全文获取类型
收费全文 | 924篇 |
免费 | 69篇 |
国内免费 | 33篇 |
专业分类
化学 | 717篇 |
晶体学 | 12篇 |
力学 | 39篇 |
综合类 | 1篇 |
数学 | 102篇 |
物理学 | 155篇 |
出版年
2023年 | 8篇 |
2022年 | 7篇 |
2021年 | 10篇 |
2020年 | 29篇 |
2019年 | 23篇 |
2018年 | 24篇 |
2017年 | 5篇 |
2016年 | 32篇 |
2015年 | 26篇 |
2014年 | 28篇 |
2013年 | 48篇 |
2012年 | 48篇 |
2011年 | 45篇 |
2010年 | 45篇 |
2009年 | 42篇 |
2008年 | 45篇 |
2007年 | 46篇 |
2006年 | 69篇 |
2005年 | 52篇 |
2004年 | 40篇 |
2003年 | 47篇 |
2002年 | 25篇 |
2001年 | 22篇 |
2000年 | 17篇 |
1999年 | 15篇 |
1998年 | 10篇 |
1997年 | 6篇 |
1996年 | 12篇 |
1995年 | 14篇 |
1994年 | 6篇 |
1993年 | 9篇 |
1992年 | 16篇 |
1991年 | 10篇 |
1990年 | 4篇 |
1989年 | 11篇 |
1987年 | 9篇 |
1986年 | 6篇 |
1985年 | 15篇 |
1984年 | 11篇 |
1983年 | 5篇 |
1982年 | 5篇 |
1981年 | 3篇 |
1980年 | 7篇 |
1979年 | 8篇 |
1978年 | 18篇 |
1977年 | 5篇 |
1976年 | 8篇 |
1975年 | 4篇 |
1973年 | 8篇 |
1970年 | 3篇 |
排序方式: 共有1026条查询结果,搜索用时 31 毫秒
1.
Solid state nuclear track detectors are commonly used for measurements of concentrations of radon gas and/or radon progeny. All these measurements depend critically on the thickness of the removed layer during etching. However, the thickness of removed layer calculated using the etching period does not necessarily provide a sufficiently accurate measure of the thickness. For example, the bulk etch rate depends on the strength of stirring during etching for the LR 115 detector. We propose here to measure the thickness of the removed layer by using energy-dispersive X-ray fluorescence spectrometry. In the present work, a reference silver nitrate pellet is placed beneath the LR 115 detector, and the fluorescence X-ray intensity for silver is then measured. We have found a linear relationship between the X-ray intensity and the thickness of the removed layer for LR 115 detector. This provides a fast method to measure the thickness of removed layer from etching of LR 115 detector. However, this method was found to be inapplicable for the CR-39 detector. Therefore, alternative methods have yet to be explored for the CR-39 detector. 相似文献
2.
3.
Zhong‐Zhen Yu Mingshu Yang Qingxin Zhang Chungui Zhao Yiu‐Wing Mai 《Journal of Polymer Science.Polymer Physics》2003,41(11):1234-1243
Nylon‐66 nanocomposites were prepared by melt‐compounding nylon‐66 with an alkyl ammonium surfactant pretreated montmorillonite (MMT). The thermal stability of the organic MMT powders was measured by thermogravimetric analysis. The decomposition of the surfactant on the MMT occurred from 200 to 500 °C. The low onset decomposition temperature of the organic MMT is one shortcoming when it is used to prepare polymer nanocomposites at high melt‐compounding temperatures. To provide greater property enhancement and better thermal stability of the polymer/MMT nanocomposites, it is necessary to develop MMT modified with more thermally stable surfactants. The dispersion and spatial distribution of the organic MMT layers in the nylon‐66 matrix were characterized by X‐ray diffraction. The organic MMT layers were exfoliated but not randomly dispersed in the nylon‐66 matrix. A model was proposed to describe the spatial distribution of the organic MMT layers in an injection‐molded rectangular bar of nylon‐66/organic MMT nanocomposites. Most organic MMT layers were oriented in the injection‐molding direction. Layers near the four surfaces of the bar were parallel to their corresponding surfaces; whereas those in the bulk differed from the near‐surface layers and rotated themselves about the injection‐molding direction. The influence of the spatial distribution of the organic MMT on crystallization of nylon‐66 was also investigated. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 1234–1243, 2003 相似文献
4.
We have observed three-dimensional sponge-like structures as well as strips of connecting pits on the surface of the LR 115 detector after etching, which can be confused with the small tracks formed after short etching time. We have employed an atomic force microscope (AFM) to study these “damages” as well as genuine alpha tracks for short etching time. It was found that while the track and damage openings could be similar in size and shape, the depths for the damages were consistently smaller. Therefore, the depth of the pits will serve as a clear criterion to differentiate between tracks and other damages. The ability to discriminate between genuine tracks from other damages is most important for etching for short time intervals. 相似文献
5.
6.
In this paper, the problem of estimating the covariance matrix of the elliptically contoured distribution (ECD) is considered. A new class of estimators which shrink the eigenvalues towards their arithmetic mean is proposed. It is shown that this new estimator dominates the unbiased estimator under the squared error loss function. Two special classes of ECD, namely, the multivariate-elliptical t distribution and the ε-contaminated normal distribution are considered. A simulation study is carried out and indicates that this new shrinkage estimator provides a substantial improvement in risk under most situations. 相似文献
7.
8.
9.
Paital AR Mitra T Ray D Wong WT Ribas-Ariño J Novoa JJ Ribas J Aromí G 《Chemical communications (Cambridge, England)》2005,(41):5172-5174
Based on a combined theoretical-experimental study, we propose that substituted m-phenylene ligands (m-N-Phi-N) can act as tuneable strong ferromagnetic couplers connecting Cu(II) ions; a new complex presenting that bridge with J close to +15 cm(-1) has been suggested and synthesized. 相似文献
10.