Reaction of 3-Alkoxy-7-methylenebicyclo[3.3.1]non-2-ene with N-Halosuccinimides

Russian Journal of General Chemistry -     

Synthesis and Transformations of 2-(Adamantan-1-yl)aziridine

Russian Journal of Organic Chemistry - Mono- and disubstituted aziridines derived from sterically hindered olefins of the adamantane series are synthesized. The opening of the aziridine ring under...     

Synthesis of amino polycarboxylic acids of the adamantane series

The Ritter reaction of dibasic carboxylic acids of the adamantane series with carboxy and carboxymethyl groups attached to bridgehead carbon atoms afforded a number of amino polycarboxylic acids.     

One-pot amination of cage hydrocarbons

A one-pot procedure has been proposed for the synthesis of amines directly from cage hydrocarbons. A number of cage amines have been synthesized by treatment of adamantane, its homologs, and structurally related cage hydrocarbons with nitric acid in acetic acid and subsequent addition of urea and heating.     

Synthesis of di(adamantylalkyl) tosyloxymethylphosphonates and di(adamantyloxyalkyl) tosyloxymethylphosphonates

A simple method for the synthesis of esters of tosyloxymethylphosphonic acid based on the adamantane series of alcohols and diethyl tosyloxymethyl phosphonate was developed. The di(adamantylalkyl) and di(adamantyloxyalkyl) tosyloxymethylphosphonates are of interest as key compounds in the synthesis of antiviral drugs of the nucleoside phosphonate class.     

Synthesis of substituted 1-[2-(adamantan-1-yl)ethyl]piperidines

Quaternary 1-[2-(adamantan-1-yl)ethyl]pyridinium bromides were reduced with sodium tetrahydridoborate in ethanol, and hydroarylation of the resulting 1-[2-(adamantan-1-yl)ethyl]-1,2,3,6-tetrahydropyridines with benzene in trifluoromethanesulfonic acid afforded phenylpiperidines with preferentially equatorial orientation of the phenyl substituent.     

Synthesis of Chiral Ligands on the Basis of 1-(Adamantan-1-yl)ethane-1,2-diamine

Russian Journal of Organic Chemistry - The reduction of 1-(adamantan-1-yl)-2-azidoethan-1-one oxime with LiAlH4 gave racemic 1-(adamantan-1-yl)ethane-1,2-diamine, which was resolved with l-tartaric...     

Synthesis of 2-[2-(2-aminophenyl)ethyl]-6-R-quinnoline-4-carboxylic acids from 2-[2-(2-nitrophenyl)ethenyl]-6-R-quinoline-4-carboxylic Acids

Russian Journal of Organic Chemistry -