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排序方式: 共有164条查询结果,搜索用时 296 毫秒
1.
V. P. Antonovich I. V. Stoyanova N. A. Chivireva E. V. Timukhin V. F. Zinchenko N. P. Efryushina 《Journal of Analytical Chemistry》2007,62(3):238-244
Diffuse reflectance spectroscopy in the UV, visible, and near-IR regions is found to allow the detection and identification of lanthanide oxides, fluorides, sulfides, and sulfofluorides without decomposing and dissolving samples. A nondestructive method for the detection and quantitative determination of more than 1 wt % of Eu(II) in the corresponding fluorides is proposed. 相似文献
2.
The paper studies the Painlevé VIe equations from the point of view of Hamiltonian nonintegrability. For certain infinite number of points in the parameter
space we prove that the equations are not integrable. Our approach uses recent advance in Hamiltonian integrability reducing
the problem to higher differential Galois groups as well as the monodromy of dilogarithic functions.
相似文献
3.
V. I. Simagina V. V. Litvak I. V. Stoyanova V. A. Yakovlev V. M. Mastikhin I. V. Afanasenkova V. A. Likholobov 《Russian Chemical Bulletin》1996,45(6):1321-1324
Hydrodechlorination of chlorobcnzene by chemically bound hydrogen in the presence of transition metal compounds was studied. Alkali and alkaline earth metal hydrides (NaH, MgH2, LiAlH4, NaH(LiAlH4)/12) were used as the sources of the chemically bound hydrogen. The effect of the natures of the hydride and of the transition metal on the activity was studied under comparable conditions. The Pd/C-NaH(LiAlH41/2 catalytic system was found to be the most active. This system made it possible to perform the quantitative dechlorination of 2,3-dichlorodibenzo-p-dioxin at 70 °C.Deceased.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1391–1394, June, 1996. 相似文献
4.
I. V. Shkutina O. F. Stoyanova V. F. Selemenev 《Russian Journal of Applied Chemistry》2005,78(6):981-984
Some fundamental aspects of the immobilization of a hydrolytic enzyme glucoamylase via adsorption on aminocarboxylic ion-exchangers with fibrous structure were considered. The sorption capacity of amphoteric supports for the enzyme was studied in relation to the time of immobilization, concentration of hydrogen ions and the protein, and the ionic form of a polyelectrolyte. The catalytic properties of free and immobilized enzymes were compared.__________Translated from Zhurnal Prikladnoi Khimii, Vol. 78, No. 6, 2005, pp. 1003–1005.Original Russian Text Copyright © 2005 by Shkutina, Stoyanova, Selemenev. 相似文献
5.
T. V. Koksharova I. S. Gritsenko I. V. Stoyanova 《Russian Journal of General Chemistry》2006,76(6):862-870
Complexes of Co(II), Ni(II), and Cu(II) valerates and benzoates with semicarbazide were prepared. The compounds were characterized by chemical analysis, X-ray phase analysis, IR spectroscopy, diffuse reflection spectroscopy, and thermal gravimetric analysis. 相似文献
6.
Stefan Stoyanov Tatyana Stoyanova Pericles D. Akrivos Petros Karagiannidis Peter Nikolov 《Journal of heterocyclic chemistry》1996,33(3):927-931
The electronic absorption and emission spectra of some symmetrical heterocyclic disulfides are investigated. The reversible disulfide — thione transformation in water is discussed in view of the complex equilibrium processes present. UV irradiation and pH influence on the above transformation is also studied. The emission properties at room and low temperature are related to the computed molecular geometries of the ground and low excited states of the compounds. 相似文献
7.
8.
S. P. Denisov V. N. Evdokimov A. V. Kozelova N. N. Prokopenko M. M. Soldatov D. A. Stoyanova V. I. Yakimchuk 《Bulletin of the Lebedev Physics Institute》2010,37(4):104-110
The Cherenkov counter for measuring the numbers of protons in bunches extracted from the IHEP accelerator using a slow extraction
system is described. The measurement range is from 1 to 106 particle/bunch. The maximum bunch frequency is 6 · 106 s–1. Cherenkov light is measured by an XP 2020 photomultiplier. The results of measurements of the XP 2020 signal amplitude on
the applied voltage, obtained using semiconductor light sources are presented. The data of counter calibration on the proton
beam are discussed. 相似文献
9.
D. Kocheva G. Rainovski J. Jolie N. Pietralla A. Blazhev A. Astier R. Altenkirch S. Ansari Th. Braunroth M. L. Cortés A. Dewald F. Diel M. Djongolov C. Fransen K. Gladnishki A. Hennig V. Karayonchev J. M. Keatings E. Kluge J. Litzinger C. Müller-Gatermann P. Petkov M. Rudigier M. Scheck Ph. Scholz P. Spagnoletti M. Spieker C. Stahl R. Stegmann M. Stoyanova P. Thöle N. Warr V. Werner W. Witt D. Wölk K. O. Zell P. Van Isacker V. Yu. Ponomarev 《The European Physical Journal A - Hadrons and Nuclei》2017,53(9):175
10.
Hristo Rasheev Prof. Dr. Radostina Stoyanova Prof. Dr. Alia Tadjer 《Chemphyschem》2021,22(11):1110-1123
The construction of hybrid metal-ion batteries faces a plethora of challenges. A critical one is to unveil the solvation/desolvation processes at the molecular level in electrolytes that ensure efficient transfer of several types of charge carriers. This study reports first results on simulations of mixed-ion electrolytes. All combinations of homo- and hetero-binuclear complexes of Li+, Na+ and Mg2+, solvated with varying number of ethylene carbonate (EC) molecules are modeled in non-polar and polar environment by means of first principles calculations and compared to the mononuclear analogues in terms of stability, spatial organization, charge distribution and solvation/desolvation behavior. The used PF6− counterion is shown to have minor impact on the geometry of the complexes. The desolvation energy penalty of binuclear complexes can be lowered by the fluoride ions, emerging upon the PF6− decay. These model investigations could be extended to rationalize the solvation structure and ionic mobility in dual-ion electrolytes. 相似文献