全文获取类型
收费全文 | 102篇 |
免费 | 9篇 |
国内免费 | 1篇 |
专业分类
化学 | 97篇 |
数学 | 6篇 |
物理学 | 9篇 |
出版年
2022年 | 1篇 |
2021年 | 3篇 |
2020年 | 1篇 |
2019年 | 5篇 |
2018年 | 1篇 |
2017年 | 3篇 |
2016年 | 1篇 |
2015年 | 2篇 |
2014年 | 10篇 |
2013年 | 2篇 |
2012年 | 11篇 |
2011年 | 6篇 |
2010年 | 9篇 |
2009年 | 2篇 |
2008年 | 3篇 |
2007年 | 5篇 |
2006年 | 8篇 |
2005年 | 2篇 |
2004年 | 5篇 |
2003年 | 6篇 |
2002年 | 5篇 |
2001年 | 3篇 |
2000年 | 1篇 |
1999年 | 5篇 |
1994年 | 2篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1984年 | 2篇 |
1982年 | 1篇 |
1981年 | 2篇 |
1980年 | 1篇 |
1977年 | 1篇 |
排序方式: 共有112条查询结果,搜索用时 31 毫秒
1.
Sagara T Nagata K Tsuruta H Nakashima N 《Chemical communications (Cambridge, England)》2002,(18):2116-2117
Potential-dependent dynamic adsorption-desorption and reorientation of a 4-pyridyl modified PAMAM G2 dendrimer at a Au(111) electrode has been demonstrated. 相似文献
2.
Nogita R Matohara K Yamaji M Oda T Sakamoto Y Kumagai T Lim C Yasutake M Shimo T Jefford CW Shinmyozu T 《Journal of the American Chemical Society》2004,126(42):13732-13741
Thephotochemical reaction of [3(3)](1,3,5)cyclophane 2, which is a photoprecursor for the formation of propella[3(3)]prismane 18, was studied using a sterilizing lamp (254 nm). Upon photolysis in dry and wet CH2Cl2 or MeOH in the presence of 2 mol/L aqueous HCl solution, the cyclophane 2 afforded novel cage compounds comprised of new skeletons, tetracyclo[6.3.1.0.(2,7)0(4,11)]dodeca-5,9-diene 43, hexacyclo[6.4.0.0.(2,6)0.(4,11)0.(5,10)0(9,12)]dodecane 44, and pentacyclo[6.4.0.0.(2,6)0.(4,11)0(5,10)]dodecane 45. All of these products were confirmed by the X-ray structural analyses. A possible mechanism for the formation of these photoproducts via the hexaprismane derivative 18 is proposed. The photophysical properties in the excited state of the [3n]cyclophanes ([3n]CP, n = 2-6) were investigated by measuring the emission spectra and determining the quantum yields and lifetimes of the fluorescence. All [3n]CPs show excimeric fluorescence without a monomeric one. The lifetime of the excimer fluorescence becomes gradually longer with the increasing number of the trimethylene bridges. The [3n]CPs also shows excimeric phosphorescence spectra without vibrational structures for n = 2, 4, and 5, while phosphorescence is absent for n = 3 and 6. With an increase in symmetry of the benzene skeleton in the [3(3)]- and [3(6)]CPs, the probability of the radiation (phosphorescence) process from the lowest triplet state may drastically decrease. 相似文献
3.
4.
The pigment, tecophilin, in blue flowers of Tecophilaea cyanocrocus was isolated and the structure was determined to be 3-O-(6-O-α-l-rhamnopyranosyl-β-d-glucopyranosyl)-7-O-(6-O-(4-O-(2-O-(4-O-β-d-glucopyranosyl-(E)-caffeoyl)-6-O-(4-O-β-d-glucopyranosyl-(E)-caffeoyl)-β-d-glucopyranosyl)-(E)-caffeoyl)-β-d-glucopyranosyl)delphinidin. The reproduction experiment of the same color as petals according to the results of chemical analysis and measurement of vacuolar pH of blue cells clarified that the blue color solely develops by tecophilin without interaction of metal ions nor co-pigments. 1H NMR analysis and CD spectrum indicate the co-existence of clockwise intermolecular self-association of the delphinidin nuclei and intramolecular π–π stacking between the chromophore and caffeoyl residues to derive bathochromic shift of the absorption spectrum and stabilize the color by preventing hydration reaction. 相似文献
5.
