卤化氢共振增强多光子电离光谱

测定了卤化氢(HCl, HBr 和HI) (2+1)共振增强多光子电离(REMPI)光谱, 采用模拟计算法分析推导出转动常数、谱带源以及Ω态振动谱带的同位素位移值. 得到的HCl数据同Green等人用常规分析法所推导的结果极为吻合. 得出8条振动谱带,其中包括V(¹∑⁺)态, E(¹∑⁺)的v'=4态以及HBr的5个新谱带, 此外还推导出HI的E态v'=1的4个振动谱带光谱参数. 观测了V和E态之间因同类相互作用而产生的不规则能级间距、转动参数和同位素位移. 讨论了HCl和HBr的E态和V态振动谱带中的转动谱线序列O和S对Q的强度比变化,提出了双光子激发机理.     

Three-photon absorption spectroscopy: the L(1Φ3) and m(3II1) states of HCl and DCl

Analysis of (3+1) REMPI room temperature spectra by use of three-photon absorption modelling allowed, for the first time, identification and characterization of Ω = 3, Φ states (L(¹Φ₃)) in HCl and DCl and of the m(³II₁) state in DCl. Simulation analyses and determination of isotope shifts allowed evaluation of vibrational and rotational spectroscopic parameters for both states and both molecules. The mechanism of three-photon absorption in the m(³II₁) ← X(¹Σ⁺) transition is discussed.