全文获取类型
收费全文 | 1427篇 |
免费 | 33篇 |
国内免费 | 19篇 |
专业分类
化学 | 937篇 |
晶体学 | 6篇 |
力学 | 14篇 |
数学 | 310篇 |
物理学 | 212篇 |
出版年
2023年 | 10篇 |
2022年 | 10篇 |
2021年 | 34篇 |
2020年 | 22篇 |
2019年 | 25篇 |
2018年 | 19篇 |
2017年 | 22篇 |
2016年 | 33篇 |
2015年 | 38篇 |
2014年 | 44篇 |
2013年 | 99篇 |
2012年 | 75篇 |
2011年 | 95篇 |
2010年 | 67篇 |
2009年 | 63篇 |
2008年 | 94篇 |
2007年 | 72篇 |
2006年 | 72篇 |
2005年 | 68篇 |
2004年 | 53篇 |
2003年 | 47篇 |
2002年 | 44篇 |
2001年 | 23篇 |
2000年 | 23篇 |
1999年 | 15篇 |
1998年 | 19篇 |
1997年 | 21篇 |
1996年 | 28篇 |
1995年 | 12篇 |
1994年 | 11篇 |
1993年 | 8篇 |
1992年 | 12篇 |
1991年 | 12篇 |
1990年 | 10篇 |
1989年 | 12篇 |
1988年 | 8篇 |
1987年 | 8篇 |
1986年 | 10篇 |
1985年 | 10篇 |
1984年 | 18篇 |
1983年 | 10篇 |
1982年 | 12篇 |
1981年 | 5篇 |
1980年 | 6篇 |
1979年 | 7篇 |
1978年 | 5篇 |
1977年 | 15篇 |
1976年 | 9篇 |
1975年 | 6篇 |
1974年 | 8篇 |
排序方式: 共有1479条查询结果,搜索用时 15 毫秒
1.
Attila Kovács 《International journal of quantum chemistry》2020,120(1):e26051
Lanthanide dinitrogen complexes, Ln(N2) x (x = 1-8), were investigated by Density Functional Theory computations using the B3LYP exchange-correlation functional in conjunction with quasirelativistic pseudopotentials for Ln. After a recent study on the lanthanum complexes (A. Kovács, Structural Chemistry 2018 , 29, 1825), the present study aimed to probe the changes upon variously filled 4f subshells of Ln on the structures, stabilities, and bonding properties in related complexes of Nd, Ho, and Lu. The bonding properties were assessed on the basis of natural atomic charges, Ln valence orbital populations, and analysis of bonding molecular orbitals. 相似文献
2.
András Gy. Németh Renáta Szabó Dr. Attila Domján Prof. György M. Keserű Dr. Péter Ábrányi-Balogh 《ChemistryOpen》2021,10(1):16-27
The development of a new three-component chromatography-free reaction of isocyanides, amines and elemental sulfur allowed us the straightforward synthesis of thioureas in water. Considering a large pool of organic and inorganic bases, we first optimized the preparation of aqueous polysulfide solution from elemental sulfur. Using polysulfide solution, we were able to omit the otherwise mandatory chromatography, and to isolate the crystalline products directly from the reaction mixture by a simple filtration, retaining the sulfur in the solution phase. A wide range of thioureas synthesized in this way confirmed the reasonable substrate and functional group tolerance of our protocol. 相似文献
3.
Julien Ferrari Christian Terreaux Tibor Kurtn Attila Szikszai‐Kiss Sndor Antus JeromeD. Msonthi Kurt Hostettmann 《Helvetica chimica acta》2003,86(8):2768-2778
Investigation of the methanol extract of the roots of Gnidia involucrata (Thymelaeaceae) led to the isolation and characterization of two new 3,8″‐biflavonoid diastereoisomers, named GB‐4 ( 6a ) and GB‐4a ( 6b ). Their absolute configurations were determined in mixture by on‐line LC/CD measurements, which also allowed the revision of absolute configurations of the biflavanoids GB‐1 and GB‐2, and the configurational assignment of GB‐3. 相似文献
4.
