全文获取类型
收费全文 | 274篇 |
免费 | 2篇 |
专业分类
化学 | 125篇 |
力学 | 19篇 |
数学 | 62篇 |
物理学 | 70篇 |
出版年
2016年 | 2篇 |
2014年 | 2篇 |
2013年 | 4篇 |
2011年 | 2篇 |
2009年 | 1篇 |
2006年 | 2篇 |
2005年 | 9篇 |
2004年 | 9篇 |
2003年 | 14篇 |
2002年 | 14篇 |
2001年 | 12篇 |
2000年 | 12篇 |
1999年 | 10篇 |
1998年 | 1篇 |
1997年 | 3篇 |
1996年 | 4篇 |
1995年 | 6篇 |
1994年 | 5篇 |
1993年 | 5篇 |
1992年 | 8篇 |
1991年 | 5篇 |
1990年 | 3篇 |
1989年 | 6篇 |
1988年 | 3篇 |
1987年 | 3篇 |
1986年 | 7篇 |
1985年 | 10篇 |
1984年 | 7篇 |
1983年 | 8篇 |
1982年 | 6篇 |
1981年 | 4篇 |
1980年 | 1篇 |
1979年 | 4篇 |
1978年 | 15篇 |
1977年 | 6篇 |
1976年 | 7篇 |
1975年 | 3篇 |
1974年 | 4篇 |
1973年 | 8篇 |
1972年 | 5篇 |
1971年 | 5篇 |
1970年 | 4篇 |
1969年 | 7篇 |
1968年 | 7篇 |
1967年 | 8篇 |
1966年 | 4篇 |
1965年 | 1篇 |
排序方式: 共有276条查询结果,搜索用时 15 毫秒
1.
Maria G. Semenova Larisa E. Belyakova Anna S. Antipova Yu. N. Polikarpov Lida Klouda Anna Markovic Michael M. Il'in 《Colloids and surfaces. B, Biointerfaces》2003,31(1-4):47-54
We report on the effect of commercially important polysaccharides (maltodextrins with variable dextrose equivalent (Paselli SA-2, MD-6 and MD-10) on the surface activity at the air–water interface of small-molecule surfactants (sms), possessing different hydrophobic–lipophilic balance ((SSL (Na+), the main component is a sodium salt of stearol–lactoyl lactic acid, and PGE (080), polyglycerol ester of C18 fatty acid), and widely used in food products. A marked change of the surface activity of sms was found in the presence of maltodextrins by tensiometry. The combined data of laser multiangle light scattering and mixing calorimetry have suggested that this result is governed by specific complex formation between maltodextrins and sms in aqueous medium. Measurements have been made of the molar mass, the second virial coefficient and the enthalpy of intermolecular interactions in aqueous solutions. The implication of a degree of polymerization of maltodextrins in this phenomenon was shown. The interrelation between the molecular parameters of the formed complexes and their surface activity at the air–water interface has been revealed and discussed. 相似文献
2.
3.
M. A. Il'in P. Yu. Karasev N. A. Denisova A. V. Rezvov S. V. Tyurina 《Russian Physics Journal》1988,31(1):19-24
On the basis of numerical calculations and experimental studies we analyze the possibilities of measuring the electrophysical parameters of indium phosphide by means of infrared reflection spectra at wavelengths ranging from 5 to 200 m. We demonstrate that contactless nondestructive measurements of the electron density in the range 1016–1020 cm–3 can be made with a relative error not exceeding 15%, and of mobility with a relative error not exceeding 25%. A nomogram method is presented for rapid conversion of data from infrared reflection spectra into the parameters being measured.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 1, pp. 22–27, January, 1988. 相似文献
4.
