全文获取类型
收费全文 | 328篇 |
免费 | 0篇 |
专业分类
化学 | 308篇 |
数学 | 18篇 |
物理学 | 2篇 |
出版年
2022年 | 7篇 |
2021年 | 6篇 |
2020年 | 2篇 |
2019年 | 6篇 |
2017年 | 5篇 |
2016年 | 4篇 |
2015年 | 2篇 |
2014年 | 2篇 |
2013年 | 8篇 |
2012年 | 12篇 |
2011年 | 19篇 |
2010年 | 15篇 |
2009年 | 13篇 |
2008年 | 18篇 |
2007年 | 23篇 |
2006年 | 17篇 |
2005年 | 16篇 |
2004年 | 8篇 |
2003年 | 9篇 |
2002年 | 9篇 |
2001年 | 9篇 |
2000年 | 12篇 |
1999年 | 7篇 |
1998年 | 6篇 |
1997年 | 6篇 |
1996年 | 5篇 |
1995年 | 9篇 |
1994年 | 7篇 |
1993年 | 8篇 |
1992年 | 6篇 |
1991年 | 4篇 |
1990年 | 8篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1983年 | 1篇 |
1982年 | 2篇 |
1981年 | 5篇 |
1980年 | 5篇 |
1978年 | 2篇 |
1977年 | 1篇 |
1976年 | 6篇 |
1975年 | 5篇 |
1974年 | 4篇 |
1973年 | 4篇 |
排序方式: 共有328条查询结果,搜索用时 31 毫秒
1.
2.
3.
Arthur Greenberg Oleg P. Charkin Ralph H. Bartram István Hargittai Gyula Beke 《Structural chemistry》1992,3(3):221-224
Unsigned book reviews are by the Book Review Editor. 相似文献
4.
Please forward books for review to the book review editor: Magdolna Hargittai, Structural Chemistry Research Group of the Hungarian Academy of Sciences, Eötvös University, H-1431 Budapest, Pf. 117, Hungary 相似文献
5.
6.
7.
The aim of this research work was to clarify the role of the mixed emulsifier in the structure formation and water binding
mode in the case of o/w creams prepared with different surfactants. The swelling behavior of mixed emulsifiers was examined
by means of direct investigation methods such as transmission electron microscopy (TEM) and X-ray diffraction. The detailed
structure image of the creams was created with the help of the latter. The influence of the structure of the hydrophilic gel
phase, and the structural changes during storage were studied with rheological methods. On the basis of the results, it can
be stated that the investigated creams had different structures from those mentioned in the literature: surfactant did not
create a mixed bilayer with the structure to furnish fatty amphiphile; instead, micelles were formed. These results correlated
well with the results of the rheological tests. 相似文献
8.
The molecular structure of 4,4′-sulfanidyl-bis-thiophenol (C12H10S3) has been determined by gas electron diffraction. Assuming identical geometry and D2h local symmetry for ---SC6H4S--- moieties, the following bond lengths (rg) and bond angles were obtained: C---H = 1.101 ± 0.005, S---H = 1.388 ± 0.019, (C---C)mean = 1.400 ± 0.003, (S---C)mean = 1.778 ± 0.004 Å, Car---S---Car = 103.5 ± 1.3, C---C(S)---C = 120.4 ± 0.3, C(H)---C(H)---H = 119.1 ± 0.9 and C---S---H = 94.6 ± 3.1°. Two ratational forms were found to reproduce the experimental data, characterized by dihedral angles of the benzene rings with respect to the CarSCar plane; 1 = 67.8 ± 2.0°, 2 = 4.5 ± 7.2°, and 1 = 69.4 ± 2.0δ, 2 = −26.6 ± 7.1°. Identical signs of 1 and 2 indicate that the two benzene rings are rotated in the same direction about the respective Scentral---C axes. 相似文献
9.
10.
Schultz György Hargittai István Rot Nicolette Bickelhaupt Friedrich 《Structural chemistry》1998,9(3):209-214
The molecular structure of 1,3,5-tris (trimethylstannyl) benzene has been determined by gas-phase electron diffraction. The C — C bond length is in good agreement with that in benzene. In agreement with the somewhat electron-releasing character of the substituents, the endocyclic bond angles at the substituents are somewhat smaller than 120°. The mean value of Sn — C bond lengths is greater than that in tetraphenyltin and tetramethyltin. The SnMe3 groups appear freely rotating around the Caryl — Sn bonds. The following bond lengths (r
g) and bond angles were determined: (Sn — C)mean 2.150 ± 0.007 Å, C — C 1.399 ± 0.005 Å, (C — H)mean 1.105 ± 0.006 Å, < C — C(Sn) — C 117.7 ± 1.7º, < Caryl — Sn — Cmethyl 106.7 ± 0.7º < Sn — C — H 111.5 ± 0.9º. 相似文献