排序方式: 共有37条查询结果,搜索用时 15 毫秒
1.
The K-shell X-ray fluorescence cross sections are determined experimentally for 10 elements such as Pb, Hg, Ir, W, Lu, Tm,
Dy, Tb, Gd and Nd at excitation energy of 661.6 keV associated with γ-rays of 137Cs radioisotope. The technique employed involves the measurement of total intensity of fluorescent K X-rays that follow the
photoeffect absorption of a known flux of γ-rays using a well type Nal(Tl) detector. The obtained results are compared with the available theoretical values and other
measured values. 相似文献
2.
Synthesis of oligosaccharides catalyzed by thermostable β-glucosidase fromPyrococcus furiosus 总被引:3,自引:0,他引:3
M. A. Boon J. van der Oost W. M. de Vos A. E. M. Janssen K. van ’t Riet 《Applied biochemistry and biotechnology》1998,73(2-3):269-278
Focusing on CO2 fixation, photoautotrophic cultivation of the red algaPorphyridium cruentum was investigated by means of a batch culture under a 5% CO2-enriched atmosphere. The algal growth kinetics was successfully described with a logistic model, and simulation of a continuous
culture under the optimum growth conditions (30°C, 12 klux and 1.18 g-cells/L) showed that the algal CO2-fixation activity could reach 0.66 g-CO2/(L X d). Under the same growth conditions, eicosapentaenoic acid (20:5 n-3, EPA) and arachidonic acid (20:4 n-6, ARA) yields
were similarly calculated to be 3.6 mg-EPA/(L X d) and 6.5 mg-ARA/(L X d), respectively. 相似文献
3.
Christian Knittl-Frank Iakovos Saridakis Thomas Stephens Dr. Rafael Gomes Dr. James Neuhaus Dr. Antonio Misale Dr. Rik Oost Dr. Alberto Oppedisano Prof. Dr. Nuno Maulide 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(48):10972-10975
The metal-promoted nucleophilic addition of sulfur ylides to π-systems is a well-established reactivity. However, the driving force of such transformations, elimination of a sulfide moiety, entails stoichiometric byproducts making them unfavorable in terms of atom economy. In this work, a new take on sulfur ylide chemistry is reported, an atom-economical gold(I)-catalyzed synthesis of dihydrobenzo[b]thiepines. The reaction proceeds under mild conditions at room temperature. 相似文献
4.
Yu L Oost TK Schkeryantz JM Yang J Janowick D Fesik SW 《Journal of the American Chemical Society》2003,125(15):4444-4450
A method is described for the NMR-based screening for the discovery of aminoglycoside mimetics that bind to Escherichia coli A-site RNA. Although aminoglycosides are clinically useful, they exhibit high nephrotoxicity and ototoxicity, and their overuse has led to the development of resistance to important microbial pathogens. To identify a new series of aminoglycoside mimetics that could potentially overcome the problems associated with toxicities and resistance development observed with the aminoglycosides, we have prepared large quantities of E. coli 16 S A-site RNA and conducted an NMR-based screening of our compound library in search for small-molecule RNA binders against this RNA target. From these studies, several classes of compounds were identified as initial hits with binding affinities in the range of 70 microM to 3 mM. Lead optimization through synthetic modifications of these initial hits led to the discovery of several small-molecule aminoglycoside mimetics that are structurally very different from the known aminoglycosides. Structural models of the A-site RNA/ligand complexes were prepared and compared to the three-dimensional structures of the RNA/aminoglycoside complexes. 相似文献
5.
T. Loarer J. Gunn J. L. Lachambre E. Gravier C. Boucher K. H. Finken M. Lehnen G. Mank S. Jachmich H. Van Goubergen G. Van Oost 《Czechoslovak Journal of Physics》2001,51(10):1021-1031
Particle collection by the ALT-II belt limiter in the TEXTOR-94 tokamak is exclusively limited to the parallel outflux because the scoop walls that are oriented parallel to the field lines obstruct the poloidal E×B mass flow. With normal B
tor direction (E×B towards the scoops), a threefold decrease of plenum pressure is measured during negative biasing, while with reversed B
tor (E×B away from the scoops), a 60% pressure increase is observed. This behaviour is exactly opposite to that observed in X-point divertors. A simple fluid model explains this apparent contradiction, and gives good quantitative agreement with measurements of the parallel Mach number in the SOL. The essential physics is governed by the Bohm-Chodura criterion. 相似文献
6.
