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Bekzat ABDIKADYR Alp KILI Onur ALEV Serkan BÜYÜKK
SE Zafer Ziya
ZTÜRK 《Turkish Journal of Chemistry》2021,45(2):295
Pristine and WO3 decorated TiO2 nanorods (NRs) were synthesised to investigate n-n-type heterojunction gas sensing properties. TiO2 NRs were fabricated via hydrothermal method on fluorine-doped tin oxide coated glass (FTO) substrates. Then, tungsten was sputtered on the TiO2 NRs and thermally oxidised to obtain WO3 nanoparticles. The heterostructure was characterised by X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy-dispersive X-ray (EDX) spectroscopy. Fabricated sensor devices were exposed to VOCs such as toluene, xylene, acetone and ethanol, and humidity at different operation temperatures. Experimental results demonstrated that the heterostructure has better sensor response toward ethanol at 200 °C. Enhanced sensing properties are attributed to the heterojunction formation by decorating TiO2 NRs with WO3. 相似文献
3.
Gram‐Scale Enantioselective Formal Synthesis of Morphine through an ortho–para Oxidative Phenolic Coupling Strategy 下载免费PDF全文
Dr. Matthieu Tissot Dr. Robert J. Phipps Dr. Catherine Lucas Dr. Rafael M. Leon Dr. Robert D. M. Pace Dr. Tifelle Ngouansavanh Prof. Matthew J. Gaunt 《Angewandte Chemie (International ed. in English)》2014,53(49):13498-13501
A gram‐scale catalytic enantioselective formal synthesis of morphine is described. The key steps of the synthesis involve an ortho–para oxidative phenolic coupling and a highly diastereoselective “desymmetrization” of the resulting cyclohexadienone that generates three of the four morphinan ring junction stereocenters in one step. The stereochemistry is controlled from a single carbinol center installed through catalytic enantioselective hydrogenation. These transformations enabled the preparation of large quantities of key intermediates and could support a practical and scalable synthesis of morphine and related derivatives. 相似文献
4.
Ersen G
KTÜRK 《Turkish Journal of Chemistry》2020,44(5):1285
In this study, the catalytic activity and stability of flowerlike hybrid horseradish peroxidase (HRP) nanobiocatalyst (HRP-Cu 2+ ) obtained from Cu 2+ ions and HRP enzyme in the polymerization reaction of guaiacol were analyzed. We demonstrated that HRP-Cu 2+ and hydrogen peroxide (H 2 O 2 ) initiator showed significantly increased catalytic activity and stability on the polymerization of guaiacol compared to that of free HRP enzyme. Poly(guaiacol) was observed with quite high yields (88%) and molecular weights (38,000 g/mol) under pH 7.4 phosphate-buffered saline (PBS) conditions at 60 °C with 5 weight% of HRP-Cu 2+ loading. HRP-Cu 2+ also shows very high thermal stability and works even at 70 °C reaction temperature; free HRP enzyme denatures at that temperature. Furthermore, HRP-Cu 2+ provided considerable repeated use and showed some degree of catalytic activity, even after the fourth recycle, in the polymerization of guaiacol. 相似文献
5.
shak ERK Gzde KILI Elif
ZTÜRK engül Alpay KARAOLU Nurettin YAYLI 《Turkish Journal of Chemistry》2020,44(6):1655
The volatile components of essential oil (EO), SPME, and SPME of solvent extracts ( n -hexane, methanol, and water) obtained from fresh Serapias orientalis subsp. orientalis ( Soo ) were analyzed by GC-FID/MS. EO of Soo gave 11 compounds in the percentage of 99.97%; capronaldehyde (37.01%), 2-( E )-hexenal (23.19%), and n -nonanal (19.05%) were found to be major constituents. SPME GC-FID/MS analyses of fresh plant and solvent extracts of Soo revealed 7, 12, 7, and 4 compounds within the range of 99.7% to 99.9%. Limonene (76.5%, 41.7%, and 61.3%) was the major compound in SPMEs of the n -hexane and methanol extracts. α -Methoxy- p -cresol (52.9%) was the main component in its water extract. The antimicrobial activity of EO and the solvent extracts of Soo were screened against 9microorganisms. EO showed the best activity against Mycobacterium smegmatis , with 79.5 µg/mL MIC value. The n -hexane, methanol, and water extracts were the most active against the Staphylococcus aureus within the range of 81.25–125.0 µg/mL (MIC). IC 50 values for the lipase enzyme inhibitory activity of EO and solvent extracts ( n -hexane, methanol, and water) were determined to be 59.87 µg/mL, 64.03 µg/mL, 101.91 µg/mL, and 121.24 µg/mL, respectively. 相似文献
6.
