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1.
Nesrine Mechi Ismahen Ben Khemis Houcine Dhaou Slim Zghal Abdelmottaleb Ben Lamine 《Chinese Journal of Physics (Taipei)》2018,56(2):449-467
The Mg50Ni45Cr5 alloy for hydrogen storage is prepared by mechanical alloying. First, using the X-ray diffraction (XRD) and the scanning electron microscopy (SEM) we examine the morphology and the structure of the substrate. The obtained results highlight the effectiveness of this alloy in loading hydrogen as it is a nanocrystalline and a ductile one. Second, we attempt to justify these expectations using the statistical physic, precisely the model monolayer with two levels of energy, in modeling a hydrogen absorption and desorption isotherms on Mg50Ni45Cr5 alloy at four temperatures T?=?275?K, T?=?300?K, T?=?325?K and T?=?350?K. The model has six physicochemical parameters deduced from the fitting of the isotherms, they are divided by two categories of steric and energetic parameters. Thanks to these parameters we compare the absorption and desorption processes, in order to highlight the hysteresis phenomenon encountered during the hydrogen sorption. 相似文献
2.
Ines Belhaj-Ben Romdhane Zamen Ben Romdhane Maha Bouzid Ali Gargouri Hafedh Belghith 《Applied biochemistry and biotechnology》2013,171(8):1986-2002
Waste frying oil, which not only harms people’s health but also causes environmental pollution, can be a good alternative to partially substitute petroleum diesel through transesterification reaction. This oil contained 8.8 % of free fatty acids, which cause a problem in a base-catalyzed process. In this study, synthesis of biodiesel was efficiently catalyzed by the covalently immobilized Talaromyces thermophilus lipase and allowed bioconversion yield up to 92 % after 24 h of reaction time. The optimal molar ratio was four to six parts of methanol to one part of oil with a biocatalyst loaded of 25 wt.% of oil. Further, experiments revealed that T. thermophilus lipase, immobilized by a multipoint covalent liaison onto activated chitosan via a short spacer (glutaraldehyde), was sufficiently tolerant to methanol. In fact, using the stepwise addition of methanol, no significant difference was observed from the one-step whole addition at the start of reaction. The batch biodiesel synthesis was performed in a fixed bed reactor with a lipase loaded of 10 g. The bioconversion yield of 98 % was attained after a 5-h reaction time. The bioreactor was operated successfully for almost 150 h without any changes in the initial conversion yield. Most of the chemical and physical properties of the produced biodiesel meet the European and USA standard specifications of biodiesel fuels. 相似文献
3.
Bouhali Nesrine Azzam-Laouir Dalila Monteiro Marques Manuel D. P. 《Journal of Optimization Theory and Applications》2022,194(1):59-91
Journal of Optimization Theory and Applications - We consider a control problem in a finite-dimensional setting, which consists in finding a minimizer for a standard functional defined by way of... 相似文献
4.
Nesrine Fterich 《Applications of Mathematics》2010,55(1):1-46
The article deals with a nonlinear generalized Ginzburg-Landau (Allen-Cahn) system of PDEs accounting for nonisothermal phase
transition phenomena which was recently derived by A. Miranville and G. Schimperna: Nonisothermal phase separation based on
a microforce balance, Discrete Contin. Dyn. Syst., Ser. B, 5 (2005), 753–768. The existence of solutions to a related Neumann-Robin problem is established in an N ⩽ 3- dimensional space
setting. A fixed point procedure guarantees the existence of solutions locally in time. Next, Sobolev embeddings, interpolation
inequalities, Moser iterations estimates and results on renormalized solutions for a parabolic equation with L
1 data are used to handle a suitable a priori estimate which allows to extend our local solutions to the whole time interval.
The uniqueness result is justified by proper contracting estimates. 相似文献
5.
