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1.
Laurence E. Strong Christopher L. Brummel Robert Ryther John R. Radford Alan D. Pethybridge 《Journal of solution chemistry》1988,17(12):1145-1167
Precision molar conductances of benzoic, o-toluic, 2,6-dimethylbenzoic, 2,3,6-trimethylbenzoic, and, o-fluorobenzoic acids have been determined in aqueous solution as a function of temperature and of concentration up to near saturation (<0.035 M). At the higher concentrations molar conductances are found to be less than anticipated for the simple dissociation of a 1-1 electrolyte. Although the deviations are only 1% or less they have been interpreted to show that these acids are dimerized in solution. The interpretation includes an assumption that the dimer ionizes to produce a triple ion. Increasing numbers of methyl groups lead to increasing dimerization. For those acids with two ortho groups the dimerization increases with increasing temperature while the other three show decreasing dimerization with increasing temperature. Temperature functions have been determined for the dimerization constants and from these functions standard changes in enthalpy, entropy, and heat capacity have been determined. Comparisons are made with dimerization studies in non-aqueous solvents. From these as well as the behavior of benzene in water it is concluded that a major factor driving the dimerization is hydrophobic interaction. To provide a limiting conductance of the triple ion needed in the dimerization calculations a conductance study was also made for o-Phenylbenzoic acid on the assumption that its anion provides an approximate model of the triple ion. 相似文献
2.
R. Broda P. J. Daly J. McNeill R. V. F. Janssens D. C. Radford 《Zeitschrift für Physik A Hadrons and Nuclei》1987,327(4):403-408
The level structure of theN=81 nucleus149Er has been studied by γ-ray spectroscopy following the reaction92Mo+255 MeV60Ni. Yrast levels in149Er are established up to ~3.3 MeV, including 0.61 and 4.8 μs isomeric states. Most of the observed levels are interpreted as seniority-three states arising from the coupling of s1/2, d3/2 and h11/2 neutron holes with πh 11 2/n . Isomers identified in the reaction96Ru+255 MeV58Ni are tentatively assigned to151Yb. TheB (E2) values of high-spin isomers inZ=66?70,N=81?83 nuclei are surveyed. 相似文献
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H.E. Radford 《Chemical physics letters》1980,71(2):195-197
The rate coefficient of the reaction CH2 + O2OH → HO2 + CH2O, has been measured at 300 K by the LMR flow-tube method, and found to have the unexpectedly large value k = (2?1+2) × 10?12 cm3 molecule?1 s?1. This reaction, preceded by isomerization, may be an important route for the oxidation of CH3O in the upper atmosphere. 相似文献
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Seventeen rotational transitions up to N=7 of the NH2 radical in its ground vibronic state have been measured by far infrared laser magnetic resonance spectroscopy. Analysis of the Zeeman patterns and hyperfine structure yields precise rotational, spin-rotational and distortion parameters, and isotropic and anisotropic hyperfine interaction parameters for both 14N and 1H nuclei. 相似文献
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