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排序方式: 共有271条查询结果,搜索用时 15 毫秒
1.
We investigate the rate of convergence of the Wong-Zakai approximations for second-order stochastic PDEs of parabolic type
driven by a multi-dimensional Wiener
process W.
The title of this article in the online version was published incorrectly. The correct title appears above. Springer regrets
the error. The online version of the original article can be found at 相似文献
2.
Ferenc Sztaricskai Gyula Batta Zoltan Dinya Istvan F. Pelyvas Pal Herczegh Tamas E. Gunda Istvan Koczka 《Chemistry of Heterocyclic Compounds》1998,34(11):1296-1307
Starting from 3,5-dimethylisoxazole the carboxylic acids I and V, the amino acids VIII (L-) and IX (D-), and the ureido acids X (L-) and XI (D-) were prepared, which were used for the synthesis of the new cephalosporins XVIIb, XXa-c (L-), and XXIb (D-). Thein vitro antibacterial activity of these semi-synthetic antibiotics was studied. The resorption of XVIIb was investigated in mice.Research Group for Antibiotics of the Hungarian Academy of Sciences, H-4010 Debrecen, P.O. Box 70, Hungary. Published in Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1524–1535, November, 1998. 相似文献
3.
Mets motifs, which refer to methionine-rich sequences found in the high-affinity copper transporter Ctr1, also appear in other proteins involved in copper trafficking and homeostasis, including other Ctrs as well as Pco and Cop proteins isolated from copper-resistant bacteria. To understand the coordination chemistry utilized by these proteins, we studied the copper binding properties of a peptide labeled Mets7-PcoC with the sequence Met-Thr-Gly-Met-Lys-Gly-Met-Ser. By comparing this sequence to a series of mutants containing noncoordinating norleucine in place of methionine, we confirm that all three methionine residues are involved in a thioether-only binding site that is selective for Cu(I). Two independent methods, one based on mass spectrometry and one based on rate differences for the copper-catalyzed oxidation of ascorbic acid, provide an effective K(D) of approximately 2.5 microM at pH 4.5 for the 1:1 complex of Mets7-PcoC with Cu(I). These results establish that a relatively simple peptide containing an MX(2)MX(2)M motif is sufficient to bind Cu(I) with an affinity that corresponds well with its proposed biological function of extracellular copper acquisition. 相似文献
4.
Kaldor I Feldman PL Mook RA Ray JA Samano V Sefler AM Thompson JB Travis BR Boros EE 《The Journal of organic chemistry》2001,66(10):3495-3501
The quaternizations of dibenzoquinolizines 9 and 14 with 3-halo-1-propanols are highly cis-selective (94-100% cis), results consistent with the N-methylation of O-methylcapaurine (7b), but in contrast to the proposed trans-stereochemistry of dibenzo[a,h]quinolizine methiodide 10 and the analogous quaternizations of 1-benzyl- and 1-phenylisoquinoline congeners 5b and 5c. In this report, we describe stereoselective preparation of the unique cis-dibenzoquinolizinium propanols 15 and 16and their transformation into bis- and mixed-onium chlorofumarates 19, 20ab, and 26. Dibenzo[a,g]quinolizinium propanol 15 was prepared enantioselectively in three steps from dihydroisoquinoline 11. Asymmetric transfer hydrogenation of 11 in the presence of triethylamine/formic acid and Noyori's chiral ruthenium catalyst 12 produced R-(-)-5',8-dimethoxynorlaudanosine (13) in 98% yield and 87% ee. Pictet-Spengler cyclization of 13 in formalin/formic acid afforded the dibenzo[a,g]quinolizine 14 in 65% yield. Quaternization of 14 with 3-chloro-1-propanol under Finkelstein conditions generated cis-dibenzoquinolizinium propanol 15 in 85% yield with >94% cis-selectivity. The cis-dibenzo[a,h]quinolizinium propanol 16 was obtained as a single stereoisomer by reaction of the known tetramethoxyquinolizine 9 with neat 3-iodo-1-propanol. Bis-onium chlorofumarates 18 and 19 and the mixed-onium derivative 20ab were prepared by a pool synthesis procedure from (1R)-trans-6a, 16, and chlorofumaryl chloride (17). Mixed-onium alpha-chlorofumarate 26 was synthesized from (1S)-trans-6d, 15 and (+/-)-trans-2,3-dichlorosuccinic anhydride (22), employing a recently disclosed chlorofumarate mixed-diester synthesis. The title compounds (19, 20ab, and 26) displayed curare-like effects of ultrashort duration in rhesus monkeys. 相似文献
5.
