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排序方式: 共有143条查询结果,搜索用时 31 毫秒
1.
A simple procedure for the synthesis of an important standard, isotopically enriched methylmercury, which is not commercially available, has been established successfully. The isotopically enriched standard synthesized is utilized in conventional isotope dilution mass spectrometry (IDMS), as well as in speciated IDMS (SIDMS), for determination of the true concentration of methylmercury in environmental samples. The CH3201Hg+ standard has been synthesized from commercially available 201HgO and tetramethyltin. The synthesis time required is 1 h at 60°C. The product is highly pure, yielding more than 90% as 201Hg in CH3201Hg+. Hazardous dimethylmercury does not occur during this synthesis procedure. The product synthesized was analyzed using high‐performance liquid chromatography coupled with inductively coupled plasma mass spectrometry (ICP‐MS) and ICP‐MS alone in order to determine its concentration, isotopic composition and purity. The stability of the product was also evaluated for over 6 months and found to be stable at 4°C in the dark. The isotopically enriched methylmercury synthesized can be used in SIDMS and IDMS analyses as a standard. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
2.
Z. V. I. Zaretskii E. E. Kingston J. H. Beynon R. Lauber U. P. Schlunegger 《Journal of mass spectrometry : JMS》1985,20(5):336-342
Collision-induced dissociation mass-analysed ion kinetic energy spectrometry and translational energy release studies have established that provitamin D3 (7-dehydrocholesterol), provitamin D2 (ergosterol), vitamin D3 and vitamin D2 isomerizations in the mass spectrometer occur at the fragment ion level leading to [M? H2O? CH3]+ ions of identical structure. It was found that the reaction, [M]+˙→[M? H2O]+˙, plays a central role in these isomerizations. 相似文献
3.
James A. Ballantine Jonathan D. Barton James F. Carter Jeremy P. Davies Keith Smith Geoffrey Stedman Eric E. Kingston 《Journal of mass spectrometry : JMS》1988,23(1):1-5
The mass spectra of a number of aliphatic nitro compounds have been studied using electron Ionization (EI) and a variety of chemical Ionization (CI) techniques in attempts to obtain relative molecular mass information. The use of positive ion ammonia chemical Ionization techniques gave very satisfactory results, providing abundant [M + NH4]+ ions, not only from both primary and secondary nitro compounds, but also from the much more labile tertiary nitro compounds. However, the use of methane and isobutane positive ion CI or EI conditions resulted in facile fragmentation with little relative molecular mass information being made available. Negative ion CI using methane, isobutane or ammonia as moderating gases all gave abundant [M ? 1]? ions with primary and secondary nitro compounds but at much reduced sensitivity. 相似文献
4.
The thermal behaviour of several complexes of rhodium has been investigated. Complexes containing nitrogen ligands readily decompose to the oxide, Rh2O3? Complexes with phosphorus and arsenic ligands decompose to the same oxide of rhodium, although difficulty is encountered in removing all the phosphorus and arsenic. The suitability of the decomposition to Rh2O3 as an analytical technique for rhodium is discussed. 相似文献
5.
Robert Flammang Philippe Meyrant Andr Maquestiau Eric E. Kingston John H. Beynon 《Journal of mass spectrometry : JMS》1985,20(3):253-257
Charge-stripping spectra have been used to differentiate ionized cyclopentadiene from its acyclic isomers. The minimum amounts of translational energy lost during the charge-stripping processes and the relative charge-stripping efficiencies, which are also structurally important parameters, have been measured for these ionic species. [C5H6]+˙ ions, formed by dissociative ionization of various precursors in the ion source are found, usually, to be a mixture of cyclic and acyclic ions. In contrast, [C5H6]+˙ ions, derived from the dissociation of metastable molecular ions from a series of organic compounds, have the cyclopentadienyl structure. This structure was confirmed by collision-induced dissociation of ions formed in the first field-free region of a triple sector mass spectrometer. 相似文献
6.
The reactivity of the epoxy-fulvene 1 with various nucleophiles has been examined. It is a versatile Intermediate for the preparation of spiro[4.2]hepta-1,3-diene synthons via nucleophilic addition to the C6 position followed by intramolecular cyclization of the substituted cyclopentadiene anion generated in situ. 相似文献
7.
8.
John S. Waterhouse John G. Kingston 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》1973,24(4):653-658
Summary The general solution is given for steady two-dimensional magnetohydrodynamic flows of an incompressible, inviscid, fluid having infinite electrical conductivity when the angle between the magnetic field and the velocity field is every where constant.
Résumé On donne ici la série complète des solutions pour les écoulements magnéto-hydrodynamiques permanents bidimensionnels d'un fluide incompressible, non-visqueux ayant une conductivité électrique infinie lorsque l'angle entre le champ magnétique et le champ de vitesse est partout constant.相似文献
9.
John F. Kingston 《Tetrahedron letters》1980,21(44):4295-4298
Two new 26 carbon steroids with 128 oxygen functions were isolated from the soft coral and their structures determined from their spectral data and chemical transformations. 相似文献
10.
Eric E. Kingston James S. Shannon Michael J. Lacey 《Journal of mass spectrometry : JMS》1983,18(5):183-192
Rearrangements reported in the literature for positive ions formed by chemical ionization are briefly reviewed, with particular emphasis on illustrative examples of hydrogen and skeletal rearrangements. 相似文献