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For sequences of rational functions, analytic in some domain, a theorem of Montel's type is proved. As an application, sequences of rational functions of the best L
p
-approximation with an unbounded number of finite poles are considered. 相似文献
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Let f be a function, continuous and real valued on the segment Δ, Δ ⊂ (−∞, ∞) and {Rn} be the sequence of the rational functions of best uniform approximation to f on Δ of order (n, n). In the present work,
the convergence of {Rn} in the complex plane is considered for the special caseswhen the poles (or the zeros, respectively) of {Rn} accumulate in the terms of weak convergence of measures to acompact set of zero capacity.
As a consequence, sufficient conditions for the holomorphic and the meromorphic continuability of f are given.
The work is supported by Project 69 with Ministry of Science and Education, Bulgaria. 相似文献
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An ion-exchange procedure is proposed for determination of Pt and Pd in environmental samples, using a Dowex 1-X10 anion-exchange resin. Pt and Pd were separated from the matrix elements in the sample by selective retention on the column as anionic chloro complexes and subsequent elution by circulated thiourea at 60 °C. The eluent, containing Pt and Pd was analyzed by inductively coupled plasma (ICP) atomic emission spectrometry (AES). Average recoveries of 98% and detection limit of 15 ng/g for both metals were achieved. Analysis of Pt and Pd concentrations in road dust, sampled from several sites in Germany was performed. The comparison of the obtained data with the concentrations of Pt and Pd in the same samples, determined by ICP-MS showed a very good agreement. 相似文献
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A sequential extraction procedure was used to study the changes in the physicochemical forms of americium (Am), thorium (Th), and uranium (U) in laboratory-contaminated Chernozem soil as a result of sharp variations of the environmental temperature and soil moisture. The influence of freezing and soil drought on the radio-ecological hazard was evaluated three months after radioactive contamination with aqueous solutions of 241Am, 234Th, and U. The subsequent changes in the physicochemical forms of the actinides, caused by sharp increases in the environmental temperature and soil moisture, were examined for one month. The data showed that continuous freezing increased the potentially mobile forms of Am and Th but had the opposite effect on U. Prolonged soil drought did not influence the fractionation of Am and Th but led to the redistribution of U between the carbonates and organic matter and caused its immobilisation. The sharp increase in the temperature of the frozen soil caused the immobilisation of Am and Th and increased the potential mobility of U. The warming and enhanced humidity of the dry soil led to the immobilisation of Am and redistribution of U between the soil phases. 相似文献
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Preparation of Stereoregular Isotactic Poly(mandelic acid) through Organocatalytic Ring‐Opening Polymerization of a Cyclic O‐Carboxyanhydride 下载免费PDF全文
Dr. Antoine Buchard Dr. David R. Carbery Prof. Matthew G. Davidson Dr. Petya K. Ivanova Dr. Ben J. Jeffery Dr. Gabriele I. Kociok‐Köhn Dr. John P. Lowe 《Angewandte Chemie (International ed. in English)》2014,53(50):13858-13861
Poly(mandelic acid) (PMA) is an aryl analogue of poly(lactic acid) (PLA) and a biodegradable analogue of polystyrene. The preparation of stereoregular PMA was realized using a pyridine/mandelic acid adduct (Py?MA) as an organocatalyst for the ring‐opening polymerization (ROP) of the cyclic O‐carboxyanhydride (manOCA). Polymers with a narrow polydispersity index and excellent molecular‐weight control were prepared at ambient temperature. These highly isotactic chiral polymers exhibit an enhancement of the glass‐transition temperature (Tg) of 15 °C compared to the racemic polymer, suggesting potential future application as high‐performance commodity and biomedical materials. 相似文献
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Cabrera R Zhelyazkova P Galvis L Fernandez-Lahore M 《Journal of separation science》2008,31(13):2500-2510
Surface charge, molecular weight, and folding state are known to influence protein chromatographic behaviour onto ion exchangers. Experimentally, information related to such factors can be gathered via 2-DE methods. The application of 2-D PAGE under denaturing/reducing conditions was already shown to reveal separation trends within a large protein population from cell extracts. However, ion-exchange chromatography normally runs under native conditions. A tailored protocol consisting in a first separation based on IEF on Immobiline strips under native conditions followed by a second dimension SDS-PAGE run was adopted. The chromatographic versus electrophoretic separation behaviours of two model proteins, thaumatin (TAU) and BSA, were compared to better understand which proteomic routine would be better suited to anticipate IEX chromatographic separations. It was observed that the information contained in the pI value obtained with the adapted 2-DE protocol showed better correlation with the IEX chromatographic behaviour. On the other hand, chromatographic separations performed in the presence of urea as a denaturant have demonstrated the potential influence of hydrodynamic radius/conformation on protein separation. Moreover, the information provided by such 2-D system correlated well with the chromatographic behaviour of an additional set of pure proteins. An initial prediction of protein ion-exchange chromatographic behaviour could be possible utilizing an experimental approach based on 2-DE running under milder chemical conditions. This technique provides information that more closely resembles the separation behaviour observed with a complex biotechnological feedstock. 相似文献
9.
Maria M. Milanova Petya G. Kovacheva Radina P. Kralchevska Jovo R. Kolev Joana Ts. Zaharieva Dimitar S. Todorovsky 《Central European Journal of Chemistry》2012,10(6):1850-1858
Microcomposites consisting of TiO2 and ThF4 or UO3 (0.5?C2% of the TiO2 mass) are produced by sol-gel synthesis of TiO2 in presence of the respective additives. X-ray diffraction study reveals small effect of the latter on TiO2 phase composition and cell parameters and significant influence on the crystallite size and UV/Vis reflectance spectra. The photocatalytic tests in presence of TiO2-ThF4 microcomposites under UV and solar irradiation show a non-monotonic increase of the Malachite Green degradation rate constant with the increase of ThF4-content. No changes in the photocatalytic activity are observed in the presence of UO3 but the latter composites exhibit activity in darkness. The results are compared with previously reported data on the performance of TiO2-ThO2 photocatalyst with the same radioactivity and suggest that both radioactivity and the chemical nature of the dopants are responsible for the photocatalytic performance of TiO2-based composites containing radioactive substances. 相似文献
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Indicator space configuration for early warning of violent political conflicts by genetic algorithms
Recognition of preconflict situations has a powerful potential for early warning of violent political conflicts. This paper
focuses on the design and application of artificial neural networks as classifiers of preconflict situations. Achieving a
desired level of performance of the neural network relies on the appropriate construction of recognition space (selection
of indicators) and the choice of network architecture. A fast and effective method for the design of reliable neural recognition
systems is described. It is based on genetic algorithm techniques and optimizes both the configuration of input space and
the network parameters. The implementation of the methodology provides for increased performance of the classifier in terms
of accuracy, generalization capacity, computational and data requirements.
This revised version was published online in June 2006 with corrections to the Cover Date. 相似文献