Hafedh Hajlaoui Soumaya Arraouadi Emira Noumi Kaïss Aouadi Mohd Adnan Mushtaq Ahmad Khan Adel Kadri Mejdi Snoussi 《Molecules (Basel, Switzerland)》2021,26(12)
Herbs and spices have been used since antiquity for their nutritional and health properties, as well as in traditional remedies for the prevention and treatment of many diseases. Therefore, this study aims to perform a chemical analysis of both essential oils (EOs) from the seeds of Carum carvi (C. carvi) and Coriandrum sativum (C. sativum) and evaluate their antioxidant, antimicrobial, anti-acetylcholinesterase, and antidiabetic activities alone and in combination. Results showed that the EOs mainly constitute monoterpenes with γ-terpinene (31.03%), β-pinene (18.77%), p-cymene (17.16%), and carvone (12.20%) being the major components present in C. carvi EO and linalool (76.41%), γ-terpinene (5.35%), and α-pinene (4.44%) in C. sativum EO. In comparison to standards, statistical analysis revealed that C. carvi EO showed high and significantly different (p < 0.05) antioxidant activity than C. sativum EO, but lower than the mixture. Moreover, the mixture exhibited two-times greater ferric ion reducing antioxidant power (FRAP) (IC50 = 11.33 ± 1.53 mg/mL) and equipotent chelating power (IC50 = 31.33 ± 0.47 mg/mL) than the corresponding references, and also potent activity against 2,2-diphenyl-1-picrylhydrazyl (DPPH) (IC50 = 19.00 ± 1.00 mg/mL), β-carotene (IC50 = 11.16 ± 0.84 mg/mL), and superoxide anion (IC50 = 10.33 ± 0.58 mg/mL) assays. Antimicrobial data revealed that single and mixture EOs were active against a panel of pathogenic microorganisms, and the mixture had the ability to kill more bacterial strains than each EO alone. Additionally, the anti-acetylcholinesterase and α-glucosidase inhibitory effect have been studied for the first time, highlighting the high inhibition effect of AChE by C. carvi (IC50 = 0.82 ± 0.05 mg/mL), and especially by C. sativum (IC50 = 0.68 ± 0.03 mg/mL), as well as the mixture (IC50 = 0.63 ± 0.02 mg/mL) compared to the reference drug, which are insignificantly different (p > 0.05). A high and equipotent antidiabetic activity was observed for the mixture (IC50 = 0.75 ± 0.15 mg/mL) when compared to the standard drug, acarbose, which is about nine times higher than each EO alone. Furthermore, pharmacokinetic analysis provides some useful insights into designing new drugs with favorable drug likeness and safety profiles based on a C. carvi and C. sativum EO mixture. In summary, the results of this study revealed that the combination of these EOs may be recommended for further food, therapeutic, and pharmaceutical applications, and can be utilized as medicine to inhibit several diseases. 相似文献
6.
Zied Zarai Houda Gharsallah Adnane Hammami Hafedh Mejdoub Sofiane Bezzine Youssef-Talel Gargouri 《Applied biochemistry and biotechnology》2012,168(4):877-886
In order to report pharmacological characterization of marine snail (Hexaplex trunculus) hepatopancreatic phospholipase A2 (mSDPLA2), we have talked for the first time the antimicrobial activity against different pathogenic bacterial strains, anti-chlamydial activity as well as its cytotoxic activity against McCoy cell lines. mSDPLA2, showed a high level of activity towards Gram-positive bacteria as Staphylococcus aureus and Staphylococcus epidermidis. Whereas Gram-negative bacteria, unfortunately, exhibited a higher resistance, mSDPLA2 was also found to have a strong cytotoxic activity, causing significant morphological alterations of the McCoy cell lines surfaces and to be a hinder to the proliferation. Moreover, mSDPLA2 proved to have a very potent anti-chlamydial activity. Over 95?% inhibition of chlamydial inclusions were obtained at a concentration of 10???g/ml of mSDPLA2 after 24?h postinfection. Interestingly, at a concentration of 10???g/ml of mSDPLA2, the proliferation of McCoy cells was not affected. Approximately 50?% inhibition of cell growth was obtained with a concentration of 37???g/mL of mSDPLA2. mSDPLA2 could be considered as an excellent candidate for the development of a new anti-infective agent. This enzyme showed significant antimicrobial activities. 相似文献
7.
