Individually addressable recessed gold microelectrode arrays with monolayers of thio-cyclodextrin nanocavities

Four, individually addressable 30 microm diameter, e-beam deposited, gold microelectrodes recessed by 6 microm were suitably spaced on a single substrate to avoid diffusional overlap between each microelectrode. The single substrate device was functionalised with thiolated alpha-, beta-, and gamma-cyclodextrin nanocavities without spacer groups to ensure close proximity of the cavities to the electrode surface. The microelectrodes were assessed in two stages. The e-beam deposited micron sized electrodes were characterized using models for recessed and inlaid microdisk electrodes. Subsequently, each individually addressable, atomically flat, micro-patterned gold electrode with thiolated CD ensembles was treated as a nanoporous electrode assembly. Theoretical and experimental results were compared using cyclic voltammetry. Atomic force microscopy was also used to characterise the modified microelectrodes. Comparisons were made with thiolated CDs deposited on macroelectrodes. This is the first report of the behaviour of immobilized CD nanocavities ensembles on atomically flat gold microelectrodes.     

A robust-adaptive fuzzy coverage control for robotic swarms

In this paper, a decentralized adaptive control scheme for multi-robot coverage is proposed. This control method is designed based on centroidal Voronoi configuration integrated with robust adaptive fuzzy control techniques. We consider simple single integrator mobile robots used for covering dynamical environments, where an adaptive fuzzy logic system is used to approximate the unknown parts of control law. A robust coverage criterion is used to attenuate the adaptive fuzzy approximation error and measurement noises to a prescribed level. Therefore, the robots motion is forced to obey solutions of a coverage optimization problem. The advantages of the proposed controller can be listed as robustness to external disturbances, computation uncertainties, and measurement noises, while applicability on dynamical environments. A Lyapunov-function based proof is given of robust stability, i.e. convergence to the optimal positions with bounded error. Finally, simulation results are demonstrated for a swarm coverage problem simultaneous with tracking mobile intruders.     

Operations research in the space industry

Operations research techniques have been used in the space industry since its infancy, and various competing methods and codes, with widely varying characteristics, have been used over time. This survey is intended to give an overview of current application cases of different operations research techniques and methodologies in the domain of space engineering and space science.     

The Processing of Pyrolysis Fuel Oil by Dielectric Barrier Discharge Plasma Torch

In present paper, an atmospheric-pressure low-temperature plasma treatment of pyrolysis fuel oil (PFO) was investigated in dielectric barrier discharge plasma torch reactor. The effect of the applied voltage and the volume of feedstock, as the main parameters, on the cracking of PFO were studied. By increasing the applied voltage from 10 to 16 kV, the production rate of hydrocarbons containing methane, ethylene, acetylene, propane, propylene, and C₄ rise 18 times. In this case, the production rate of hydrogen increases by approximately 14 times and reaches 7.27 × 10^?3 mol/min for 16 kV. In the feedstock volume investigation, based on limitation of reactor volume, the production rate of hydrocarbons decreased from 0.44 × 10^?3 to 0.15 × 10^?3 mol/min by increasing volume of feedstock from 1 to 5 cc.     

Photocatalytic ozonation for degradation of 2-sec-butyl-4,6-dinitrophenol (DNBP) using titanium dioxide: effect of operational parameters and wastewater treatment

The results of degradation efficiency of 2-sec-butyl-4,6-dinitrophenol (DNBP) in a batch system by various advanced oxidation processes revealed the order of TiO₂/UV/O₃ > TiO₂/O₃ > UV/O₃ > O₃ > UV/TiO₂. All processes followed pseudo-first order kinetics. The influence of operational parameters such as initial pH, initial concentration of DNBP, ozone and catalyst dosage on the TiO₂/UV/O₃ process, which was the most significant investigated method. The ozone dosage was found to have the noticeable impact on the process; however, initial pH and TiO₂ dosage were less effective. The mineralization of 40 mg/L of DNBP and petrochemical wastewater under the obtained optimal conditions was monitored by total organic carbon and chemical oxygen demand, respectively. The results demonstrated that the TiO₂/UV/O₃ process was a very effective method for degradation and mineralization of DNBP in aqueous solutions and industrial wastewater. The degradation intermediates were identified by GC–MS.