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Spectrophotometric Study of Luminol in Dimethyl Sulfoxide–Potassium Hydroxide

The spectrophotometric study of luminol (LH₂) in dimethyl sulfoxide (DMSO), DMSO-water solutions, and alkaline DMSO and DMSO-water solutions has been done, focusing on the effect of the KOH additon on LH₂ absorption and fluorescence properties. The absorption spectra indicate an acid-base equilibrium, and the luminol dianion (L^2–) formation at 3 × 10^–4 – 2.4 × 10^–3 M KOH. The decrease of the fluorescence intensity and the variation of the excitation spectra of LH₂-DMSO-KOH solutions with KOH concentration have been similarly explained. The acid-base process is reversible. The addition of HCl to the solution with 3.0 × 10^–3 M KOH leads to an increase of the fluorescence intensity to its highest value, observed in pure DMSO. The addition of HCl to the LH₂-DMSO solution leads to the decrease of the fluorescence intensity as a result of the LH⁺ ₃ cation formation. In LH₂-DMSO-water, the fluorescence band is shifted from 405 nm to 424 nm and increased in the intensity. In the presence of KOH (in LH₂-DMSO-water-KOH solution) a new band appears, with the maximum at 485 nm and the band at 405 nm decreased. The changes in fluorescence lifetimes also evidence the different chemical species formed.     

Kinetics of the thermal decomposition of bis(trifluoromethyl) peroxydicarbonate,CF3OC(O)OOC(O)OCF3

Thermal decomposition of bis(trifluoromethyl) peroxydicarbonate has been studied. The mechanism of decomposition is a simple bond fission, homogeneous first‐order process when the reaction is carried out in the presence of inert gases such as N₂ or CO. An activation energy of 28.5 kcal mol^?1 was determined for the temperature range of 50–90°C. Decomposition is accelerated by nitric oxide because of a chemical attack on the peroxide forming substances different from those formed with N₂ or CO. An interpretation on the influence of the substituents in different peroxides on the O? O bond is given. © 2002 Wiley Periodicals, Inc. Int J Chem Kinet 35: 15–19, 2003     

On the correspondence between rotational bands in the mass regionsA ≃ 100 andA ≃ 150

A refined technique is presented to project rotational bands observed in the well studiedZ≧60 rare-earth region into the region of stable ground-state deformation atA ～-100 with corresponding neutron numbers ofN ≧60. With this procedure, estimates of properties of so far unknown nuclei in the A～-100 region can be obtained. As an illustration, isotopes aroundN=64 are discussed within this projection method and within the frame-work of the recent quartet model.     

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Diophantine equations between polynomials obeying second order recurrences

Periodica Mathematica Hungarica -     

Fast switching ferroelectric side-chain liquid-crystalline polymer and copolymer

New ferroelectric side-chain liquid-crystalline polymers, a copolymer and a homopolymer, with siloxane backbone and a triaromatic mesogen as the side group have been synthesized. The materials exhibit a chiral smectic C phase over a large temperature range extending to room temperature. They possess high values of spontaneous polarization: 105 nC cm^-2 for the homopolymer and 180 nC cm^-2 for the copolymer. The electro-optic switching time in the chiral smectic C phase is extremely fast (150 μs). In the smectic A phase, an electroclinic effect with switching times less than 100 μs and with field induced tilt angles of 18° is observed.     

Scale functions on $p$-adic Lie groups

Let G be a p-adic Lie group. Then G is a locally compact, totally disconnected group, to which Willis [14] associates its scale function G : G→ℕ. We show that s can be computed on the Lie algebra level. The image of s consists of powers of p. If G is a linear algebraic group over ℚ _p , s(x)=s(h) is determined by the semisimple part h of x∈G. For every finite extension K of ℚ _p , the scale functions of G and H:=G(K) are related by s _H ∣ _G =s _G ^{[ K :ℚ} _p ^]. More generally, we clarify the relations between the scale function of a p-adic Lie group and the scale functions of its closed subgroups and Hausdorff quotients. Received: 20 February 1997; Revised version: 18 May 1998