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1.
We give combinatorial proofs that certain families of differences of products of Schur functions are monomial-positive. We
show in addition that such monomial-positivity is to be expected of a large class of generating functions with combinatorial
definitions similar to Schur functions. These generating functions are defined on posets with labelled Hasse diagrams and
include for example generating functions of Stanley's (P,ω)-partitions.
T.L. was supported in part by NSF DMS-0600677. 相似文献
2.
Ivica ?ilovi Dubravka Matkovi‐alogovi Ivan Kos Mladen Biru Milena Jadrijevi‐Mladar Taka
《Acta Crystallographica. Section C, Structural Chemistry》2007,63(1):o45-o47
In the crystal structures of two cyclic trihydroxamic acid derivatives containing the same substructure unit, viz. 1,3,5‐trihydroxy‐1,3,5‐triazinane‐2,4,6‐trione dihydrate, C3H3N3O6·2H2O, (I), and 1,3,5‐benzyloxy‐1,3,5‐triazinane‐2,4,6‐trione, C24H21N3O6, (II), there is no significant difference in the geometric parameters. In (I), there are 11 hydrogen bonds of the O—H⋯O type interconnecting the molecules in a three‐dimensional network, while in (II) there are only two weak C—H⋯O hydrogen bonds. The results of IR spectroscopic analysis are in good agreement with the crystallographic study. 相似文献
3.
4.
Kos V Budic B Hudnik V Lobnik F Zupan M 《Analytical and bioanalytical chemistry》1996,354(5-6):648-652
Plant samples (Plantago lanceolata - narrow leaf plantain and Cichorium endiviae - endive) were collected in the surroundings of heavy metal emission sources and in other less contaminated areas. After digestion in a closed microwave system using HNO(3), the concentrations of Cd, Co, Cr, Cu, Fe, Mn, Mo, Ni, Pb, and Zn were determined using ICP-AES. Detection limits for all the elements of interest are given. Differences in heavy metal uptake rate between both plant species were observed. The uptake is more intensive for endive than for narrow leaf plantain. High concentrations of some heavy metals were determined in the unwashed plant samples as a result of exposure to aerosols. Tukey's statistical test was used to confirm the discrepancy of Cr concentration in plant samples from various areas. Washing the leaves with water was found to remove a large amount of water-soluble aerosols. 相似文献
5.
Abstract— We have shown previously that the viability of E. coli B.U.- and E. coli B. try- could be restored after u.v.-irradiation if post-irradiation incubation took place in the presence of chloramphenicol or in the absence of an essential metabolite. By way of contrast, the viability of the u.v.-irradiated E. coli K.12 meth- decreased rapidly during post-irradiation incubation in the presence of chloramphenicol or in the absence of methionine. During the study of the biosynthesis of nucleic acids and protein in the above strains we made the following observations.
Protein synthesis was permanently inhibited in both amino acid requiring strains during post-irradiation incubation in the absence of the respective essential metabolite. In E. coli B.U.- a slow synthesis of protein could be observed even if post-irradiation incubation took place in the absence of uracil.
DNA synthesis was completely and permanently inhibited in both E. coli B. try- and E. coli K.12 meth- during post-irradiation incubation in the absence of the respective essential amino acid. In E. coli B.U.- , however, DNA synthesis resumed after a prolonged lag even if the bacteria were incubated after u.v.-irradiation in the absence of uracil.
RNA synthesis was completely and permanently inhibited in both E. coli B. mutants, the uracil requiring and the tryptophan requiring, if they were incubated after irradiation in the absence of uracil and tryptophan respectively. In E. coli K.12 meth- a small amount of RNA is synthesized during post-irradiation incubation in the absence of the essential amino acid. 相似文献
Protein synthesis was permanently inhibited in both amino acid requiring strains during post-irradiation incubation in the absence of the respective essential metabolite. In E. coli B.U.
DNA synthesis was completely and permanently inhibited in both E. coli B. try
RNA synthesis was completely and permanently inhibited in both E. coli B. mutants, the uracil requiring and the tryptophan requiring, if they were incubated after irradiation in the absence of uracil and tryptophan respectively. In E. coli K.
6.
