全文获取类型
收费全文 | 89篇 |
免费 | 4篇 |
专业分类
化学 | 42篇 |
力学 | 2篇 |
数学 | 11篇 |
物理学 | 38篇 |
出版年
2021年 | 4篇 |
2019年 | 4篇 |
2018年 | 4篇 |
2017年 | 2篇 |
2016年 | 2篇 |
2015年 | 2篇 |
2013年 | 2篇 |
2012年 | 5篇 |
2011年 | 3篇 |
2010年 | 1篇 |
2009年 | 3篇 |
2008年 | 1篇 |
2007年 | 2篇 |
2006年 | 2篇 |
2005年 | 6篇 |
2004年 | 2篇 |
2003年 | 2篇 |
2002年 | 1篇 |
2001年 | 3篇 |
2000年 | 5篇 |
1999年 | 4篇 |
1996年 | 2篇 |
1995年 | 3篇 |
1994年 | 3篇 |
1993年 | 1篇 |
1992年 | 2篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1989年 | 2篇 |
1988年 | 3篇 |
1987年 | 1篇 |
1985年 | 1篇 |
1983年 | 1篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1971年 | 1篇 |
1969年 | 3篇 |
1966年 | 2篇 |
1935年 | 2篇 |
排序方式: 共有93条查询结果,搜索用时 15 毫秒
1.
Fry FH Holme AL Giles NM Giles GI Collins C Holt K Pariagh S Gelbrich T Hursthouse MB Gutowski NJ Jacob C 《Organic & biomolecular chemistry》2005,3(14):2579-2587
Certain cancer cells proliferate under conditions of oxidative stress (OS) and might therefore be selectively targeted by redox catalysts. Among these catalysts, compounds containing a chalcogen and a quinone redox centre are particularly well suited to respond to the presence of OS. These catalysts combine the specific electrochemical features of quinones and chalcogens. They exhibit high selectivity and efficiency against oxidatively stressed rat PC12, human Jurkat and human Daudi cells in cell culture, where their mode of action most likely involves the catalytic activation of existent and the generation of new reactive oxygen species. The high efficiency and selectivity shown by these catalysts makes them interesting for the development of anti-cancer drugs. 相似文献
2.
3.
The short-time intramolecular dynamics of highly vibrationally excited HCCD and DCCD, as determined by classical trajectories, have qualitative features distinct from HCCH and from one another. The possible differences are also considered from the point of view of the symmetries of the normal modes. The short-time evolution will be reflected in the coarse-grained frequency spectrum and could be detectable via stimulation emission pumping. 相似文献
4.
The yellowing of white and pastel coloured textiles and garments has been a problem for many years in the textile industry. In the last 15 years much evidence has been published which suggests that a large proportion of storage yellowing is attributable not to the yellowing of fibre substrate or textile finish but to the yellowing of phenolic antioxidants which migrate onto the textiles from polyethylene and polypropylene packaging. These mobile phenolic compounds interact with atmospheric pollutants, particularly oxides of nitrogen, to give yellow compounds. A brief outline of the problems of yellowing is given, together with the identification of the yellow substances produced by BHT (2,6-di-tert-butyl-4-methyl phenol) and possible mechanisms of their formation. Prophylactic measures that can be taken by the garment manufacturer and finisher to prevent or minimise yellowing are also discussed. 相似文献
5.
The complex formation in concentrated sulfuric acid between boric acid and quinalizarin (1,2,5,8-tetrahydroxyanthraquinone) or alizarin (1,2-dihydroxyanthraquinone) was studied by spectrophotometry. Both systems contained only one species, viz. a complex between one boric acid and one hydroxyanthraquinone molecules. The reactions of boric acid with hydroxyanthraquinones are discussed and compared with the reaction of boric acid with 1,1'-dianthrimide. 相似文献
6.
In this paper,we study the surface instability of a cylindrical pore in the absence of stress. This instability is called the Rayleigh-Plateau instabilty. We consider the model developed by Spencer et ... 相似文献
7.
Ebraheem Abdu Musad Saleh Abdullah Mohammed AL Dawsari Kakul Husain Ismail Hassan Kutty K.M.Lokanatha Rai 《Molecules (Basel, Switzerland)》2021,26(2)
A novel synthesis of thiazolo[2,3-b]quinazolines 4(a–e), pyrido[2′,3′:4,5]thiazolo[2,3-b]quinazolines {5(a–e), 6(a–e), and 7(a–e)}, pyrano[2′,3′:4,5]thiazolo[2,3-b]quinazolines 8(a–e), and benzo[4,5]thiazolo[2,3-b]quinazoloine9(a–e) derivatives starting from 2-(Bis-methylsulfanyl-methylene)-5,5-dimethyl-cyclohexane-1,3-dione 2 as efficient α,α dioxoketen dithioacetal is reported and the synthetic approaches of these types of compounds will provide an innovative molecular framework to the designing of new active heterocyclic compounds. In our study, we also present optimization of the synthetic method along with a biological evaluation of these newly synthesized compounds as antioxidants and antibacterial agents against the bacterial strains, like S. aureus, E. coli, and P. aeruginosa. Among all the evaluated compounds, it was found that some showed significant antioxidant activity at 10 μg/mL while the others exhibited better antibacterial activity at 100 μg/mL. The results of this study showed that compound 6(c) possessed remarkable antibacterial activity, whereas compound 9(c) exhibited the highest efficacy as an antioxidant. The structures of the new synthetic compounds were elucidated by elemental analysis, IR, 1H-NMR, and 13C-NMR. 相似文献
8.
9.
Bearden IG Beavis D Besliu C Blyakhman Y Budick B Bøggild H Chasman C Christensen CH Christiansen P Cibor J Debbe R Enger E Gaardhøje JJ Hagel K Hansen O Holm A Holme AK Ito H Jakobsen E Jipa A Jørdre JI Jundt F Jørgensen CE Karabowicz R Keutgen T Kim EJ Kozik T Larsen TM Lee JH Lee YK Løvhøiden G Majka Z Makeev A McBreen B Mikelsen M Murray M Natowitz J Nielsen BS Norris J Olchanski K Olness J Ouerdane D Płaneta R Rami F Ristea C Röhrich D Samset BH Sandberg D Sanders SJ Sheetz RA Staszel P 《Physical review letters》2002,88(20):202301
We present charged-particle multiplicities as a function of pseudorapidity and collision centrality for the 197Au+197Au reaction at square root[s(NN)] = 200 GeV. For the 5% most central events we obtain dN(ch)/deta/(eta = 0) = 625+/-55 and N(ch)/(-4.7< or =eta < or =4.7) = 4630 +/- 370, i.e., 14% and 21% increases, respectively, relative to square root[s(NN)] = 130 GeV collisions. Charged-particle production per pair of participant nucleons is found to increase from peripheral to central collisions around midrapidity. These results constrain current models of particle production at the highest RHIC energy. 相似文献
10.
Joshua Rokach Yves Girard Yvan Guindon Joseph G. Atkinson Marie Larue Robert N. Young Paul Masson George Holme 《Tetrahedron letters》1980,21(16):1485-1488
The synthesis and biological characteristics of an SRS-like leukotriene are described. 相似文献