Genetic diversity and haplotype structure of 21 Y‐STRs,including nine noncore loci,in South Tunisian Population: Forensic relevance 下载免费PDF全文
Faten Makki‐Rmida Arwa Kammoun Nadia Mahfoudh Adnene Ayadi Abdullah Ahmed Gibriel Bakhta Mallek Leila Maalej Zouheir Hammami Samir Maatoug Hafedh Makni Saber Masmoudi 《Electrophoresis》2015,36(23):2908-2913
Y chromosome STRs (Y‐STRs) are being used frequently in forensic laboratories. Previous studies of Y‐STR polymorphisms in different groups of the Tunisian population identified low levels of diversity and discrimination capacity (DC) using various commercial marker sets. This definitely limits the use of such systems for Y‐STRs genotyping in Tunisia. In our investigation on South Tunisia, 200 unrelated males were typed for the 12 conventional Y‐STRs included in the PowerPlex® Y System. Additional set of nine noncore Y‐STRs including DYS446, DYS456, DYS458, DYS388, DYS444, DYS445, DYS449, DYS710, and DYS464 markers were genotyped and evaluated for their potential in improving DC. Allele frequency, gene diversity, haplotype diversity (HD), and DC calculation revealed that DYS464 was the most diverse marker followed by DYS710 and DYS449 markers. The standard panel of 12 Y‐STRs (DC = 80.5%) and the nine markers were combined to obtain DC of 99%. Among the 198 different haplotypes observed, 196 haplotypes were unique (HD = 99.999). Out of the nine noncore set, six Y‐STRs (DYS458, DYS456, DYS449, DYS710, DYS444, and DYS464) had the greatest impact on enhancing DC. Our data provided putative Y‐STRs combination to be used for genetic and forensic applications. 相似文献
8.
Hafedh Ben Belgacem Sergio Conti Antonio DeSimone Stefan Müller 《Archive for Rational Mechanics and Analysis》2002,164(1):1-37
We derive an optimal scaling law for the energy of thin elastic films under isotropic compression, starting from three-dimensional nonlinear elasticity. As a consequence we show that any deformation with optimal energy scaling must exhibit fine-scale oscillations along the boundary, which coarsen in the interior. This agrees with experimental observations of folds which refine as they approach the boundary. We show that both for three-dimensional elasticity and for the geometrically nonlinear Föppl-von Kármán plate theory the energy of a compressed film scales quadratically in the film thickness. This is intermediate between the linear scaling of membrane theories which describe film stretching, and the cubic scaling of bending theories which describe unstretched plates, and indicates that the regime we are probing is characterized by the interplay of stretching and bending energies. Blistering of compressed thin films has previously been analyzed using the Föppl-von Kármán theory of plates linearized in the in-plane displacements, or with the scalar eikonal functional where in-plane displacements are completely neglected. The predictions of the linearized plate theory agree with our result, but the scalar approximation yields a different scaling. 相似文献
9.
Kamoun F Fguira IB Hassen NB Mejdoub H Lereclus D Jaoua S 《Applied biochemistry and biotechnology》2011,165(1):300-314
This study reports on the identification, characterization and purification of a new bacteriocin, named Bacthuricin F103,
from a Bacillus thuringiensis strain BUPM103. Bacthuricin F103 production began in the early exponential phase and reached a maximum in the middle of the
same phase. Two chromatographic methods based on high performance liquid chromatography and fast protein liquid chromatography
systems were used to purify Bacthuricin F103. Sodium dodecyl sulphate-polyacrylamide gel electrophoresis revealed that this
bacteriocin had a molecular weight of approximately 11 kDa. It also showed a wide range of thermostability of up to 80 °C
for 60 min and a broad spectrum of antimicrobial activity over a pH range of 3.0–10.0. This bacteriocin was noted, and for
the first time, to exhibit potent antimicrobial activity against Agrobacterium subsp. strains, the major causal agents of crown gall disease in tomato and vineyard crops, and against several challenging
organisms in food, such as Listeria monocytogenes and Bacillus cereus. Complete killing with immediate impact on cells was observed within a short period of time. The sequence obtained for Bacthuricin
F103 by direct N-terminal sequencing shared considerable homology with hemolysin. Bacthuricin F103 was noted to act through
the depletion of intracellular ions, which suggest that the cell membrane was a possible target to Bacthuricin F103. 相似文献
10.
Ammar S Mahjoub MA Charfi N Skandarani I Chekir-Ghedira L Mighri Z 《Chemical & pharmaceutical bulletin》2007,55(3):385-388
A new skeleton of an O-heteroside natural substance named zinolol, the first representative of a new class of aminated hydroxyhydroquinone, has been isolated from the whole plant Anagallis monelli. Its structure has been established by one and two dimensional NMR spectroscopic procedures. Antioxidant, mutagenic, antimutagenic activities were realised and positive results were recorded. 相似文献