S. G. Il'in M. V. Reshetnyak G. K. Oleinikova Yu. T. Struchkov 《Chemistry of Natural Compounds》1992,28(3-4):298-301
A complete x-ray structural investigation has been made of 3-acetoxy-22S,25-epoxyholosta-7,9(11)-dien-17-ol. Important conformational differences between this compound and its 17-deoxy derivative have been found which show the mobility of the conformation of rings B and C of the holostane series and the tetrahydrofuran ring of the side chain of the molecule. It has been shown that the conformation of the side chain of the molecule is stabilized by an 017-H...022 intramolecular hydrogen bond, without excluding the possibility of the participation of the hydroxy group in the formation of intermolecular hydrogen bonds (bifurcated).Pacific Ocean Institute of Bioorganic Chemistry, Far Eastern Branch, Russian Academy of Sciences, Vladivostok. Translated from Khimiya Prirodnykh Soedinenii, Nos. 3,4, pp. 341–344, May–August, 1992. 相似文献
5.
Yu. G. Gol'tsov L. A. Matkovskaya V. G. Voloshinets V. G. Il'in 《Theoretical and Experimental Chemistry》1995,30(5):254-258
Changing the cation composition (Na+ to K+, NH4
+ Cs+) of faujasite with hexacyanoferrate(II) encapsulated in the large pores causes distortion of the octahedral symmetry of the complex.Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 30, No. 5, pp. 293–297, September–October, 1994. 相似文献
6.
Bobonich F. M. Yaroshenko N. A. Solomakha V. N. Strelko V. V. Il'in V. G. 《Theoretical and Experimental Chemistry》2004,40(4):254-259
Under the conditions studied for the synthesis of mesophase materials with alkylpyridinium halides an increase in the density of packing of these molecules in the encapsulated micelles was observed with an increase in the length of the alkyl radicals. The difference in the density of packing of these surface active reagents (SAR) depended to a considerable extent on the perfection of the hexagonal structure and the characteristic absorption properties of the mesophase materials of MCM-41 type. 相似文献
7.
N. V. Turutina O. A. Pilyankevich A. I. Prilipko G. M. Tel'biz V. G. Il'in 《Theoretical and Experimental Chemistry》1995,31(1):44-47
The acid properties of intermediate products in crystallization of pentasil-type zeolites have been investigated using programmed thermal desorption of ammonia and adsorption of pyridine. It was found that acidity increases with increasing crystallinity due to proton-donor centers. A correlation was established between this change in acidity and methanol TPSR data.Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 31, No. 1, pp. 48–51, January–February, 1995. 相似文献
8.
9.
Yanishpolskii V. V. Pavlenko A. N. Tertykh V. A. Il'in V. G. Leboda R. Skubiszewska-Zieba J. 《Journal of Thermal Analysis and Calorimetry》2000,62(2):569-573
Mesoporous titanium-containing silicas with TiO2 contents from 1 up to 70 mol% were prepared. The obtained samples have been characterized by the powder X-ray diffraction
data, the diffuse reflectance infrared Fourier transform method, and nitrogen adsorption at 77 K. Specific surface area, total
pore volume, distribution pore volume on pore sizes were determined from nitrogen adsorption isotherm for synthesized titanosilicas.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
10.
V. A. Emel'yanov I. A. Baidina S. P. Khranenko S. A. Gromilov M. A. Il'in A. V. Belyaev 《Journal of Structural Chemistry》2003,44(1):37-45
The paper describes synthesis of (nBu4N)2[RuNOCl5](I), (nBu4N)2[RuNOCl4OH](II), (nBu4N)2×[RuNOCl4OH]·6H2O (III), and (nBu4N)2[RuNOCl5]· 2(nBu4N)2[RuNOCl4(H2O)]·2H2O (IV). The complexes were studied by IR spectroscopy and powder Xray and crystal Xray analyses. The structures are built up of [RuNOCl5]2- (I, IV), [RuNOCl4OH]2- (II, III), and [RuNOCl4(H2O)]- (IV) complex anions, (nBu4N)+ cations, and crystal water molecules (III, IV). The substances are moderately soluble in water; highly soluble in polar organic solvents, such as acetone, ethanol, chloroform, methylene chloride; and almost insoluble in carbon tetrachloride and toluene. Under storage in light, the compounds decompose from the surface; in darkness I and II are stable, whereas III and IV can lose part of the crystal water. 相似文献