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Characterization of autocatalytic decomposition reactions is important
for the safe handling and storage of energetic materials. Isothermal differential
scanning calorimetry (DSC) has been widely used to detect autocatalytic decomposition
of energetic materials. However, isothermal DSC tests are time consuming and
the choice of experimental temperature is crucial. This paper shows that an
automatic pressure tracking calorimeter (APTAC) can be a reliable and efficient
screening tool for the identification of autocatalytic decomposition behavior
of energetic materials.
Hydroxylamine nitrate (HAN) is an important
member of the hydroxylamine family. High concentrations of HAN are used as
liquid propellants, and low concentrations of HAN are used primarily in the
nuclear industry for decontamination of equipment. Because of its instability
and autocatalytic decomposition behavior, HAN has been involved in several
incidents. 相似文献
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R. Gonczarek M. Krzyzosiak A. Gonczarek 《The European Physical Journal B - Condensed Matter and Complex Systems》2008,61(3):299-308
In this paper we find and present on diagrams in the coordinates of η=2t1/t0 (the ratio of the second and the first nearest
neighbor hopping integrals) and n (the carrier concentration) the
areas of stability for the superconducting spin-singlet s-
and d-wave and the spin-triplet p-wave order
parameters hatching out during the phase transition from the normal
to the superconducting phase. The diagrams are obtained for an
anisotropic two-dimensional superconducting system with a relatively
wide partially-filled conduction band. We study a tight-binding
model with an attractive nearest neighbor interaction with the
amplitude V1, and the on-site interaction (with the amplitude
V0) taken either as repulsive or attractive. The problem of the
coexistence of the s-, p- and d-wave order
parameters is addressed and solved for chosen values of the ratio
V0/V1. A possible island of stability of the d-wave
order parameter in the s-wave order parameter environment for
a relatively strong on-site interaction is revealed. The triple
points, around which the s-, d-, and p-wave
order parameters coexist, are localized on diagrams. It is shown
that results of the calculations performed for the two-dimensional
tight-binding band model are dissimilar with some obtained within
the BCS-type approximation. 相似文献
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Several magnetic and optical processes contribute to the magneto-optical response of nickel thin films after excitation by a femtosecond laser pulse. We achieved a first complete identification by explicitly measuring the time-resolved Kerr ellipticity and rotation, as well as its temperature and magnetic field dependence in epitaxially grown (111) and (001) oriented Cu/Ni/Cu wedges. The first hundreds of femtoseconds the response is dominated by state filling effects. The true demagnetization takes approximately 0.5-1 ps. At the longer (sub-ns) time scales the spins are found to precess in their anisotropy field. Simple and transparent models are introduced to substantiate our interpretation. 相似文献
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Mateusz Krzyzosiak Ryszard Gonczarek Adam Gonczarek Lucjan Jacak 《Frontiers of Physics》2016,11(6):117407
A framework for analytical studies of superconducting systems is presented and illustrated. The formalism, based on the conformal transformation of momentum space, allows one to study the effects of both the dispersion relation and the structure of the pairing interaction in two-dimensional anisotropic high-T c superconductors. In this method, the number of employed degrees of freedom coincides with the dimension of the momentum space, which is different compared to that in the standard Van Hove scenario with a single degree of freedom. A new function, the kernel of the density of states, is defined and its relation to the standard density of states is explained. The versatility of the method is illustrated by analyzing coexistence and competition between spin-singlet and spin-triplet order parameters in superconducting systems with a tight-binding-type dispersion relation and an anisotropic pairing potential. Phase diagrams of stable superconducting states in the coordinates η (the ratio of hopping parameters) and n (the carrier concentration) are presented and discussed. Moreover, the role of attractive and repulsive on-site interactions for the stability of the s-wave order parameter is explained. 相似文献
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