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Wijkens P Jastrzebski JT van Der Schaaf PA Kolly R Hafner A van Koten G 《Organic letters》2000,2(11):1621-1624
A general method for the functionalization of Si-Cl terminated carbosilane dendritic molecules via organolithium or organomagnesium reagents is described. Quantitative exchange of the bromine atoms of 4-bromophenyl-functionalized dendrimers affords polylithiated species that are valuable starting materials for further functionalization, e.g., into pyridyl alcohols. The latter were successfully applied as catalyst precursors in a ruthenium-mediated ring-closure metathesis reaction. 相似文献
3.
[reaction: see text] The gas-phase thermal isomerization of cis,anti,cis-tricyclo[6.3.0.0(2,7)]undec-3-ene (1) to endo-tricyclo[5.2.2.0(2,6)]undec-8-ene (2) at 315 degrees C occurs cleanly through a symmetry-forbidden [1,3] suprafacial,retention (sr) pathway. 相似文献
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Gordeev SN Zhukov AA de Groot PA Jansen AG Gagnon R Taillefer L 《Physical review letters》2000,85(21):4594-4597
We report on transport measurements of YBa 2Cu 3O (7-delta) single crystals with different oxygen contents in the geometry B, J ||ab (J perpendicularB). Our data show that the vortices become confined between the Cu-O planes below a well-defined temperature at which the effective size 2xi of the vortex core is approximately equal to the period of the Cu-O layers. This confinement strongly increases the vortex liquid freezing temperature. A new melting line is found separating a vortex liquid and a smectic phase, which shows an oscillatory field dependence reflecting differences between commensurate and incommensurate smectic states. 相似文献
6.
Ming Xia LI Yan Ming WANG Ru Ru CHEN* Research Institute of Elemento-Organic Chemistry Nankai University Tianjin Pittsburgh University Medical Center Pittsburgh PA U. S. A 《中国化学快报》2001,(6)
The chiral diols ((,(,((,((-Tetraaryl-1,3-dioxolane-4,5-dimethanols) have been used for the formation of cyclic titanates and similar derivatives of Mg, Al and Zr. These complexes of oxophilic metal centers were employed in catalytic and stiochiometric enantioselective reactions such as enantioselective addition reactions of carbon-centered nucleophiles to aldehydes1, [2+2] cycloadditions2, and Diels-Alder reactions3. So far, the two hydrogen atoms of all this type of diols are in trans form… 相似文献
7.
We consider diffraction by a semi-infinite crack located alonga fusion interface between two differing elastic media. Twotypes of crack, namely open and partially closed cracks, areinvestigated. An open crack is modelled by a stress-free contactboundary condition and a partially closed crack is modelledby a spring contact boundary condition. For the latter, thejump in the stress across the crack is assumed to be proportionalto the jump in the displacement across the crack. This situationarises in, for example, a K-weld where the fine grain of theparent material (for example, ferritic or forged austeniticsteel) is in stark contrast with the coarse-grained weld metal(for example, austenitic weld metal). In the metal weld thedirection of the grain axis varies through the metal. However,diffraction is a local phenomenon and so the austenitic steelis assumed to have a zonal axis so that it may be modelled bya transversely isotropic composite. The ferritic or forged austeniticsteel will be modelled as an isotropic material. 相似文献
8.
J.M. Nitschke M. Fowler A. Ghiorso R.E. Leber M.E. Leino M.J. Nurmia L.P. Somerville K.E. Williams E.K. Hulet J.H. Landrum R.W. Lougheed J.F. Wild C.E. Bemis R.J. Silva P. Eskola 《Nuclear Physics A》1981,352(1):138-146
A rotating drum system was used to search for an 80 ms spontaneous fission (sf) activity in the reaction of 15N with 249Bk. No such activity was found beyond a cross section limit of 0.5 nb. A sf activity with a half-life of 23 ± 2 ms and a maximum formation cross section of 19 ± 4 nb at 82 MeV was observed. The identity of this activity has not been determined. 相似文献
9.
James F. Woodward André de Klerk Gail Kahler Kathrine Leber Peter Pompei Daniel Schultz Sharon Stern 《Foundations of Physics》1972,2(2-3):241-244
An experiment designed to test the highly speculative hypothesis of photon consciousness was executed. It was found that, within the accuracy attainable with the apparatus, there is no empirical justification for the hypothesis. 相似文献
10.
S. S. Barshay R. E. Leber R. M. Lambrecht 《Applied Physics A: Materials Science & Processing》1974,5(1):67-70
The Doppler broadening of positron annihilation photons was measured in 17 metals. A model which considers the positron lifetime spectra in metals to be composed of terms for annihilation with conduction and core electrons and surface centers of low electron momentum is used to correlate calculated core annihilation rates with the Doppler lineshape. Ta metal was doped with defects with high energy implantations of14N+4 ions at variable doses. Differences in the Doppler linewidths were ascribed as being principally a reflection of the probabilty of annihilation with core electrons relative to annihilation with conduction electrons. 相似文献