Summary A series of new five-coordinate complexes of cobalt(II) of the type, dihalotris-(2-substituted imidazole)cobalt(II), of formulae Co(2-MeIm)3Cl2, Co(2-EtIm)3X2 (X = Cl, Br, I) and Co(2-i-PrIm)3I2, were synthesized and characterized by elemental analyses, electrolytic conductivity, diffuse reflectance as well as by solution spectra, i.r. and far i.r. spectra, x-ray powder pattern and magnetic susceptibility measurements. The mass spectra of the complexes did not exhibit peaks due to the molecular ions, but only showed the ligand fragmentation patterns. The t.g.a. and d.t.a. measurements were also carried out for the complexes. 相似文献
Summary The new macrocyclic ligand 7,14-o-hydroxyphenyl-5,12-dimethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene (1=L) has been prepared and complexes with copper(II), nickel(II) and cobalt(III) characterised. The nickel(II) complex is a yellow square-planar species, while the purple-red copper(II) complex is probably tetragonal in both the solid state and solution. The complexes appear to have an N-meso arrangement of the chiral nitrogen centres with the HOC6H4 groups occupying equatorial sites so that axial interactions with the metal do not occur. A variety oftrans-[CoLX2]ClO4 complexes (X=Cl, Br, NO2, or N3) have been characterised. 相似文献
A non-destructive, in situ current normalized particle induced gamma-ray emission methodology has been standardized for quantification of fluorine (F) in soil samples from Punjab state, India. The samples were irradiated using 4 MeV proton beam from the Folded Tandem Ion Accelerator at BARC, Mumbai. The gamma rays of energies 197 and 478 keV arising from 19F(p, p′γ)19F and 7Li(p, p′γ)7Li nuclear reactions were measured using high resolution gamma-ray spectrometry. The concentration of fluorine in soil samples was found to vary between 414 and 5,746 mg kg?1. 相似文献
Nuclear analytical methods namely in situ current normalised Particle Induced Gamma Ray Emission (PIGE) and conventional Instrumental Neutron Activation Analysis (INAA) were utilized for determining major, minor and trace concentrations of eighteen elements in five soda-lime (automobile) glass samples. Concentration of four major elements (Si, Na, Mg and Al) by PIGE and fourteen elements including ten trace elements by INAA were determined. For forensic application, major elements were used for confirming the class of glass samples, whereas concentration results of trace elements like transition and rare earth elements were utilized for finding similarity or differences among the glass samples.
Amorphous ribbons of different thicknesses of Co64.5Fe3.5Si16B14Ni2 alloy were synthesized using the melt spinning technique by varying wheel speed. The effect of cooling rate on the ribbon thickness and their soft magnetic properties have been studied. The amorphous structure has been characterized in terms of structural free volume and medium range order (MRO) by positron annihilation spectroscopy and fluctuation electron microscopy techniques. Positron lifetime spectra of amorphous samples showed two lifetime components. The first component was found to be correlated with MRO whereas, the second lifetime component was found to be associated with nanovoid type of defects, and the second component was strongly dependent on processing conditions. It could be established that the coercivity of the amorphous samples produced by the rapid solidification technique mainly depends on the defects formed during processing rather than change induced in MRO. 相似文献
Dynamics of ethylene glycol (EG) adsorbed in H-ZSM5 zeolite as studied using quasielastic neutron scattering (QENS) technique
is reported here. Analysis of QENS data revealed that observed dynamics correspond to isotropic rotational motion of EG. Rotational
diffusion coefficient of EG adsorbed in H-ZSM5 zeolite is found to be slower compared to bulk and comparable to that of benzene
adsorbed in the same host. Positron Annihilation Spectroscopy (PAS) technique is used to understand the nature of guest-host
interaction and the results of both QENS and PAS are found to be consistent with each other. 相似文献
Temperature dependence of positron annihilation lifetime spectra of polysilanes such as, poly(methyl-n-propylsilane) (PMPrS) and poly(di-n-hexylsilane) (PDHS) has been investigated. The τ3 in PMPrS is seen to increase monotonically around the solid–liquid transition temperature. The transition temperature and free volume are observed to depend on the molecular weight and/or packing of the backbones. For PDHS, a sharp change in τ3 and I3 is seen at the solid–solid transition temperature. Free volume radius probability density functions, above and below the transition temperature, are presented in PMPrS and PDHS. Positron studies are complimented by conventional thermal analysis studies. 相似文献