Siti Masturah binti Fakhruddin Kosuke Ino Kumi Y. Inoue Yuji Nashimoto Hitoshi Shiku 《Electroanalysis》2022,34(2):212-226
Bipolar electrode-based (BPE-based) electrochromic devices have garnered increasing attention in the past decade. These BPE-based electrochromic devices have been used for analytical health monitoring, point-of-care (POC) diagnostics, and chemical sensing. In this review, we highlight recent progress made regarding BPE-based electrochromic devices constructed for these analytical applications. Various, available electrochromic materials are summarized in the first section, after which the different device types (e. g., paper-based and self-powered) are discussed. Biological- and chemical-based analytical demonstrations of these devices are then reviewed. Finally, we conclude this review with a perspective on the future developments of BPE-based electrochromic devices in analytical applications. 相似文献
6.
Juraj Kumičák 《Czechoslovak Journal of Physics》1999,49(4):527-537
A model of 1/f noise is considered, based on moving averages of ordern. The coefficientsα
k
defining the model are calculated numerically using Seidel iteration which turns out to converge rapidly. The convergence
is independent ofn which seems to be caused by the fact that the nonlinear problem solved is defined by a self-similar matrix. The coefficientsα
k
appear to approach, with indefinitely growingn, valuesα
k
=1/√k and thus the model has a kind of Fourier invariance. Physical interpretation of the invariance is suggested as well
as of coefficientsα
k
describing long-range correlations. Fractal sets of dimensiond=2.5 are proposed to play certain role in explaining the latter.
This work was partly supported by the Scientific Grant Agency of the Ministry of Education of Slovak Republic (VEGA) under
the Grant No. 1/3143/96 and by the Slovak Literary Fund. 相似文献
7.
Kumi Yasuda 《Journal of Functional Analysis》2004,216(2):422-454
This article aims at showing a p-adic analogue of Selberg's trace formula, which describes a duality between the spectrum of a Hilbert-Schmidt operator and the length of prime geodesics appearing in the p-adic upper half-plane associated with a hyperbolic discontinuous subgroup of . Then we construct Markov processes on the fundamental domain relative to such subgroups, to whose transition operators the trace formula applied and a p-adic analogue of prime geodesic theorem is proved. 相似文献
8.
Ferroelectric SrBi2Ta2O9 film was prepared using the sol-gel technique. The sol-gel precursor resulted in good ferroelectric performance at annealing temperatures as low as 700°C. The baking profiles changed the orientation and the grain size in the film. The finer grain size and the higher switching charge were consistent under the slower baking profile. 相似文献
9.
10.
Kumi Y. Inoue Kosuke Ino Hitoshi Shiku Tomokazu Matsue 《Electrochemistry communications》2010,12(8):1066-1069
We have developed a zymogen-based electrochemical sensor. Zymogen is an inactive enzyme precursor (proenzyme) and it is necessary to transform it biochemically (e.g., by hydrolysis and conformational change) to make it an active enzyme. In this study, we demonstrated the detection of endotoxin by using recombinant Factor C (rFC), which is a protease zymogen activated by endotoxin binding. The activated rFC hydrolyzes a synthetic substrate of Boc-Val-Pro-Arg-p-nitroanilnide to generate an electrochemical active compound, p-nitroaniline (pNA). The liberated pNA was detected by differential pulse voltammetry at –0.75 V. By using this electrochemical process, 5000 endotoxin units (EU) L?1 and 1000 EU L?1 were detected in a Tris-Ac buffer with a pH of 7.5 at 37 °C for reaction times of 1 h and 3 h, respectively. The concept of zymogen-based electrochemical sensors is expected to lead to the development of new biosensors. 相似文献