Single electron tunneling rates in multijunction circuits

The rate of electron tunneling through normal metal tunnel junctions is calculated for the case of ultrasmall junction capacitances. The so-called Coulomb blockade of electron tunneling at low temperatures is shown to be strongly affected by the external electrical circuit. Under the common experimental condition of a low impedance environment the Coulomb blockade is suppressed for single tunnel junctions. However, a Coulomb gap structure emerges for junctions embedded in a high impedance environment. For a double junction setup a Coulomb blockade of tunneling arises even for low impedance environments due to the charge quantization on the metallic island between the junctions. An approach using circuit analysis is presented which allows to reduce the calculation of tunneling rates in multijunction circuits to those of a single junction in series with an effective capacitance. The range of validity of the socalled local rule and global rule rates is clarified. It is found that the tunneling rate tends towards the global rule rate as the number of junctions is increased. Some specific results are given for a one-dimensional array of tunnel junctions.     

Planar Chromatographic Study of Flavonoids and Soyasaponins for Validation of Fingerprints of Desmodium adscendens of Different Origin

JPC – Journal of Planar Chromatography – Modern TLC - The flavonoid and triterpenoid soyasaponin content of the aerial parts of Desmodium adscendens from four geographical origins of...     

Plant drug analysis by planar chromatography

Optimal performance laminar chromatography and automated multiple development chromatography are relatively recent techniques of planar chromatography that can be applied with success in plant material analysis. Therefore, these methods are used to study plant extracts and constituents belonging to different chemical classes of secondary metabolism: heterocyclic oxygen compounds (coumarins, flavonoids, and anthocyanins), alkaloids and quaternary ammonium salts, cannabinoids, essential oils, ginsenosides, and cardiac heterosides. Generally, the results obtained with these methods are good, and in most cases they compare with those of thin-layer chromatography.     

Direct observation of macroscopic charge quantization

The circuit formed by a nanoscale tunnel junction in series with a capacitance and a voltage source is the building block of most multi-junction circuits of single electronics. The state of this single electron box is entirely determined by the numbern of extra electrons on the intermediate island electrode between the junction and the capacitance. We have fabricated such a system and measured the charge on the junction capacitance, which is directly related to the average value ofn, as a function of the bias voltage using a Fulton-Dolan electrometer. At low temperature, the junction charge followed thee-periodic sawtooth function expected from the theory of macroscopic charge quantization. Strikingly,e-periodic variations were also observed when the box was superconducting. The thermal rounding of the sawtooth function is well explained by a simple model, except at the lowest temperatures.     

Separation and identification of cannabis components by different planar chromatography techniques (TLC, AMD, OPLC)

The use of cannabis is illicit in numerous countries, and the increasing consumption has led to a multiplication of scientific studies. New methods of planar chromatography such as automated multiple development (AMD) and optimum performance laminar chromatography (OPLC) techniques can be used as a substitute for the traditional thin-layer chromatography for the identification and quantitation of the Indian hemp components. Each method offers its own advantage: high resolution with neither diffusion nor spot stretching for AMD and speed, efficiency, and the possibility of working in the semipreparative mode for OPLC.     

An expeditious construction of 9-membered rings

9-Membered rings are readily constructed through a radical addition-cyclisation sequence on a 1,6-dien-3-ol system followed by a Grob-type fragmentation.     

Superconducting atomic contacts under microwave irradiation

We have measured the effect of microwave irradiation on the dc current-voltage characteristics of superconducting atomic contacts. The interaction of the external field with the ac supercurrents leads to replicas of the supercurrent peak, the well-known Shapiro resonances. The observation of supplementary fractional resonances for contacts containing highly transmitting conduction channels reveals their nonsinusoidal current-phase relation. The resonances sit on a background current which is itself deeply modified, as a result of photon-assisted multiple Andreev reflections. The results provide firm support for the full quantum theory of transport between two superconductors based on the concept of Andreev bound states.