全文获取类型
收费全文 | 525篇 |
免费 | 28篇 |
国内免费 | 1篇 |
专业分类
化学 | 384篇 |
晶体学 | 2篇 |
力学 | 18篇 |
数学 | 88篇 |
物理学 | 62篇 |
出版年
2023年 | 3篇 |
2022年 | 8篇 |
2021年 | 21篇 |
2020年 | 26篇 |
2019年 | 18篇 |
2018年 | 18篇 |
2017年 | 10篇 |
2016年 | 22篇 |
2015年 | 22篇 |
2014年 | 15篇 |
2013年 | 36篇 |
2012年 | 27篇 |
2011年 | 35篇 |
2010年 | 25篇 |
2009年 | 26篇 |
2008年 | 31篇 |
2007年 | 33篇 |
2006年 | 17篇 |
2005年 | 22篇 |
2004年 | 28篇 |
2003年 | 21篇 |
2002年 | 24篇 |
2001年 | 4篇 |
2000年 | 9篇 |
1999年 | 3篇 |
1998年 | 5篇 |
1997年 | 3篇 |
1996年 | 4篇 |
1995年 | 6篇 |
1994年 | 2篇 |
1993年 | 4篇 |
1992年 | 3篇 |
1991年 | 3篇 |
1990年 | 1篇 |
1989年 | 3篇 |
1988年 | 5篇 |
1987年 | 1篇 |
1986年 | 5篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1981年 | 1篇 |
1975年 | 2篇 |
排序方式: 共有554条查询结果,搜索用时 46 毫秒
1.
Chromatographia - The present work deals with the optimization, validation and application of a versatile HPLC–DAD method for concurrent estimation of nine antimicrobials and proton pump... 相似文献
2.
3.
Control over Nanostructures and Associated Mesomorphic Properties of Doped Self‐Assembled Triarylamine Liquid Crystals 下载免费PDF全文
Dr. Yuya Domoto Dr. Eric Busseron Prof. Dr. Mounir Maaloum Dr. Emilie Moulin Prof. Dr. Nicolas Giuseppone 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(5):1938-1948
We have synthesized a series of triarylamine‐cored molecules equipped with an adjacent amide moiety and dendritic peripheral tails in a variety of modes. We show by 1H NMR and UV/Vis spectroscopy that their supramolecular self‐assembly can be promoted in solution upon light stimulation and radical initiation. In addition, we have probed their molecular arrangements and mesomorphic properties in the bulk by integrated studies on their film state by using differential scanning calorimetry (DSC), variable‐temperature polarizing optical microscopy (VT‐POM), variable‐temperature X‐ray diffraction (VT‐XRD), and atomic force microscopy (AFM). Differences in the number and the disposition of the peripheral tails significantly affect their mesomorphic properties associated with their lamellar‐ or columnar‐packed nanostructures, which are based on segregated stacks of the triphenylamine cores and the lipophilic/lipophobic periphery. Such structural tuning is of interest for implementation of these soft self‐assemblies as electroactive materials from solution to mesophases. 相似文献
4.
A tunable microwave notch absorber filter 总被引:3,自引:0,他引:3
Mounir Laroussi 《International Journal of Infrared and Millimeter Waves》1992,13(10):1557-1569
A magnetized plasma column is found to be a notch absorber of microwave radiation propagating in the extraordinary mode. Based on this fact, a compact tunable microwave filter is designed and tested successfully. The center frequency of the absorbed band can be varied by adjusting the background magnetic field stength. The 3dB bandwidth and amount of attenuation are functions of the plasma current. These characteristics offer a great tunability, often sought after in microwave devices. This filter can find applications in microwave measurement systems where filtering of unwanted harmonics and spurious signals can directly affect the accuracy and resolution of the measurements. 相似文献
5.
[reaction: see text] A highly diastereoselective acetate aldol reaction that uses a tert-leucine-derived thiazolidinethione auxiliary and dichlorophenylborane has been developed. The reaction proceeds in excellent yields and with high diastereoselectivities (drs range from 9.5:1 to >100:1). 相似文献
6.
