Ungleichungen für elementare Mittelwerte

Ohne Zusammenfassung     

Metamagnetic phase transition of the antiferromagnetic Heisenberg icosahedron

The observation of hysteresis effects in single molecule magnets like Mn12-acetate has initiated ideas of future applications in storage technology. The appearance of a hysteresis loop in such compounds is an outcome of their magnetic anisotropy. In this Letter we report that magnetic hysteresis occurs in a spin system without any anisotropy, specifically where spins mounted on the vertices of an icosahedron are coupled by antiferromagnetic isotropic nearest-neighbor Heisenberg interaction giving rise to geometric frustration. At T = 0 this system undergoes a first-order metamagnetic phase transition at a critical field Bc between two distinct families of ground state configurations. The metastable phase of the system is characterized by a temperature and field dependent survival probability distribution.     

Efficient implementation of the Lanczos method for magnetic systems

Numerically exact investigations of interacting spin systems provide a major tool for an understanding of their magnetic properties. For medium size systems the approximate Lanczos diagonalization is the most common method. In this article we suggest two improvements: efficient basis coding in subspaces and simple restructuring for openMP parallelization.     

Modulated spin waves and robust quasi-solitons in classical Heisenberg rings

We investigate the dynamical behavior of finite rings of classical spin vectors interacting via nearest-neighbor isotropic exchange in an external magnetic field. Our approach is to utilize the solutions of a continuum version of the discrete spin equations of motion (EOM) which we derive by assuming continuous modulations of spin wave solutions of the EOM for discrete spins. This continuum EOM reduces to the Landau-Lifshitz equation in a particular limiting regime. The usefulness of the continuum EOM is demonstrated by the fact that the time-evolved numerical solutions of the discrete spin EOM closely track the corresponding time-evolved solutions of the continuum equation. It is of special interest that our continuum EOM possesses soliton solutions, and we find that these characteristics are also exhibited by the corresponding solutions of the discrete EOM. The robustness of solitons is demonstrated by considering cases where initial states are truncated versions of soliton states and by numerical simulations of the discrete EOM equations when the spins are coupled to a heat bath at finite temperatures.     

Zur reaktion von organophosphinen mit chalkogenen und ithalogenen: Rasche übertragung von tellur und jod zwischen phosphinen

Nucleophilic attack of tertiary phosphines at tellurium in R₃PTe and at iodine in R₃PI⁺ is indicated by rapid Te (or I⁺) transfer reactions in the systems R₃PTe PR₃ and R₃PI⁺/PR₃ (R = (CH₃)₃C, (CH₃)₂N). Linear intermediates of the type R₃PYPR3 (Y = Te, I⁺) are proposed.     

Graphs having circuits with at least two chords

All 2-connected non-bipartite graphs are characterized which have a minimal valency ≥3 and which have no odd circuit with two or more chords. From this it is derived that in each graph with chromatic number ≥4 containing no complete 4-graph there is an odd circuit with two or more chords. This result was conjectured by P. Erdös. Corresponding results for even circuits and for circuits with a fixed edge are obtained. Some related problems of the Turán type are solved.     

On the foundations of the physical probability concept

An exact formulation of the frequency interpretation of probability is proposed on the basis of G. Ludwig's concept of physical theories. Starting from a short outline of this concept, a formal definition of weak approximate reduction is developed, which covers the reduction of probability to frequency as a special case.