排序方式: 共有23条查询结果,搜索用时 437 毫秒
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Jozef Rychlý Aysegul Kocer Fathy Tanis Lyda Matisová-Rychlá Ivica Janigová Katarína Csomorová 《Chemical Papers》2009,63(4):471-478
Difference in the kinetics of chemiluminescence (CL) and differential scanning calorimetry records for decomposition of originally
solid benzoyl peroxide continuing as a melt reaction was outlined. While the main portion of heat measured by DSC is released
in the spontaneous decomposition of benzoyl peroxide starting as a homolytic scission of peroxidic bonds, the CL light emission
in oxygen comes presumably from the subsequent disproportionation reaction of polyphenyl peroxyl radicals and monitors the
induced decomposition of peroxide. Thermogravimetry revealed that oxygen remains partially bound to the products of benzoyl
peroxide decomposition. 相似文献
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Bobeldijk I Bouwhuis M Ireland DG de Jager CW Jans E de Jonge N Kasdorp WJ Konijn J Lapikás L van Leeuwe JJ van der Meer RL Nooren GJ Passchier E Schroevers M van der Steenhoven G Steijger JJ Theunissen JA van Uden MA de Vries H de Vries R de Witt Huberts PK Blok HP van den Brink HB Dodge GE Harakeh MN Hesselink WH Kalantar-Nayestanaki N Pellegrino A Spaltro CM Templon JA Hicks RS Kelly JJ Marchand C 《Physical review letters》1994,73(20):2684-2687
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Queuing systems with finite buffers are reasonable models for many manufacturing, telecommunication, and healthcare systems. Although some approximations exist, the exact analysis of multi‐server and finite‐buffer queues with general service time distribution is unknown. However, the phase‐type assumption for service time is a frequently used approach. Because the Cox distribution, a kind of phase‐type distribution, provides a good representation of data with great variability, it has a vast area of application in modeling service times. The research focus is twofold. First, a theoretical structure of a multi‐server and finite‐buffer queuing system in which the service time is modeled by the two‐phase Cox distribution is studied. It is focused on finding an efficient solution to the stationary probabilities using the matrix‐geometric method. It is shown that the stationary probability vector can be obtained with the matrix‐geometric method by using level‐dependent rate matrices, and the mean queue length is computed. Second, an empirical analysis of the model is presented. The proposed methodology is applied in a case study concerning the geriatric patients. Some numerical calculations and optimizations are performed by using geriatric data. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
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Melis Kesik Ozgecan Kocer Fulya Ekiz Kanik Naime Akbasoglu Unlu Eda Rende Evren Aslan‐Gurel Rene M. Rossi Yasemin Arslan Udum Levent Toppare 《Electroanalysis》2013,25(8):1995-2006
Surface functionalization plays a crucial role in the design of biosensors. For this purpose, a novel functional monomer, 6‐(4,7‐bis(2,3‐dihydrothieno[3,4‐b][1,4]dioxin‐5‐yl)‐2H‐benzo[d][1,2,3]triazol‐2‐yl)hexan‐1‐amine (BEDOA‐6), was designed and synthesized. Poly(BEDOA‐6) was utilized as an immobilization matrix for glucose oxidase biosensor construction. Moreover, polymethylmethacrylate (PMMA) layered silicate nanocomposites were prepared by in situ suspension polymerization. Conducting polymer surface was modified with PMMA/clay nanocomposite material and a glucose biosensor was developed. In addition, XPS and SEM were utilized to characterize the surface properties. The biosensor shows a wide linear range between 2.8 µM and 1.2 mM to glucose with a low detection limit of 1.99 µM. Finally, the biosensor was tested on serum samples containing actual human blood. The results were in well‐agreement with a reference method. 相似文献
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荧光寿命的快速傅里叶变换拟合方法 总被引:7,自引:2,他引:5
介绍了一种利用快速傅里叶变换算法对稀土掺杂物质的荧光寿命进行数据拟合的方法。稀土掺杂物质可用来制备多种光学传感器,用于温度、pH值等多种参量测量领域。本方法利用快速傅里叶变换(FFT)结果作为基础,从非零项的相位角的正切值得出被测的荧光寿命,具有速度快、误差小、不受本底干扰等一系列优点。以掺铒光纤为例,通过数字仿真将本方法与其它几种传统的拟合方法进行了比较。快速傅里叶变换方法的测量偏差不到Prony方法的50%,为对数似合(log-fit)方法测量偏差的1/6。另外,快速傅里叶变换方法由于不受本底噪声影响,可以不必在信号处理时去掉本底噪声,因而可以明显缩短测量时间。 相似文献