Kamal Y. El-Baradie Tarek M. Fayed Ibrahim M. El-Mehasseb 《Monatshefte für Chemie / Chemical Monthly》2005,96(3):1157-1169
Mono- and homobinuclear complexes of Mn(II), Co(II), Ni(II), and Cu(II) with phthalein purple are prepared and characterized by elemental analysis, thermal studies (TGA and DTA), spectral methods (IR, UV/Vis, and ESR), magnetic moment determination, and electrochemical reduction (DC polarography at DME and CV at HMDE). Thermal degradation of the complexes was studied by TGA and DTA where some thermodynamic parameters were determined. The mode of bonding and geometry of the complexes were determined from the spectral studies. Magnetic moment values showed some antiferromagnetism in the homobinuclear complexes. The reduction of the metal ions proceeds to the metallic state along an irreversible process. 相似文献
7.
Mohamed El Guendouzi Abderrahim Dinane Abdelfetah Mounir 《Journal of solution chemistry》2002,31(2):119-129
The mixed aqueous electrolyte system of ammonium and lithium chlorides has been studied by the hygrometric method at 25°C. The relative humidities of this system are measured at total molalities from 0.3 to 6 mol-kg– 1 for different ionic-strength fractions y of NH4Cl with y = 0.33, 0.50, and 0.67. The data obtained allow the deduction of new water activities and osmotic coefficients. The experimental results are compared with the predictions of the ECA (extended composed additivity) law proposed in our previous work. The Zdanovskii–Stokes–Robinson (ZSR), the Robinson–Stokes (RS), Reilly–Wood–Robinson (RWR), the Pitzer, and the Lietzke–Stoughton (LS II) models are also compared with our results. Predictions made using these models are, in general, consistent with our results. From these measurements, new Pitzer mixing ionic parameters are determined and used to predict the solute activity coefficients in the mixture for different ionic-strength fractions. 相似文献
8.
Issa RM Fayed TA Awad MK El-Kony SM 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2005,62(4-5):980-986
The absorption spectra of mono- and bis-azo-derivatives obtained by coupling the diazonium salts of aromatic amines and 2,7-dihydroxynaphthalene have been studied in six organic solvents. The different absorption bands have been assigned and the effect of solvents on the charge transfer band is also discussed. The diagnostic IR spectral bands and 1H NMR signals are assigned and discussed in relation to molecular structure. Also, semi-empirical molecular orbital calculations using the atom superposition and electron delocalization molecular orbital (ASED-MO) theory have been performed to investigate the molecular and electronic structures of these compounds. According to these calculations, an intramolecular hydrogen bonding is essential for stabilization of such molecules. 相似文献
9.
Mounir Laroussi 《International Journal of Infrared and Millimeter Waves》1996,17(12):2215-2232
In this paper, the total scattering and back-scattering cross-sections (respectively represented by and b) of an air plasma layer surrounding a conducting cylinder are studied. The plasma layer can be turned ON and OFF to allow for a comparison between the scattering cross-section of the bare cylinder and the plasma covered cylinder. The plasma layer is generated at atmospheric pressure, which results in a very highly collisional case. The scattered fields are calculated using a cylindrical expansion, with coefficients satisfying the appropriate boundary conditions, and which are a function of the refractive index of the air plasma. The results of our study are presented as plots of the total scattering cross-section, , and back-scattering cross-section, b, versus frequency. The scattering cross-section gives an average characteristic of the scattering process from obstacles. Once the scattering cross-section is known, the actual scattered energy per unit length per second can be calculated by multiplying by the incident energy per unit area per second. 相似文献
10.
Ahmed A. El-Asmy Yehia M. Shaibi Abdallah S. Babaqi Mohamed Mounir Salah A. Ashour 《Transition Metal Chemistry》1988,13(5):332-335
Summary The interaction of 1-benzoin-4-phenylthiosemicarbazone (H2 BPS) with some transition metal ions has been investigated. The ligand can function as a tridentate chelating agent, giving M(HBPS)2 and M(BPS). Potentiometric studies proved that the mechanism of chelation is based on hydrogen ion liberation. Spectral studies in solution show that the ligand could be used for the microdetermination of CuIIions. On the basis of magnetic and spectral data, an octahedral structure is proposed for the CoII and NiII complexes and a square-planar structure for the CuII complex. The corrosion inhibition of aluminium in Cl3CCO2H using H2BPS is studied. The electrical conductivity of H2BPS and of its complexes have been measured. The ligand shows an activation energy in the range of semiconducting materials. The antimicrobial activity of all compounds has also been demonstrated. 相似文献