A note on a generalized Douglas space 总被引:1,自引:0,他引:1
Periodica Mathematica Hungarica - 相似文献
5.
We compare the efficiency of two Faddeev-type approaches for the nuclear three-body Coulomb problem. The first one is a modification
of Noble’s approach, the second one is due to Sasakawa and Sawada. In an integral-equation formulation both of these methods
rely on the same Green’s operators and driving terms. The differences lie in the treatment of the long-range Coulomb potentials.
Numerical examples show that the modified Faddeev-Noble approach provides for faster convergence. 相似文献
6.
In this paper we extend a result of Semrl stating that every 2-local automorphism of the full operator algebra on a separable infinite dimensional Hilbert space is an automorphism. In fact, besides separable Hilbert spaces, we obtain the same conclusion for the much larger class of Banach spaces with Schauder bases. The proof rests on an analogous statement concerning the 2-local automorphisms of matrix algebras for which we present a short proof. The need to get such a proof was formulated in Semrl's paper.
7.
The concept of rigid sphericalt-designs was introduced by Bannai. He conjectured that there is a functionf(t, d) such that ifX is a sphericalt design in thed-dimensional Euclidean space so that |X|>f(t, d), theX is non-rigid. Furthermore, he asked to find examples of rigid but not tight sperical designs. In the present article we shall investigate the case whenX is an orbit of a finite reflection group and prove thatX is rigid iff tight for the groupsA
n
,B
n
,C
n
,D
n
,E
6,E
7,F
4,I
3.Research was partially supported by Hungarian National Research fund Grant No. 4267. 相似文献
8.
In this paper the effects of surface roughness and annealing temperature (T) of latex coating films on adhesion are discussed for the different stages of the film formation process. The surface free energy of latex films was assessed in terms of practical work of adhesion (W) (or adherence) using a custom-built adhesion-testing device (ATD), atomic force microscopy (AFM), and contact angle measurements. For preannealed latex films surface roughness averages (Ra) were determined from AFM height images and were related to the values of W obtained from ATD measurements at room temperature. The results obtained using these tests exhibiting surface behavior on different length scales indicate a dependence of the measured adhesion on surface roughness and temperature, as well as on the length scale of the measurements.First preannealed samples were studied, which were obtained by heat treatment above the respective glass transition temperatures (Tg). Increasing the temperature of preannealing resulted in a decrease of the adherence observed in ATD experiments at room temperature. However, on the nanoscale, using AFM, no significant variation of the adherence was observed. This observation can be explained by roughness arguments. Preannealing decreases roughness which results in lower adherence values measured by ATD while for essentially single asperity AFM experiments roughness has an insignificant effect. Specimens were also annealed over a constant period of time (90 min) at different temperatures. At the end of the heat treatment, adhesion was measured at the treatment temperature by ATD. The amplified effect of temperature observed in this case on adherence is attributed to the combination of roughness decrease and increasing test temperature. In a third set of experiments completely annealed samples were studied by ATD as well as by AFM as a function of temperature. With increasing T values ATD showed a decrease in adherence, which is attributed to a decreasing surface free energy of the annealed films at elevated T values. AFM, on the other hand, showed an opposite trend which is assigned to increasing penetration of the tip into the tip/wetting polymer samples versus increasing temperature. Finally, annealing isotherms as a function of time were investigated by ATD in situ at different temperatures. This last set of experiments allowed us to optimize annealing time and temperature to achieve complete curing. 相似文献
9.
10.
The three-body Coulomb problem for nuclear clusters is solved numerically for a model below three-body breakup threshold. An orthogonalized multi-channels method is employed. The method allows to check for convergence by considering the norm square of the closed-channels part of the wave function. The numerical results show that convergence can well be achieved on present-day computers. 相似文献