全文获取类型
收费全文 | 29885篇 |
免费 | 106篇 |
国内免费 | 274篇 |
专业分类
化学 | 11146篇 |
晶体学 | 278篇 |
力学 | 1401篇 |
综合类 | 12篇 |
数学 | 8950篇 |
物理学 | 8478篇 |
出版年
2018年 | 1192篇 |
2017年 | 1458篇 |
2016年 | 710篇 |
2015年 | 564篇 |
2014年 | 472篇 |
2013年 | 669篇 |
2012年 | 3144篇 |
2011年 | 2344篇 |
2010年 | 1820篇 |
2009年 | 1566篇 |
2008年 | 603篇 |
2007年 | 642篇 |
2006年 | 631篇 |
2005年 | 4473篇 |
2004年 | 3959篇 |
2003年 | 2345篇 |
2002年 | 527篇 |
2001年 | 332篇 |
2000年 | 135篇 |
1999年 | 184篇 |
1998年 | 130篇 |
1997年 | 84篇 |
1996年 | 62篇 |
1995年 | 59篇 |
1994年 | 68篇 |
1993年 | 42篇 |
1992年 | 194篇 |
1991年 | 176篇 |
1990年 | 148篇 |
1989年 | 127篇 |
1988年 | 124篇 |
1987年 | 72篇 |
1986年 | 60篇 |
1985年 | 61篇 |
1984年 | 56篇 |
1983年 | 40篇 |
1982年 | 37篇 |
1981年 | 40篇 |
1979年 | 46篇 |
1978年 | 43篇 |
1977年 | 38篇 |
1976年 | 100篇 |
1975年 | 57篇 |
1974年 | 51篇 |
1973年 | 53篇 |
1972年 | 43篇 |
1970年 | 36篇 |
1969年 | 39篇 |
1968年 | 42篇 |
1966年 | 43篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
Tetsuo Irifune Chiaki Ueda Shohei Ohshita Hiroaki Ohfuji Takehiro Kunimoto Toru Shinmei 《高压研究》2020,40(1):96-106
ABSTRACTNano-polycrystalline diamond (NPD) with various grain sizes has been synthesized from glassy carbon at pressures 15–25?GPa and temperatures 1700–2300°C using multianvil apparatus. The minimum temperature for the synthesis of pure NPD, below which a small amount of compressed graphite was formed, significantly increased with pressure from ~1700°C at 15?GPa to ~1900°C at 25?GPa. The NPD having grain sizes less than ~50?nm was synthesized at temperatures below ~2000°C at 15?GPa and ~2300°C at 25?GPa, above which significant grain growth was observed. The grain size of NPD decreases with increasing pressure and decreasing temperature, and the pure NPD with grain sizes less than 10?nm is obtained in a limited temperature range around 1800–2000°C, depending on pressure. The pure NPD from glassy carbon is highly transparent and exhibits a granular nano-texture, whose grain size is tunable by selecting adequate pressure and temperature conditions. 相似文献
2.
Julia K Pruns Jens-Peter Vietzke Manfred Strassner Claudius Rapp Ulrich Hintze Wilfried A K?nig 《Rapid communications in mass spectrometry : RCM》2002,16(3):208-211
A new solvent-free sample preparation method using silver trifluoroacetate (AgTFA) was developed for the analysis of low molecular weight paraffins and microcrystalline waxes by laser desorption/ionization time-of-flight mass spectrometry (LDI-TOFMS). Experiments show that spectral quality can be enhanced by dispersing AgTFA directly in liquid paraffins without the use of additional solvents. This preparation mixture is applied directly to the MALDI probe. Solid waxes could be examined by melting prior to analysis. The method also provides sufficiently reproducible spectra that peak area ratios between mono- and bicyclic alkane peaks indicated variations in the cycloalkane content of paraffin samples. Dehydrogenation of hydrocarbons observed during the desorption/ionization process was studied by analysis of alkane standards. 相似文献
3.
J Szeman H Ueda J Szejtli E Fenyvesi Y Machida T Nagai 《Chemical & pharmaceutical bulletin》1987,35(1):282-288
4.
The versatile behavior of a trihydrazidophosphoradamantane allowing the synthesis of a variety of neutral, mono- or di-cationic water-soluble molecules of potential interest for biphasic catalysis is reported. 相似文献
5.
In this paper we construct an example of a word metric on an infinite cyclic subgroup. This example shows that subexponential
distortion does not obstruct non-trivial growth of connected radii. This answers a question of Gromov [6]. The constructed
metric has other pathological properies. Specifically, its asymptotic cone depends on the choice of ultrafilter and scaling
sequence.
The work has been partially supported by the Swiss National Science Foundation. 相似文献
6.
We build a metric space which is homeomorphic to a Cantor set but cannot be realized as the attractor of an iterated function system. We give also an example of a Cantor set K in R3 such that every homeomorphism f of R3 which preserves K coincides with the identity on K. 相似文献
7.
Milan Medved? 《Journal of Mathematical Analysis and Applications》2002,267(2):643-650
A criterion for the nonexplosion of solutions to semilinear evolution equations on Banach spaces is proved. The result is obtained by applying a modification of the Bihari type inequality to the case of a weakly singular nonlinear integral inequality. 相似文献
8.
N Murakami T Morimoto H Imamura T Ueda S Nagai J Sakakibara N Yamada 《Chemical & pharmaceutical bulletin》1991,39(9):2277-2281
Seven new monogalactosyl diacylglycerols (1-7) and six new digalactosyl diacylglycerols (11-16) were isolated from an axenically cultured cyanobacterium, P. tenue. Their structures were elucidated on the basis of physicochemical evidence and the results of enzymatic hydrolysis using a lipase (from Rhizopus arrhizus). Comparison of antialgal activity for P. tenue between monogalactosyl diacylglycerols (1-8) and digalactosyl diacylglycerols (11-19) revealed that the former showed more potent activity than the latter. 相似文献
9.
We consider the one-dimensional steady-state semiconductor deviceequations modelling a pnpn device. There are two relevant scalingsof the equations corresponding to small and large applied voltages.In both scalings, the semiconductor equations can be consideredas singularly perturbed. It turns out that the small-voltagescaling breaks down for current values between two saturationcurrents. In that interval, the large-voltage scaling has tobe employed. For both scalings, we derive the first-order termsof an asymptotic expansion and show that the reduced problemhas a solution. An example verifies that the current-voltagecurves obtained have the expected qualitative structure. 相似文献
10.
Could simple intraannular-arm macrocyclic systems exist in enantiopure stable forms? The effective synthesis of two representative compounds of such a class, their resolution into enantiomers, and experiments justifying their stability toward racemization are presented. 相似文献