the outer boundary of a ring using coefficients of influence

A procedure is explained to determined the amount of several pairs of diametrical loads applied to the outside boundary of a ring when stresses at selected points of the inside or outside boundaries are known. Coefficients of influence are used, following an approach similar to the one presented in a previous paper. Examples of application are given and the possible increase in precision is shown when the number of points of measurements is larger than the number of loads to be determined.