Guido Van Oost James P. Gunn Alexander Melnikov Jan Stöckel Michael Tendler 《Czechoslovak Journal of Physics》2001,51(10):957-975
Radial electric fields (E
r) and their role in the establishment of edge transport barriers and improved confinement have been studied in the tokamaks TEXTOR-94 and CASTOR, where E
r is externally applied to the plasma in a controlled way using a biased electrode, as well as in the tokamak T-10 where an edge transport barrier (H-mode) is obtained during electron-cyclotron resonance heating (ECRH) of the plasma.The physics of radial currents was studied and the radial conductivity in the edge of TEXTOR-94 (R = 1.75 m, a = 0.46 m) was found to be dominated by recycling (ion-neutral collisions) at the last closed flux surface (LCFS) and by parallel viscosity inside the LCFS. From a performance point of view (edge engineering), such electrode biasing was shown to induce a particle transport barrier, a reduction of particle transport, and a concomitant increase in energy confinement. An H-mode-like behaviour can be induced both with positive and negative electric fields. Positive as well as negative electric fields were shown to strongly affect the exhaust of hydrogen, helium, and impurities, not only in the H-mode-like regime.The impact of sheared radial electric fields on turbulent structures and flows at the plasma edge is investigated on the CASTOR tokamak (R = 0.4 m, a = 0.085 m). A non-intrusive biasing scheme that we call "separatrix biasing" is applied whereby the electrode is located in the scrape-off layer (SOL) with its tip just touching the LCFS. There is evidence of strongly sheared radial electric field and E×B flow, resulting in the formation of a transport barrier at the separatrix. Advanced probe diagnosis of the edge region has shown that the E×B shear rate that arises during separatrix biasing is larger than for standard edge plasma biasing. The plasma flows, especially the poloidal E×B drift velocity, are strongly modified in the sheared region, reaching Mach numbers as high as half the sound speed. The corresponding shear rates ( 5×106 s-1) derived from both the flow and electric field profiles are in excellent agreement and are at least an order of magnitude higher than the growth rate of unstable turbulent modes as estimated from fluctuation measurements.During ECRH in the tokamak T-10 (R = 1.5 m, a = 0.3 m), a regime of improved confinement is obtained with features resembling those in the H-mode in other tokamaks. Using a heavy ion beam probe, a narrow potential well is observed near the limiter together with the typical features of the L-H transition. The time evolution of the plasma profiles during L-H and H-L transitions is clearly correlated with that of the density profile and the formation of a transport barrier near the limiter. The edge electric field is initially positive after the onset of ECRH. It changes its sign during the L-H transition and grows till a steady condition is reached. Similar to the biasing experiments in TEXTOR-94 and CASTOR, the experimentally observed transport barrier is a barrier for particles. 相似文献
7.
G. De Mey G. Verhenne K. Van Oost J. Landuyt 《Applied Physics A: Materials Science & Processing》1987,43(2):93-95
Non-uniform planar resistors are modelled by a small stochastic conductivity pattern superimposed on the constant mean conductivity. At first a theoretical analysis is presented giving the mean square deviation of the resistor current for a given applied voltage. The same problem is then simulated by Monte-Carlo experiments and a good agreement is observed. 相似文献
8.
A. Litnovsky C. Boucher P. Sicard G. Lebrun J.-P. St-Germain G. Van Oost 《Czechoslovak Journal of Physics》2003,53(10):903-910
Electrical probes are an excellent tool for local measurements of basic plasma parameters, fluctuations and plasma flow studies. However, the application of a probe diagnostics is usually accompanied by theoretical restrictions, practical limitations and problems. In this paper we describe the new probe system recently developed for the TOMAS toroidal device (Forschungszentrum Jülich, Germany). This system comprises multi-collector Gundestrup probe for flow measurements and Langmuir probe for plasma characterization. During development of such a system, several physical and technical issues, which are common for probe applications, were solved or essentially suppressed. 相似文献
9.
P. Devynck J. Stöckel J. Adámek I. Ďuran M. Hron G. Van Oost 《Czechoslovak Journal of Physics》2003,53(10):853-862
The poloidal structure of the turbulence and the turbulent particle flux in the scrape-off layer (SOL) of the CASTOR tokamak are analysed by means of a poloidal ring of 124 probes distributed uniformly along the whole poloidal circumference. Fluctuation measurements are performed in standard ohmic regime as well as in discharges when a biased electrode is inserted either into the SOL or deeper into the confinement region. It is found that in both cases a strongly sheared radial electric field is created in the SOL, which de-correlates the density and radial velocity fluctuations and reduces their levels. Consequently, the turbulent flux is reduced. However, no phase shift is observed between density and radial velocity fluctuations. When the electrode is localized in the confinement region, all the above effects are less pronounced because of a smaller shear. In addition, the increase of the E × B velocity at biasing leads in both cases to the formation of oscillations in the temporal correlation function. These oscillations are specifically associated to the poloidal mode (m = q), which is created for a limited time and rotates poloidally. This mode does not modify the phase between density and radial velocity fluctuations and has no further effect on the turbulent flux. 相似文献
10.