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1.
Raana Kashfi‐Sadabad Laura Gonzalez‐Fajardo Derek Hargrove Bahar Ahmadi Daniel Munteanu Sina Shahbazmohamadi Michael Jay Xiuling Lu 《Particle & Particle Systems Characterization》2019,36(4)
Nonspecific high‐energy radiation for treatment of metastatic ovarian cancer is limited by damage to healthy organs, which can be mitigated by the use of radiosensitizers and image‐guided radiotherapy. Gold (Au) and tantalum oxide (TaOx) nanoparticles (NPs), by virtue of their high atomic numbers, find utility in the design of bimetallic NP systems capable of high‐contrast computed tomography (CT) imaging as well as a potential radiosensitizing effect. These two radio‐dense metals are integrated into dendritic mesoporous silica NPs (dMSNs) with radial porous channels for high surface‐area loading of therapeutic agents. This approach results in stable, monodispersed dMSNs with a uniform distribution of Au on the surface and TaOx in the core that exhibits CT attenuation up to seven times greater than iodine or monometallic dMSNs without either TaOx or Au. Tumor targeting is assessed in a metastatic ovarian cancer mouse model. Ex vivo micro‐CT imaging of collected tumors shows that these NPs not only accumulate at tumor sites but also penetrate inside tumor tissues. This study demonstrates that after intraperitoneal administration, rationally designed bimetallic NPs can simultaneously serve as targeted contrast agents for imaging tumors and to enhance radiation therapy in metastatic ovarian cancer. 相似文献
2.
A new method for modeling and analysis of deformed carbon nanotubes (CNTs) using Green’s function, is presented in this paper,
for the first time. Using the proposed method, a new circuit model is obtained for the deformation region of a deformed single-walled
CNT (SWCNT), which the values of its elements depend on the type of deformation and also the deformation parameters such as
the coupling matrices and the energy variations of deformation region. The comparison between the obtained results from the
analysis of proposed model and the literature gives a good match which approves the accuracy and correctness of the proposed
model. 相似文献
3.
Enhanced properties of photovoltaic devices tailored with novel supramolecular structures based on reduced graphene oxide nanosheets grafted/functionalized with thiophenic materials 下载免费PDF全文
Samira Agbolaghi Sara Ebrahimi Bakhshali Massoumi Saleheh Abbaspoor Raana Sarvari Farhang Abbasi 《Journal of Polymer Science.Polymer Physics》2017,55(24):1877-1889
For verifying the influence of donor–acceptor supramolecules on photovoltaic properties, different hybrids were designed and used in organic solar cells. In this respect, reduced graphene oxide (rGO) was functionalization with 2‐thiophene acetic acid (rGO‐f‐TAA) and grafted with poly(3‐dodecylthiophene) (rGO‐g‐PDDT) and poly(3‐thiophene ethanol) (rGO‐g‐PTEt) to manipulate orientation of poly(3‐hexylthiophene) (P3HT) assemblies. Face‐on, edge‐on, and flat‐on orientations were detected for assembled P3HTs on rGO and its functionalized and grafted derivatives, respectively. Alteration of P3HT orientation from face‐on to flat‐on enhanced current density (J sc), fill factor (FF), and power conversion efficiency (PCE) and thus J sc = 7.11 mA cm?2, FF = 47%, and PCE = 2.14% were acquired. By adding phenyl‐C71‐butyric acid methyl ester (PC71BM) to active layers composed of pre‐designed P3HT/rGO, P3HT/rGO‐f‐TAA, P3HT/rGO‐g‐PDDT, and P3HT/rGO‐g‐PTEt hybrids, photovoltaic characteristics further improved, demonstrating that supramolecules appropriately mediated in P3HT:PC71BM solar cells. Phase separation was more intensified in best‐performing photovoltaic systems. Larger P3HT crystals assembled onto grafted rGOs (95–143 nm) may have acted as convenient templates for the larger and more intensified phase separation in P3HT:PCBM films. The best performances were reached for P3HT:P3HT/rGO‐g‐PDDT:PCBM (J sc = 9.45 mA cm?2, FF = 54%, and PCE = 3.16%) and P3HT:P3HT/rGO‐g‐PTEt:PCBM (J sc = 9.32 mA cm?2, FF = 53%, and PCE = 3.11%) photovoltaic systems. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2017 , 55 , 1877–1889 相似文献
4.
Mansoori Y. Sarvari R. Zamanloo M. R. Imanzadeh G. H. 《Russian Journal of Organic Chemistry》2009,45(1):154-157
Different bis-phenols reacted with cyanogen bromide in the presence of triethylamine as base to give the corresponding bis-cyanates
which were treated with sodium azide in acetone as solvent to produce new bis(5-oxy-1H-tetrazole) derivatives. One more bis-tetrazole derivative was synthesized by reaction of 5-(4-aminophenoxy)-1H-tetrazole with adipoyl chloride. The prepared compounds were characterized by usual spectroscopic techniques.
