全文获取类型
收费全文 | 18413篇 |
免费 | 779篇 |
国内免费 | 352篇 |
专业分类
化学 | 7884篇 |
晶体学 | 379篇 |
力学 | 1128篇 |
综合类 | 16篇 |
数学 | 1676篇 |
物理学 | 8461篇 |
出版年
2023年 | 121篇 |
2022年 | 238篇 |
2021年 | 252篇 |
2020年 | 238篇 |
2019年 | 254篇 |
2018年 | 329篇 |
2017年 | 282篇 |
2016年 | 448篇 |
2015年 | 368篇 |
2014年 | 509篇 |
2013年 | 941篇 |
2012年 | 1133篇 |
2011年 | 1412篇 |
2010年 | 986篇 |
2009年 | 943篇 |
2008年 | 1111篇 |
2007年 | 1050篇 |
2006年 | 1060篇 |
2005年 | 841篇 |
2004年 | 746篇 |
2003年 | 584篇 |
2002年 | 544篇 |
2001年 | 950篇 |
2000年 | 645篇 |
1999年 | 546篇 |
1998年 | 356篇 |
1997年 | 362篇 |
1996年 | 274篇 |
1995年 | 232篇 |
1994年 | 226篇 |
1993年 | 171篇 |
1992年 | 189篇 |
1991年 | 162篇 |
1990年 | 164篇 |
1989年 | 127篇 |
1988年 | 106篇 |
1987年 | 91篇 |
1986年 | 75篇 |
1985年 | 79篇 |
1984年 | 61篇 |
1983年 | 39篇 |
1982年 | 30篇 |
1981年 | 28篇 |
1980年 | 17篇 |
1978年 | 17篇 |
1977年 | 18篇 |
1976年 | 27篇 |
1975年 | 27篇 |
1974年 | 20篇 |
1973年 | 19篇 |
排序方式: 共有10000条查询结果,搜索用时 471 毫秒
1.
Li Y. Shi W. H. Dong L. M. Xu S. X. Huang H. J. Yin J. R. 《Journal of Applied Spectroscopy》2022,89(3):534-541
Journal of Applied Spectroscopy - Sr3B2O6:Dy3+, Eu3+ single-matrix white-light-emitting materials are prepared using the high-temperature solid-state method. The microstructure, emission spectrum,... 相似文献
2.
Atopic dermatitis is characterized by leukocyte migration into the skin dermis and typically driven by excessive chemokine production at the site of inflammation. Conventional topical formulations such as gels, creams, and ointments are insufficient for this treatment because of low penetration of drug molecules into the targeted skin tissues. Herein, using a simple, green, sustainable strategy, we have developed novel primary zein nanoparticles embedded in curcumin (Cur) and coated with silk sericin (ZHSCs) for the topical delivery of Cur to penetrate into the dermis and exercise anti-dermatitis effects on the lesion with minimal side-effects. Transdermal delivery experiments and porcine skin fluorescence imaging indicated that ZHSCs facilitate the penetration of Cur across the epidermis layer of skin to reach deep-seated sites. Notably, ZHSCs = 1:0.25 (zein-to-silk sericin mass ratios of 1:0.25) markedly elevated the skin permeability and cumulative turnover of Cur transferred, which were provided a greater than a 3.8-fold increase relative to free Cur. The special nanoparticles of ZHS = 1:0.25 possessed the deepest localization depth and experience a transition of the particle structure and core-shell separation after penetrating into the dermis of skin. In a cell model of dermatitis induced by tumor necrosis factor α/interferon γ co-stimulation, compared with free Cur, Cur-loaded ZHS nanoparticles down-regulated the generation of inflammatory cytokines and chemokines in keratinocytes through suppression of the nuclear translocation of NF-κBp65 and hence exerted an anti-dermatitis effect. This strategy may provide new avenues and direction for the demanding issues of valid topical delivery systems. 相似文献
3.
4.
Su X. F. Zhang Y. L. Maximov A. L. Zhang K. Xin Q. Feng C. Q. Bai X. F. Wu W. 《Russian Journal of Applied Chemistry》2020,93(1):127-136
Russian Journal of Applied Chemistry - Nanoscale ZSM-5 (AlZ5-D) and Ga-substituted ZSM-5 zeolites ((Al,Ga)Z5-D and GaZ5-D) were synthesized by a green dry-gel conversion strategy. For comparison,... 相似文献
5.
Journal of Thermal Analysis and Calorimetry - In the present work, pyrolysis kinetic mechanism was studied for regenerated cellulosic fiber (RCF) and composite RCF containing silicon/nitrogen flame... 相似文献
6.
Efficient control of regioselectivity is a key concern in transition-metal-catalyzed direct C–H functionalization reactions. Various strategies for regiocontrol have been established by tuning the selectivity of the C–H activation step as a common mode. Herein, we present our study on an alternative mode of regiocontrol, in which the selectivity of the C–H activation step is no longer a key concern. We found that, in a reaction where the C–H activation step exhibits a different regio-preference from the subsequent functionalization step, a ligand-enabled switch of the regioselectivity-determining step could provide efficient regiocontrol. This mode has been exemplified by the Pd(ii)-catalyzed aerobic oxidative Heck reaction of indoles, in which a ligand-controlled C3-/C2-selectivity was achieved for the first time by the development of sulfoxide-2-hydroxypyridine (SOHP) ligands.Ligand-enabled switch of the regioselectivity-determining step allowed for efficient regiocontrol in the aerobic oxidative Heck reaction of indole. 相似文献
7.
采用量子统计系综理论,研究了基态NO分子宏观气体摩尔熵、摩尔内能、摩尔热容等热力学性质.首先应用课题组前期建立的变分代数法(variational algebraic method, VAM)计算获得了基态NO分子的完全振动能级,得到的VAM振动能级作为振动部分,结合欧拉-麦克劳林渐进展开公式的转动贡献,应用于经典的热力学与统计物理公式中,从而计算得到了1000-5000 K温度范围内NO宏观气体的摩尔内能、摩尔熵和摩尔热容.将不同方法计算得到的摩尔热容结果分别与实验值进行比较,结果表明基于VAM完全振动能级获得的结果优于其他方法获得的理论结果.振动部分采用谐振子模型对无限能级求和计算热力学性质的方法有一定的局限性,应当使用有限的完全振动能级进行统计求和. 相似文献
8.
9.
Zhang Kailun Wu Hongjuan Wang Tian Yao Meng Xie Jixing Jiao Yunhong 《Journal of Thermal Analysis and Calorimetry》2021,145(6):3067-3075
Journal of Thermal Analysis and Calorimetry - A phosphazene-based flame retardant (PBFA) was synthesized by hexachlorocyclotriphosphazene and N-aminoethylpiperazine. To improve the flame retardancy... 相似文献
10.
Kinetics and Catalysis - A series of Cu-SSZ-13@CeO2 catalysts with surface modification with CeO2 was prepared by the modified self-resemble method based on the one-pot synthesized Cu-SSZ-13... 相似文献