Svitlana V. Shishkina Irina S. Konovalova Pavlo V. Trostianko Anna O. Geleverya Sergiy M. Kovalenko Natalya D. Bunyatyan 《Acta Crystallographica. Section C, Structural Chemistry》2019,75(6):822-832
The polymorphic study of 3‐(3‐phenyl‐1H‐1,2,4‐triazol‐5‐yl)‐2H‐1‐benzopyran‐2‐one, C17H11N3O2, was performed due to its potential biological activity and revealed three polymorphic modifications in the triclinic space group P, the monoclinic space group P21 and the orthorhombic space group Pbca. These polymorphs have a one‐column layered type of crystal organization. The strongest interactions between the molecules of the studied structures is stacking between π‐systems, while N—H…N and C—H…O hydrogen bonds link stacked columns forming layers as a secondary basic structural motif. C—H…π hydrogen bonds were observed between neighbouring layers and their role is the least significant in the formation of the crystal structure. Packing differences between the polymorphic modifications are minor and can be identified only using an analysis based on a comparison of the pairwise interaction energies. 相似文献
7.
Two analogues of diphenylethene carrying phenanthrene (1-(9-phenanthryl)-1-phenylethene (PPE)) and anthracene (1-(2-anthryl)-1-phenylethene (APE)) units were used in radical polymerization of styrene (St) and methyl methacrylate (MMA) at 80 °C using AIBN as initiator. Because of the nature of the polymerization, the resulting polymers possess the corresponding chromophoric groups. Using the methodology of a DPE system, these labelled polymers were further used for the synthesis of block copolymers. In this way poly(methyl methacrylate)-b-poly(styrene) and poly(methyl methacrylate)-b-poly(acrylonitrile) with molar masses of 60,000-90,000 g/mol were synthesized. Incorporation of the chromophoric groups into both homo- and block copolymers was confirmed by spectral measurements. 相似文献
8.
Summary The virial theorem for a molecule in the relativistic clamped-nuclei approximation is derived. The individual energy contributionsA (momentum energy),B (mass energy),T=A+B (kinetic energy) andV (potential energy) are expressed in terms ofE, E/R (derivate w.r.t. the nuclear coordinates) and the relativistic correction E/2 (derivative w.r.t. Sommerfield's fine-structure constant ). IfE and E/R are known as functions of , then all individual energy terms are also known as functions of . As an example, numerical results for H
2
+
are presented. The relativistic and nonrelativistic potential energy curves and the paradoxical behavior of their different contributions are analyzed and interpreted in both the largeR and shortR ranges.Dedicated to Professor W. Kutzelnigg on the occasion of his 60th birthday 相似文献
9.
Tanja Brezo-Borjan Zorica Stojanovi Zvonimir Suturovi Jovana Kos Sneana Kravi Ana urovi 《Monatshefte für Chemie / Chemical Monthly》2020,151(3):285-291
A new electroanalytical method for vitamin B1 determination, based on adsorptive chronopotentiometric stripping analysis and non-specific adsorption onto mercury film electrode, was developed and validated. Stripping chronopotentiograms showed a single well-defined oxidation wave corresponding to vitamin B1 at about − 0.43 V in citrate buffer pH 6.0. The most important experimental factors affecting the monitored electroanalytical response of vitamin B1 were investigated and optimised. Under the optimal experimental conditions, linear response of vitamin B1 was obtained in the concentration range of 5–50 mg dm−3, with the achieved limit of detection of 1.64 mg dm−3, and the limit of quantitation of 4.97 mg dm−3. A mean recovery of 97.1% and relative standard deviations of 3.75% were achieved. The developed electrochemical procedure was successfully applied for the determination of vitamin B1 in pharmaceutical products. The results of the proposed method were in good agreement with those obtained by parallel HPLC analyses, confirming an accuracy of the developed method. 相似文献
10.
Svitlana V. Shishkina Igor V. Ukrainets Olga V. Vashchenko Natali I. Voloshchuk Pavlo S. Bondarenko Lidiya A. Petrushova Galina Sim 《Acta Crystallographica. Section C, Structural Chemistry》2020,76(1):69-74
The title benzothiazine‐3‐carboxamide, C17H16N2O4S, crystallized in two enantiomorphic crystal forms with the space groups P32 and P31 despite the absence of a classic stereogenic atom. The molecular structures are mirror images of each other. Only one sulfonyl O atom takes part in intramolecular hydrogen bonding as a proton acceptor and this atom is different in the two enantiomorphic structures. As a result, the S atom becomes a pseudo‐stereogenic centre. This fact is worth taking into account due to the different biological activities of the enantiomorphic forms. One form possesses a high analgesic activity, while the other form revealed a high anti‐inflammatory activity. 相似文献