全文获取类型
收费全文 | 191篇 |
免费 | 2篇 |
专业分类
化学 | 118篇 |
晶体学 | 1篇 |
力学 | 1篇 |
数学 | 16篇 |
物理学 | 57篇 |
出版年
2021年 | 2篇 |
2019年 | 3篇 |
2016年 | 3篇 |
2014年 | 3篇 |
2013年 | 4篇 |
2012年 | 7篇 |
2011年 | 14篇 |
2010年 | 6篇 |
2009年 | 9篇 |
2008年 | 10篇 |
2007年 | 10篇 |
2006年 | 11篇 |
2005年 | 9篇 |
2004年 | 12篇 |
2003年 | 3篇 |
2002年 | 5篇 |
2001年 | 3篇 |
2000年 | 10篇 |
1999年 | 4篇 |
1998年 | 1篇 |
1997年 | 2篇 |
1996年 | 1篇 |
1994年 | 3篇 |
1992年 | 2篇 |
1990年 | 1篇 |
1989年 | 5篇 |
1988年 | 2篇 |
1987年 | 1篇 |
1986年 | 2篇 |
1985年 | 5篇 |
1984年 | 4篇 |
1983年 | 6篇 |
1981年 | 1篇 |
1980年 | 2篇 |
1979年 | 4篇 |
1977年 | 1篇 |
1976年 | 1篇 |
1975年 | 3篇 |
1974年 | 2篇 |
1972年 | 1篇 |
1963年 | 1篇 |
1961年 | 1篇 |
1959年 | 1篇 |
1958年 | 1篇 |
1956年 | 1篇 |
1955年 | 1篇 |
1948年 | 2篇 |
1940年 | 2篇 |
1921年 | 2篇 |
1916年 | 1篇 |
排序方式: 共有193条查询结果,搜索用时 31 毫秒
1.
J. B. Lewis E. L. Baldeschwieler L. D. Tabern E. F. Shelberg D. Hillis S. Cromer I. F. Bingham S. Givaudon M. Aubert M. R. Moutte A. Andant P. Lambert J. Lecomte J. Tausz H. Wolf B. Gordon W. Dachnow I. Perrier M. Lobunetz M. O. Chaikin C. Engler D. Holde 《Analytical and bioanalytical chemistry》1940,119(7-8):307-310
2.
R. Riva J. Rieger R. Jrme PH. Lecomte 《Journal of polymer science. Part A, Polymer chemistry》2006,44(20):6015-6024
This paper aims at reporting on the synthesis of a heterograft copolymer by combining the “grafting onto” process based on atom transfer radical addition (ATRA) and the “grafting from” process by atom transfer radical polymerization (ATRP). The statistical copolymerization of ε‐caprolactone (εCL) and α‐chloro‐ε‐caprolactone (αClεCL) was initiated by 2,2‐dibutyl‐2‐stanna‐1,3‐dioxepane (DSDOP), followed by ATRA of parts of the chlorinated units of poly(αClεCL‐co‐εCL) on the terminal double bond of α‐MeO,ω‐CH2?CH? CH2? CO2‐poly(ethylene oxide) (PEO). The amphiphilic poly(εCL‐g‐EO) graft copolymer collected at this stage forms micelles as supported by dynamic light scattering (DLS) and transmission electron microscopy (TEM). The unreacted pendant chloro groups of poly(εCL‐g‐EO) were used to initiate the ATRP of styrene with formation of copolymer with two populations of randomly distributed grafts, that is PEO and polystyrene. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 6015–6024, 2006 相似文献
3.
Claiser N Souhassou M Lecomte C Gillon B Carbonera C Caneschi A Dei A Gatteschi D Bencini A Pontillon Y Lelièvre-Berna E 《The journal of physical chemistry. B》2005,109(7):2723-2732
High-resolution X-ray diffraction and polarized neutron diffraction experiments have been performed on the Y-semiquinonate complex, Y(HBPz3)2(DTBSQ), in order to determine the charge and spin densities in the paramagnetic ground state, S = (1/2). The aim of these combined studies is to bring new insights to the antiferromagnetic coupling mechanism between the semiquinonate radical and the rare earth ion in the isomorphous Gd(HBPz3)2(DTBSQ) complex. The experimental charge density at 106 K yields detailed information about the bonding between the Y3+ ion and the semiquinonate ligand; the topological charge of the yttrium atom indicates a transfer of about 1.5 electrons from the radical toward the Y3+ ion in the complex, in agreement with DFT calculations. The electron density deformation map reveals well-resolved oxygen lone pairs with one lobe polarized toward the yttrium atom. The determination of the induced spin density at 1.9 K under an applied magnetic field of 9.5 T permits the visualization of the delocalized magnetic orbital of the radical throughout the entire molecule. The spin is mainly distributed on the oxygen atoms [O1 (0.12(1) mu B), O2(0.11(1) mu B)] and the carbon atoms [C21 (0.24(1) mu B), C22(0.20(1) mu B), C24(0.16(1) mu B), C25(0.12(1) mu B)] of the carbonyl ring. A significant spin delocalization on the yttrium site of 0.08(2) mu B is observed, proving that a direct overlap with the radical magnetic orbital can occur at the rare earth site and lead to antiferromagnetic coupling. The DFT calculations are in good quantitative agreement with the experimental charge density results, but they underestimate the spin delocalization of the oxygen toward the yttrium and the carbon atoms of the carbonyl ring. 相似文献
4.
