Efficient One-Pot Synthesis of β-Unsaturated Isoxazol-5-ones and Pyrazol-5-ones Under Ultrasonic Irradiation

4-Arylmethylidene-3-isopropylisoxazol-5-ones and 4-arylmethylidene-1-phenyl-3-isopropylpyrazol-5-ones have been prepared from the reactions of hydroxylamine and phenylhydrazine with methyl 4-methyl-3-oxovalerate and aromatic aldehydes in an aqueous medium at room temperature in the presence of pyridine under ultrasonic irradiation. The simple and facile method produced products in good yields.

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4-芳亚甲基-4,5-二氢-1,3-二苯基吡唑-5-酮的一锅法合成

报道了以乙酸为催化剂,由苯甲酰乙酸乙酯、苯肼和芳香醛经三组分一锅法缩合制备4-芳亚甲基-4,5-二氢-1,3-二苯基吡唑-5-酮衍生物的新方法.该方法缩短了反应时间,得到了中等产率.产物结构经MS,1HNMR,IR和元素分析确证.     

The convenient synthesis of 4-arylmethylidene-4,5-dihydro-3-phenylisoxazol-5-ones

4-Arylmethylidene-4,5-dihydro-3-phenylisoxazol-5-ones were synthesized by the convenient three-component reaction of ethyl benzoylacetate,hydroxylamine and aromatic aldehydes in the presence of pyridine.The target compounds were also obtained by the reaction between 3-phenylisoxazol-5-one and aromatic aldehydes at 105℃under solvent free condition.Yields of products depended considerably on the aldehyde used.     

型钢混凝土柱的非线性推覆分析原理

以建立型钢混凝土柱简便、廉价、准确及易于使用的理论分析工具为目的,将非线性推覆分析方法运用到型钢混凝土柱的非线性分析,首先建立了型钢混凝土柱的非线性推覆分析模型和材料本构关系,然后利用此模型和本构关系编制了非线性推覆分析程序,最后使用本程序对已有试验数据的型钢混凝土柱进行计算,通过试验结果和理论计算结果的比较验证了程序的可靠性,结果表明：非线性推覆分析方法用于型钢混凝土柱的理论分析其概念明确、原理简单、容易实现、结果准确、耗时少、计算费用低,可以用于实用的目的．     

非对称截面型钢混凝土柱承载能力的研究

通过已有的试验数据验证了非线性推覆分析方法用于分析型钢混凝土柱的可靠性,用此方法确定了非对称截面型钢混凝土柱的分析模型,分析了当型钢混凝土柱的长度和荷载作用位置等参数变化时,随着型钢偏心距的不同型钢混凝土柱受力性能的变化情况,通过大量的计算找出了型钢偏心对整柱承载力影响的变化规律．