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Galal H. Elgemeie Wafaa A. Zaghary Tamer M. Nasr Kamelia M. Amin 《Journal of carbohydrate chemistry》2013,32(6):345-356
Reported is the first method to prepare a new class of thienopyrazole thioglycosides via a one‐pot reaction of the sodium thienopyrazolthiolate salts with 2,3,4,6‐tetra‐O‐acetyl‐α‐D‐gluco‐and galactopyranosyl bromides. The sodium thienopyrazolthiolate salts are prepared using pyrazoldithioic acids and their corresponding mono ‐ and dithiolate salts. 相似文献
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8-Chloro-7-formyl-4-oxo-2-phenyl-4H-pyrimido[1,2-a]pyrimidine-3-carbonitrile ( 3 ) is constructed using N-(5-cyano-6-oxo-4-phenyl-1,6-dihydropyrimidin-2-yl) acetamide ( 2 ) via Vilsmeier-Haack formylation reaction. Compound 3 reacted with 3-(triethoxysilyl)propan-1-amine under different conditions. Condensation of pyrimidopyrimidine 3 with thiosemicarbazone derivative gave Schiff base 8 , which upon treating with Vilsmeier-Haack reagent afforded pyrazole carbothioamide 9 . Cyclocondensation of compound 3 with some binucleophiles namely thiocarbohyrazide, hydrazine carbodithioic acid, benzyl hydrazinecarbodithioate and/or 2-thioxopyrimidinone was investigated. Structures of the new synthesized compounds were confirmed by their analytical and spectral data. 相似文献
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The buildup of poly(L-glutamic acid) (PGA) and poly(L-lysine) (PLL) multilayers on beta-FeOOH colloidal particles was investigated by means of electro-optics and electrophoresis. The films were built at different (acidic) pH in the absence of salt. We found that the thickness of the film grows linearly when the fully charged PLL (at pH 5.5) is combined with almost fully charged PGA (at pH 6.5), with a thickness of about 2 nm per single layer. When the fully charged PLL is combined with weakly charged PGA (at pH 4.5), the film thickness increases exponentially with the number of deposited layers. The thickness of the exponentially growing film increases to 300 nm after deposition of 16 layers. The exponential film growth is attributed to the ability of the PLL to diffuse "in" and "out" of the film bulk at each deposition step. The variation in the electrical polarizability of the film-coated particles was also monitored as a function of the number of adsorbed layers. The result reveals that the PLL chains, which can diffuse into the film bulk, have no measurable contribution to the electro-optical effect of the films terminated with PLL. It is only due to the polarization of counterions of the PLL adsorbed on the film surface. 相似文献
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The interaction of bright solitons with impurities in the on-site anisotropy of a ferromagnetic chain is studied. This type of impurities leads to linear and nonlinear perturbing terms in the corresponding nonlinear Schrödinger equation. We have found static soliton-impurity bound states and considered the conditions for their formation. For large values of the anisotropy the character of the impurities is mainly linear. The interaction of propagating solitons with the impurities is also investigated. We have obtained that the solitons can be transmitted, trapped or reflected. The behavior depends on the soliton velocity and width, magnetic parameters and the impurity strength. 相似文献
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Y Zhu J Wyrick KD Cohen KM Magnone C Holzke D Salib Q Ma D Sun L Bartels 《J Phys Condens Matter》2012,24(35):354005
Acetylene on Cu(111) is investigated by scanning tunnelling microscopy (STM); a surface pattern previously derived from diffraction measurements can be validated, if the variation of the STM image transfer function through absorption of an acetylene molecule onto the tip apex is taken into account. Density functional theory simulations point to a balance between short-range repulsive interactions of acetylene/Cu(111) associated with surface stress and longer range attractive interactions as the origin of the ordering. 相似文献
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Marina T. Primatarowa Radostina S. Kamburova 《Central European Journal of Physics》2012,10(5):1102-1108
We present a study of the ferromagnetic spin chain with both first- and second-neighbor interactions. We obtain the condition for the appearance and stability of bright and dark solitons for arbitrary wave number in the Brillouin zone. The influence of the second-neighbor interaction and the anisotropy on the soliton properties is considered. The scattering of dark solitons from point defects in the discrete spin chain is investigated numerically. 相似文献
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Mary Kamburova 《Mikrochimica acta》1998,128(3-4):177-180
The interaction of Cr(VI) and Nitrotetrazolium Blue has been examined. A 12 NTB (CrO3Cl)2 ion-associate is formed and is extractable into 1,2-dichloroethane. The optimum conditions have been established. The molar absorptivity at 260 nm was (8.2 ± 0.06) × 104L mol–1cm–1. Beer's law was obeyed in the range 0.01–0.4 g ml–1 Cr(VI). A sensitive and selective method for determination of micro-quantities of Cr(VI) in soils and steels is suggested. 相似文献
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Layer-by-layer deposition of sodium carboxymethylcellulose (NaCMC) and chitosan (CHI) was used to create polyelectrolyte multilayers on ellipsoidal beta-FeOOH particles at low ionic strength. Using electro-optics, we investigated the formation of films in dependence on the polyelectrolyte charge density by controlling pH of the dipping solutions. We found out a linear growth of the CMC/CHI films when they are constructed from highly charged CHI (at pH 4.0) and weakly charged NaCMC (at pH 4.0 and 5.5). The hydrodynamic thickness of the film constructed at pH 4.0/4.0 is unusually large for a linearly growing film (ca. 220 nm after deposition of 8 bilayers), but it strongly decreases (ca. 4 times) with increasing ionization of NaCMC (at pH 5.5). In both cases, the multilayer buildup proceeded through a series of adsorption-desorption steps. This was explained by a partial loss of CHI from the film surface on exposure to the solution of longer NaCMC molecules. The irregular film growth correlated quite well with the variations in the electrical polarizability of the polymer-coated particles. This correlation enabled us to conclude that the adsorption of both polymers occurs only on the film surface, with no diffusion in and out of the film bulk during deposition of each CMC/CHI bilayer. 相似文献