A turbidimetric method is described for the determination of tantalum with phenylarsonic acid. The method is fast and rarely requires preliminary separation. The only interfering elements are zirconium and niobium when present in molar ratios greater than Nb : Ta = 1 and Zr : Ta = 5. 相似文献
5.
Alkyl- and arylmanganese reagents react with o-chloro or o-bromoaryl ketones to give the substituted ketones in high yields. The cross-coupling reaction is performed under mild conditions (-60 to +40 degrees C, 30 min to 4 h) and takes place with excellent chemoselectivity. [reaction: see text] 相似文献
6.
Girault J. Longueville D. Malgouyat J. M. Istin B. Lecomte G. Fourtillan J. B. 《Chromatographia》1994,39(3-4):228-238
Summary A simple and sensitive assay has been developed for the quantitative measurement of a new platelet activating factor antagonist (BN50730), and its two main metabolites (BN50727 and BN50922), at the picomole level in human plasma and urine. The three compounds of interest and the internal standard (BN50765) were measured by combined LC-negative chemical ionization MS. A simple solid-liquid extraction procedure was used to isolate the parent drug and the two metabolites. The MS was tuned to monitor the intense ionm/z 333 generated in the ion source by a dissociative capture process. The assay was on 1 ml plasma or 0.1 ml urine and the quantitation limit was calculated as 1 ng·ml–1. The very low relative standard deviations and mean percentages of error calculated for within-day or between-day repeatability assays demonstrate the ruggedness of the technique for routine determination in biological fluids. Some preliminary results on the pharmacokinetics of the parent drug and its two main metabolites illustrate the applicability of this method. 相似文献
7.
M.C. Silva G. Trolliard O. Masson R. Guinebretiere A. Dauger A. Lecomte B. Frit 《Journal of Sol-Gel Science and Technology》1997,8(1-3):419-424
Three different precursor materials giving rise to contrasted nanostructures, xerogels, aerogels and precipitates, are prepared by a sol gel route in the Zrn -propoxide—acetylacetone—water—n-propanol system. Clear homogeneous gels are made by using a proper amount of acetylacetone and water. The gels are dried either by conventional processing (xerogels) or by supercritical evacuation of alcoholic solvent (aerogels). The complexation ratio (R = [acetylacetone]/[Zr(OR)4]) is the main parameter controlling the size of ZrO2 primary particles. WhenR = 0 , precipitates are obtained.Xerogels, aerogels and precipitates are characterized and their textures are compared through small angle X-ray scattering measurements. The fractal structure of gels is destroyed by conventional drying and is preserved in aerogels. On the other hand precipitates are described as homogeneous agglomerates of very small primary units.The first crystallization steps are studied by transmission electron microscopy and X-ray diffraction experiments. The contribution of crystallite size and microstrain effects are investigated by Rietveld whole pattern fitting. The crystallization of precipitate powders starts at the agglomerate scale with large crystal like distorted lattices. 相似文献
8.
We present a new formulation for the prediction of tyre belt vibrations in the frequency range 0-500 Hz. Our representation includes the effects of belt width, curvature and anisotropy, and also explicitly models the tyre sidewalls. Many of the associated numerical parameters are fixed by physical considerations; the remainder require empirical input. A systematic and general approach to this problem is developed, and illustrated for the specific example of a Goodyear Wrangler tyre. The resulting predictions for the radial response to radial forcing show good correspondence with experiment up to 300 Hz, and satisfactory agreement up to 1 kHz. 相似文献
9.
10.
The spaces of linear differential operators
acting on -densities on
and the space
of functions on
which are polynomial on the fibers are not isomorphic as modules over the Lie algebra Vect (n) of vector fields of n. However, these modules are isomorphic as sl(n + 1,)-modules where
is the Lie algebra of infinitesimal projective transformations. In addition, such an
-equivariant bijection is unique (up to normalization). This leads to a notion of projectively equivariant quantization and symbol calculus for a manifold endowed with a (flat) projective structure. We apply the
-equivariant symbol map to study the
of kth-order linear differential operators acting on -densities, for an arbitrary manifold M and classify the quotient-modules
. 相似文献