全文获取类型
收费全文 | 857篇 |
免费 | 11篇 |
国内免费 | 1篇 |
专业分类
化学 | 487篇 |
晶体学 | 5篇 |
力学 | 26篇 |
数学 | 69篇 |
物理学 | 282篇 |
出版年
2022年 | 9篇 |
2021年 | 12篇 |
2020年 | 16篇 |
2019年 | 16篇 |
2018年 | 16篇 |
2017年 | 9篇 |
2016年 | 13篇 |
2015年 | 9篇 |
2014年 | 34篇 |
2013年 | 66篇 |
2012年 | 38篇 |
2011年 | 49篇 |
2010年 | 29篇 |
2009年 | 21篇 |
2008年 | 34篇 |
2007年 | 23篇 |
2006年 | 29篇 |
2005年 | 32篇 |
2004年 | 22篇 |
2003年 | 16篇 |
2002年 | 35篇 |
2001年 | 17篇 |
2000年 | 13篇 |
1999年 | 13篇 |
1998年 | 10篇 |
1997年 | 14篇 |
1996年 | 11篇 |
1995年 | 9篇 |
1994年 | 12篇 |
1993年 | 17篇 |
1992年 | 12篇 |
1991年 | 11篇 |
1990年 | 7篇 |
1989年 | 9篇 |
1988年 | 12篇 |
1987年 | 11篇 |
1986年 | 11篇 |
1984年 | 11篇 |
1983年 | 7篇 |
1982年 | 10篇 |
1981年 | 6篇 |
1980年 | 9篇 |
1979年 | 12篇 |
1978年 | 13篇 |
1977年 | 7篇 |
1976年 | 7篇 |
1975年 | 12篇 |
1974年 | 7篇 |
1973年 | 12篇 |
1972年 | 5篇 |
排序方式: 共有869条查询结果,搜索用时 572 毫秒
1.
Synthesis,spectral investigation and development of tetrahedral copper(II) complexes as artificial metallonucleases and antimalarial agents 下载免费PDF全文
Seven new copper(II) complexes of type [Cu(A)(L)]?H2O (A = sparfloxacin, ciprofloxacin, levofloxacin, gatifloxacin, pefloxacin, ofloxacin, norfloxacin; L = 5‐[(3‐chlorophenyl)diazenyl]‐4‐hydroxy‐1,3‐thiazole‐2(3H)‐thione) were synthesized and characterized using elemental and thermogravimetric analyses, and electronic, electron paramagnetic resonance (EPR), Fourier transform infrared and liquid chromatography–mass spectroscopies. Tetrahedral geometry around copper is assigned in all complexes using EPR and electronic spectral analyses. All complexes were investigated for their interaction with herring sperm DNA utilizing absorption titration (Kb = 1.27–3.13 × 105 M?1) and hydrodynamic volume measurement studies. The studies suggest the classical intercalative mode of DNA binding. The cleavage reaction on pUC19 DNA was monitored by agarose gel electrophoresis. The results indicate that the Cu(II) complexes can more effectively promote the cleavage of plasmid DNA. The superoxide dismutase mimic activity of the complexes was evaluated by nitroblue tetrazolium assay, and the complexes catalysed the dismutation of superoxide at pH = 7.8 with IC50 values in the range 0.597–0.900 μM. The complexes were screened for their in vitro antibacterial activity against five pathogenic bacteria. All the complexes are good cytotoxic agents and show LC50 values ranging from 5.559 to 11.912 µg ml?1. All newly synthesized Cu(II) complexes were also evaluated for their in vitro antimalarial activity against Plasmodium falciparum strain (IC50 = 0.62–2.0 µg ml?1). Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
2.
The dependence of the beam propagation factor (M
2 parameter) with the absorbed pump power in the case of monolithic microchip laser under face-cooled configuration is extensively
studied. Our investigations show that the M
2 parameter is related to the absorbed pump power through two parameters (α and β) whose values depend on the laser material properties and laser configuration. We have shown that one parameter arises due
to the oscillation of higher order modes in the microchip cavity and the other parameter accounts for the spherical aberration
associated with the thermal lens induced by the pump beam. Such dependency of M
2 parameter with the absorbed pump power is experimentally verified for a face-cooled monolithic microchip laser based on Nd3+ -doped GdVO4 crystal and the values of α and β parameters were estimated from the experimentally measured data points. 相似文献
3.
4.
5.
P. C. Mehta 《Hyperfine Interactions》1987,37(1-4):325-345
Optical data processing is an advancing field which has received much attention in recent years. Optical techniques have already
shown their applicability in target identification, advanced signal processing operations and advanced linear algebra operations.
The potential capabilities of processing of data using photons instead of electrons as the carrier of information have established,
beyond any doubt, that the optical techniques will be the next generation technology surpassing electronic techniques in some
important areas such as air traffic control, missile guidance and remote sensing. Although great strides have been made in
all the areas of optical data processing, the goal of high performance, high speed and very accurate all-optical computers
would be realised only around the year 1995. The main difficulty is that the required materials for high resolution and fast
spatial light modulators and optical interconnects are yet to be perfected. The present paper reviews the recent trends and
the future prospects of optical data processing. 相似文献
6.
The objective of this paper is to investigate the role of the set of irrational numbers as the codomain of order-preserving
functions defined on topological totally preordered sets. We will show that although the set of irrational numbers does not
satisfy the Debreu property it is still nonetheless true that any lower (respectively, upper) semicontinuous total preorder
representable by a real-valued strictly isotone function (semicontinuous or not) also admits a representation by means of
a lower (respectively, upper) semicontinuous strictly isotone function that takes values in the set of irrational numbers.
These results are obtained by means of a direct construction. Moreover, they can be related to Cantor’s characterization of the real line to obtain much more general results on the semicontinuous
Debreu properties of a wide family of subsets of the real line.
相似文献
7.
Heavy ion irradiation in the electronic stopping power region induces macroscopic dimensional change in metallic glasses and introduces magnetic anisotropy in some magnetic materials. The present work is on the irradiation study of ferromagnetic metallic glasses, where both dimensional change and modification of magnetic anisotropy are expected. Magnetic anisotropy was measured using Mössbauer spectroscopy of virgin and irradiated Fe40Ni40B20 and Fe40Ni38Mo4B18 metallic glass ribbons. 90 MeV 127I beam was used for the irradiations. Irradiation doses were 5×1013 and 7.5×1013 ions/cm2. The relative intensity ratios D 23 of the second and third lines of the Mössbauer spectra were measured to determine the magnetic anisotropy. The virgin samples of both the materials display in-plane magnetic anisotropy, i.e., the spins are oriented parallel to the ribbon plane. Irradiation is found to cause reduction in magnetic anisotropy. Near-complete randomization of magnetic moments is observed at high irradiation doses. Correlation is found between the residual stresses introduced by ion irradiation and the change in magnetic anisotropy. 相似文献
8.
9.
10.
Excess volumes V
E
of binary liquid mixtures of quinoline with alkanols have been determined from densities at 30°C as a function of composition. The excess volumes are negative over the whole mole fraction range for all the mixtures and decrease with increasing length of alkanol (C1–C10). The VE data have been analyzed in terms of an approach which uses graph theoretical connectivity parameters of the third degrees for two components. The analysis gives information regarding associated species in the pure state and in the mixture. It is suggested that, in the mixture state, no change occurs in the association of alkanols. 相似文献