Enantiomerically pure syn-anti and syn-syn configured triol units are efficiently synthesized by the SnCl4 mediated allylation of chiral α-benzyloxyaldehydes with the uniquely functionalised allylstannane 9. Remarkably, the stereochemistry of the adducts is solely governed by the amount of Lewis acid employed. 相似文献
6.
7.
G. F. Gantefor D. M. Cox A. Kaldor 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1991,19(4):59-61
In this paper we describe the application of a special form of electron photodetachment spectroscopy, zero electron kinetic energy (ZEKE) spectroscopy, to the study of cold metal cluster anions. From this study we have obtained vibrational and thus structural information of several neutral and charged clusters, e.g. Au 2 ?/0 , Ag 3 ?/0 , Sn 2 ?/0 and Al 3 ?/0 . In addition, in separate measurements of the relative photodetachment cross section of Au 2 ? , we have discovered sharp resonances which are due to electronic autodetachment from a short lived excited state. 相似文献
8.
Istvan Bakk Dietrich Gudat Stefan Hp Martin Nieger Lszl Nyulaszi Lszl Szarvas 《无机化学与普通化学杂志》2005,631(1):47-54
Reactions of the phosphonio‐benzophospholide π‐complexes 3a, b[Cr] with [M(CO)5(olefin)] or of the σ‐complexes 2a, b[M] (M = Cr, Mo, W) with [M(CO)3(aren)] lead to the first binuclear complexes 4a, b[CrM] featuring phosphonoio‐benzophospholides as μ‐bridging 8e‐donor ligands to two group 6 metal atoms. The constitution of the products was determined by spectroscopic and X‐ray diffraction studies. Mixed complexes with both group 6 and 7 metals were not accessible. Mechanistic studies showed that the reactions follow a complicated mechanism whose single steps may involve transfer of either M(CO)n fragments or single CO ligands between complexes; the latter are associated with a σ/π‐coordination isomerization of the benzophospholide unit. Competition between both reaction channels can lead to the formation of product mixtures whose composition is controlled by the relative thermodynamic stabilities of the products. Computational studies suggest that in the more stable isomer of heterobimetallic complexes 4a, b[MM′] end‐on coordination to the heavier and side‐on coordination to the lighter metal atom is preferred. 相似文献
9.
Jan Brunvoll Rgine Guidetti-Grept Istvan Hargittai Reinhart Keese 《Helvetica chimica acta》1993,76(8):2838-2846
The efficient synthesis of all-cis-[5.5.5.5]fenestrane ( 2 ) from the readily available intermediate 3 allowed the electron-diffraction analysis of 2 . This structure analysis revealed long C? C bonds in the central C(C)4 fragment and a twist-envelope conformation for the four cyclopentane substructures. The four bridgehead H-atoms are in a synclinal rather than an ecliptic position with an approximate D2 symmetry of 2 . Planarizing distortions are evident from the opposite bond angles at the central C-atom being 116.2 ± 0.5° with the remaining four being 103.7 ± 0.2°. 相似文献
10.
Istvan Hargittai 《Structural chemistry》2014,25(6):1597-1600
The stereochemist and steroid chemist Carl Djerassi turned poet, novelist, and playwright, published another autobiography taking stock of his prolific production of science-in-fiction during the last decades. He has been successful in bridging the gap between science and art. 相似文献