Published in Russian in Zhurnal Organicheskoi Khimii, 2009, Vol. 45, No. 1, pp. 156–159.
The text was submitted by the authors in English. 相似文献
5.
Palladium Supported on Zinc Oxide Nanoparticles as Efficient Heterogeneous Catalyst for SuzukiMiyaura and Hiyama Reactions under Normal Laboratory Conditions 下载免费PDF全文
Nanoscale Pd supported on ZnO was prepared by a facile coprecipitation method. Pd/ZnO Nanoparticles were characterized by using XRD, TEM, SEM, XPS, BET specific surface area measurement, and thermogravimetric analysis. This catalyst was used as novel and excellent heterogeneous catalyst for ligand‐free C? C bond‐formation particularly in the synthesis of unsymmetrical biaryls by Suzuki? Miyaura and Hiyama cross‐coupling reactions under air atmosphere without use of any Ar or N2 flow. The catalyst can be recovered and recycled several times without marked loss of activity. 相似文献
6.
An Efficient Method for Chemoselective Reduction of Nitro Compounds Using Bimetallic Fe‐Ni NPs/H3PW12O40.×H2O System 下载免费PDF全文
Soodabeh Rezazadeh Batool Akhlaghinia Elaheh K. Goharshadi Hossein Sarvari 《中国化学会会志》2014,61(10):1108-1114
The selective reduction of nitro compounds by treatment with bimetallic Fe‐Ni nanoparticles (NPs) and tungestophosphoric acid hydrate (H3PW12O40.×H2O) in H2O is reported. The method has been applied to a broad range of nitro compounds with different sensitive functionalities, including halides, carbonyl, hydroxyl, aldehyde, methyl, acetyl, nitrile, and ester substituents with excellent yields. The reaction yielded single product in all cases with very high yield. The simple experimental procedure and easy purification make the protocol advantageous. 相似文献
7.
Davood?FathiEmail author Behjat?Forouzandeh Reza?Sarvari 《Applied Physics A: Materials Science & Processing》2011,102(1):231-238
A new method for the analysis of electron transmission property in single-walled carbon nanotubes (SWCNTs) using Green’s function
is presented in this paper for the first time. Using the proposed method, a new relation for the transmission function through
a deformed SWCNT is obtained, which depends on the energy variations and the coupling matrices related to the mechanical deformations
applied to the structure of CNT. The obtained new relation is explained by the presented results in the literature. 相似文献
8.
9.
Yagoub Mansoori Raana Sarvari Mohammad Reza Zamanloo Gholam Hassan Imanzadeh 《高分子科学》2010,28(1):21-28
<正>In the present work,new thermally stable polymers containing 1,3,4-oxadiazole units have been synthesized through Huisgen reaction of the aromatic bis-tetrazole compounds with the aromatic/aliphatic bis-acid chlorides in pyridine as solvent.The obtained polymers are insoluble or slightly soluble in polar aprotic solvents such as DMSO and DMF. Thermal analyses of the polymers using DSC and TGA techniques showed that the polymers had improved thermal stabilities.The model reaction was also investigated and the resulting bis-l,3,4-oxadiazole compounds were characterized by conventional spectroscopic methods. 相似文献
10.
Hashem Sharghi Mona Hosseini‐Sarvari Fatemeh Moeini Reza Khalifeh AlirezaSalimi Beni 《Helvetica chimica acta》2010,93(3):435-449
A safe, efficient, and improved procedure for the regioselective synthesis of 1‐(2‐hydroxyethyl)‐1H‐1,2,3‐triazole derivatives under ambient conditions is described. Terminal alkynes reacted with oxiranes and NaN3 in the presence of a copper(I) catalyst, which is prepared by in situ reduction of the copper(II) complex 4 with ascorbic acid, in H2O. The regioselective reactions exclusively gave the corresponding 1,4‐disubstituted 1H‐1,2,3‐triazoles in good to excellent yields. This procedure avoids the handling of organic azides as they are generated in situ, making this already powerful click process even more user‐friendly and safe. The remarkable features of this protocol are high yields, very short reaction times, a cleaner reaction profile in an environmentally benign solvent (H2O), its straightforwardness, and the use of nontoxic catalysts. Furthermore, the catalyst could be recovered and recycled by simple filtration of the reaction mixture and reused for ten consecutive trials without significant loss of catalytic activity. No metal‐complex leaching was observed after the consecutive catalytic reactions. 相似文献