全文获取类型
收费全文 | 417篇 |
免费 | 13篇 |
国内免费 | 7篇 |
专业分类
化学 | 256篇 |
晶体学 | 2篇 |
力学 | 26篇 |
数学 | 58篇 |
物理学 | 95篇 |
出版年
2023年 | 3篇 |
2022年 | 4篇 |
2021年 | 7篇 |
2020年 | 10篇 |
2019年 | 18篇 |
2018年 | 15篇 |
2017年 | 17篇 |
2016年 | 24篇 |
2015年 | 17篇 |
2014年 | 25篇 |
2013年 | 54篇 |
2012年 | 20篇 |
2011年 | 38篇 |
2010年 | 30篇 |
2009年 | 33篇 |
2008年 | 21篇 |
2007年 | 23篇 |
2006年 | 12篇 |
2005年 | 10篇 |
2004年 | 9篇 |
2003年 | 8篇 |
2002年 | 9篇 |
2001年 | 4篇 |
2000年 | 3篇 |
1999年 | 2篇 |
1998年 | 2篇 |
1997年 | 1篇 |
1995年 | 1篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1992年 | 3篇 |
1991年 | 1篇 |
1990年 | 2篇 |
1984年 | 1篇 |
1982年 | 1篇 |
1980年 | 2篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1975年 | 3篇 |
排序方式: 共有437条查询结果,搜索用时 31 毫秒
1.
2.
3.
Echabaane M. Hfaiedh S. Smiri B. Saidi F. Dridi C. 《Journal of Solid State Electrochemistry》2021,25(6):1797-1806
Journal of Solid State Electrochemistry - The fast and sensitive detection of copper ions would be essential for water monitoring. Herein, we report a novel development of an impedimetric sensor... 相似文献
4.
Kazem Ghanbari 《Positivity》2006,10(4):721-729
We denote the spectrum of an square matrix A by σ(A), and that of the matrix obtained by deleting the first i rows and columns of A by σi(A). It is known that a symmetric pentadiagonal oscillatory (SPO) matrix may be constructed from σ, σ1 and σ2. The pairs σ, σ1 and σ1, σ2 must interlace; the construction is not unique; and the conditions on the data which ensure that A is oscillatory are extremely complicated. Given one SPO matrix A, the paper shows that operations may be applied to A to construct a family of such matrices with σ and σ1 in common. Moreover, given one totally positive (TP) matrix A, we construct a family of TP matrices with σ, σ1 and σ2 in common. 相似文献
5.
6.
Treatment of aliphatic and aromatic aldehydes with chiral amines and trimethylsilyl cyanide in the absence or in the presence
of Lewis acids (including lithium perchlorate) under solvent-free conditions afforded the corresponding α-aminonitriles in
good yields and with a diastereoselectivity of 68 to 86%.
Published in Russian in Zhurnal Organicheskoi Khimii, 2006, Vol. 42, No. 1, pp. 56–59.
The text was submitted by the authors in English. 相似文献
7.
Ahmad Rouhollahi Mohammad Kazem Amini Mojtaba Shamsipur 《Journal of solution chemistry》1994,23(1):63-74
Proton NMR was used to study the complexation reaction between lead ion and 18-crown-6 in a number of binary acetonitrile-water mixtures. Formation constant for the resulting 11 complexes in different solvent mixtures was determined by computer fitting of the chemical shift-mole ratio data. There is an inverse relationship between the complex stability and amount of water in the mixed solvent. The dissociative kinetics of the complex was studied by proton line-shape analysis. The Arrhenius plots showed a distinct isokinetic temperature at about 25°C at which the decomplexation rate is more or less independent of the solvent composition. the complexation rate and the activation parameters E
a
, H and S, for the exchange have been determined and found to be strongly solvent dependent. There is actually a linear relationship between the mole fraction of acetonitrile in the mixed solvent and logarithm of the stability constant as well as activation parameters. 相似文献
8.
Iodine, was found to be a practical and novel catalyst for the reaction of aminal and trimethylsilyl cyanide under mild and neutral reaction condition to afford the corresponding α-aminonitriles in high yields and short reaction times. Trimethylsilyl iodide derived in situ from elemental iodine and trimethylsillyl cyanide catalyzed this conversion. 相似文献
9.
A highly regioselective ring opening of epoxides and aziridines can be carried out efficiently with acetic anhydride to form the acetates of the corresponding 1,2-diols and 2-amino-alcohols, respectively, using ammonium-12-molybdophosphate (AMP) as a heterogeneous catalyst, at room temperature, in the absence of solvent. 相似文献
10.
An efficient method for the enantioselective 1,4-conjugate addition of amines to α,β-unsaturated esters containing an inexpensive chiral auxiliary, such as (S)-2-methyl-1-butanol and fenchyl alcohol, in solvent-free conditions mediated by solid lithium perchlorate is reported. Over 12 examples of the products are generated in excellent yields, accompanied by moderate enantioselectivity. The concentrated solution of LiClO4 in a diethyl ether system works well for the enantioselective 1,4-addition of organolithium compounds to α,β-unsaturated amides without any side reactions. 相似文献