Condensation of all-cis-tetraphenylcyclotetrasiloxanetetraol in ammonia: new method for preparation of ladder-like polyphenylsilsesquioxanes

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Relative kinetic stability towards redox decomposition of cerium(IV) complexes with some organic compounds

Monatshefte für Chemie - Chemical Monthly - A comparative analysis is performed on the stability constants $${\upbeta }_{1yn}$$ and intramolecular redox decomposition rate constants $$k_{n\; =...     

Electrochemical reduction of monothiobenzils in the presence of aroyl chlorides. First synthesis of (Z)-α-benzoyloxy-β-benzoylthiostilbenes

The first method for the synthesis of the title compounds has been established involving a stereoselective electrochemical diacylation process. The cathodic reductions of monothiobenzils in an aprotic medium, under constant potential, in the presence of twofold molecular amounts of aroyl chlorides provide previously unknown (Z)-α-benzoyloxy-β-benzoythiostilbenes in high to quantitative yields.     

Spin and quark states in the probability representation of quantum mechanics

A short review of the general principles of constructing tomograms of spin and quark states is presented.     

A sequential injection system for the spectrophotometric determination of calcium, magnesium and alkalinity in water samples.

A sequential injection methodology for the spectrophotometric determination of calcium, magnesium and alkalinity in water samples is proposed. A single manifold is used for the determination of the three analytes, and the same protocol sequence allows the sequential determination of calcium and magnesium (the sum corresponds to the water hardness). The determination of both metals is based on their reaction with cresolphtalein complexone; mutual interference is minimized by using 8-hydroxyquinoline for the determination of calcium and ethylene glycol-bis(beta-aminoethyl ether)-N,N,N',N'-tetraacetic acid (EGTA) for the determination of magnesium. Alkalinity determination is based on a reaction with acetic acid, and corresponding color change of Bromcresol Green. Working ranges of 0.5 - 5 mg dm(-3) for Ca, 0.5 - 10 mg dm(-3) for Mg, and 10 - 100 mg HCO3- dm(-3), for alkalinity have been achieved. The results for water samples were comparable to those of the reference methods and to a certified reference water sample. RSDs lower than 5% were obtained, a low reagent consumption and a reduced volume of effluent have been accomplished. The determination rate for calcium and magnesium is 80 h(-1), corresponding to 40 h(-1) per element, while 65 determinations of alkalinity per hour could be carried out.     

Astrogeometry: Toward mathematical foundations

Inimage processing (e.g., inastronomy), the desired black-and-white image is, from the mathematical viewpoint, aset. Hence, to process images, we need to process sets. To define a generic set, we need infinitely many parameters; therefore, if we want to represent and process sets in the computer, we must restrict ourselves to finite-parameter families of sets that will be used to approximate the desired sets. The wrong choice of a family can lead to longer computations and worse approximation. Hence, it is desirable to find the family that it isthe best in some reasonable sense. In this paper, we show how the problems of choosing the optimal family of sets can be formalized and solved. As a result of the described general methodology, forastronomical images, we get exactly the geometric shapes that have been empirically used by astronomers and astrophysicists; thus, we have atheoretical explanation for these shapes.     

Prediction problem in quantum mechanics is intractable (NP-Hard)

It is proved that both the prediction problem and the problem of reconstructing the state from the observations in quantum mechanics are NP-hard.     

Anomalous capacitance of quantum well double-barrier diodes

The S-parameters of several different quantum well double barrier diodes have been measured. A technique has been developed for measuring whisker contacted diodes with and HP 8510B automatic network analyzer. Special coaxial mounts using K-connectors were designed to enable measurements up to 20 GHz. The voltage-dependent conductance and capacitance were derived from the measured reflection coefficient of each device. The C/V characteristics were observed to exhibit an anomalous increase at voltages corresponding the the negative differential resistance region (NDR). These are the first reported S-parameter measurements in the negative differential resistance region of quantum well double barrier diodes. A theory is presented that explains, in part, the observed results.