Phipps RK Petersen BO Christensen KB Duus JØ Frisvad JC Larsen TO 《Organic letters》2004,6(20):3441-3443
[structure: see text] Hesseltin A 1, a novel compound of mixed polyketide-terpenoid origins was isolated from the filamentous fungus Penicillium hesseltinei. The structure and stereochemistry were determined from extensive one- and two-dimensional NMR and mass spectral data. 相似文献
7.
T. Yabe C. Phipps K. Aoki M. Yamaguchi R. Nakagawa C. Baasandash Y. Ogata M. Shiho G. Inoue M. Onda K. Horioka I. Kajiwara K. Yoshida 《Applied Physics A: Materials Science & Processing》2003,77(2):243-249
Laser-supported propulsion of a micro-airplane with a water-covered ablator is demonstrated. The repetitive use of an overlay
structure is experimentally demonstrated with a specially designed water supply. Various transparent overlays are investigated
by the CIP-based hydrodynamic code and by experiments using a pendulum and using a semi-conductor load cell. A momentum-coupling
efficiency of ∼104 N s/MJ is achieved by water–exotic-target experiments, in agreement with the simulation code, which predicts a maximum efficiency
of ∼105 N s/MJ. The concept of laser-supported propulsion can also be used for driving a Mach 5 airplane in the stratosphere, a micro-ship
inside the human body, and a robot in a nuclear power reactor accident, during which large numbers of neutrons make electronic
devices useless.
Received: 7 October 2002 / Accepted: 20 January 2003 / Published online: 28 May 2003
RID="*"
ID="*"Corresponding author. Fax: +81-3/5734-2165, E-mail: yabe@mech.titech.ac.jp 相似文献
8.
The task of assessing the similarity of pattern between the entries of two square matrices has been discussed extensively over the last decade, as a unifying strategy for approaching a variety of seemingly disparate statistical problems. As typically defined, the comparison depends on a measure of matrix correspondence, usually a normalized cross-product measure of some form, that is evaluated for relative size by the use of a reference distribution constructed through an equally likely permutation hypothesis defined at the level of the objects corresponding to the rows and columns of the two matrices. The extreme generality provided by this very simple framework subsumes a variety of different statistical problems, ranging from the study of spatial autocorrelation for variables observed over a set of geographic locations, to the topics of analysis of variance, the measurement of rank correlation, and confirmation techniques concerned with various conjectures of combinatorial structure that might be posited for an empirically determined measure of relationship between pairs of a given set of objects. The comparison strategies extant always assume that both matrices are fixed, and in those cases where one of the matrices codifies a given theoretical structure to be evaluated according to a second, this assumption can lead to substantial arbitrariness in how matrix similarity might be indexed, and thus, in how the comparison is implemented. As developed in this paper, exactly the same principles appropriate for use in the fixed comparison context can be extended to include matrices constructed through optimally weighted linear combinations of other sets of matrices. This generalization provides one mechanism for developing comparison strategies that allow assessment against very broad classes of matrices, which in turn serve to represent very general conjectures of possible combinatorial structure. This paper reviews some of these extensions in detail, with a particular emphasis on categorical and ordered categorical variables and whether they may reflect an empirically generated measure of object relationship. 相似文献
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