Indium-mediated Facile Synthesis of （6-Chloropyridine-3-yl）methyl Heterocyclic Thioether Derivatives in Aqueous Media

A series of substituted (6-chloropyridine-3-yl)methyl heterocyclic thioether derivatives were prepared by indium mediating in water. The preliminary biological tests showed that compound 3d exhibited good antiviral activity.     

A THEORETICAL APPROACH TO P_(co_2) EVOLUTION IN THE ATMOSPHERE BASED ON ASSOCIATIONS OF SEDIMENTARY MINERALS

Based on the theory of pH evolution of sea water and the balance between the seawater and the atmosphere the authors discussed the problems about (i) the method ofcalculating P_(CO_2) in the ancient atmosphere with the associations of sedimentary miner-als; (ii) the evolution of P_(CO_2) values in the geologic history; (iii) the relations of thepH evolution of sea water with carbonate precipitations; and (iv) calculation of the pHlimit for some associations of sedimentary minerals and its corresponding P_(CO_2) valuesin the atmosphere. The authors pointed out that though carbonates had deposited little in the Archaean,the content of CO_2 gas in the Archaean atmosphere was very high and was gradually go-ing up to form a thick CO_2 atmosphere. Up to 2600 Ma ago, the P_(CO_2) had reached a gradeof 10- 50 atm. There was a general trend of evolution that from the early Proterozoicera to the present the depositional horizon of carbonate layers was gradually risingand finally surpassed the horizons of clay min     

Theoretical investigation of the Gamow-Teller transition across N=40 shell

The Gamow-Teller transitions for pf shell nuclei with proton number less than 40 and neutron number larger than 40 were believed to be blocked, due to the full filling of the neutron orbit. However, recent experimental research shows that the Gamow-Teller transitions for these kinds of nuclei are not blocked. In this paper, we systematically calculate the GT transition of pf shell nuclei ⁷⁶Se in different truncations, and the results are compared with experimental results. It is shown that, due to correlations, the believed blocked GT transition occurs, and the shell model calculations reproduce the experimental GT strength. In addition, the electron capture rates in a stellar environment are calculated and discussed.     

Synthesis and fluorescence properties of dysprosium‐coordinated with high‐Tg polyaryletherketones containing carboxyl side groups

A series of novel dysprosium coordination polymers were synthesized using new high‐T_g carboxyl‐containing polyaryletherketones (PEKs) as macromolecular ligands and a small molecule, 1,10‐phenanthroline, as co‐ligand. The FTIR, WAXD, and UV–Vis results indicated that the dysprosium ions were coordinated simultaneously with carboxyl group of PEKs and 1,10‐phenanthroline, and homogeneously distributed along the polymer backbone. These obtained dysprosium coordination polymers showed excellent film‐formation properties. Moreover, all the dysprosium coordination polymers could exhibit the intense characteristic emission of dysprosium ions under UV excitation. Meanwhile, the emission intensity increased with increasing dysprosium ion content, and no obvious fluorescence quenching happened at the Dy³⁺ ion content up to 10.71 wt%, which was attributed to the very rigid structure of PEK and synergistic coordination effect of PEK and 1,10‐phenanthroline. Copyright © 2009 John Wiley & Sons, Ltd.     

EXPERIMENTAL ANALYSIS OF ACTIVE STEERING HARDWARE-IN-LOOP BASED ON SLIDING MODE CONTROL 1)

为了提高重型车辆在转向过程中的稳定性和安全性,本文提出了一种基于滑模变结构控制的主动前轮转向控制策略,基于这种策略设计了主动转向控制器,建立了三轴商用车的二自由度车辆动力学简化模型及整车模型,利用TruckSim--Simulink建立联合仿真平台以及进行硬件在环实验。在不同工况、不同车速下,分别对有无主动转向控制器的车辆进行了操纵稳定性分析,并在此基础上进行了滑模变结构控制的主动转向影响因素敏感性分析。实验结果表明,这种控制器策略在不同工况下具有较强的适应性。     

THE CHEMICAL COMPOSITIONS OF MINERALS IN QINGZHEN METEORITE AND ITS GEOCHEMISTRY SIGNIFICANCE

The chemical compositions of silicate minerals, sulphide minerals and metal Fe-Ni in theQingzhen meteorite were measured by the microprobe analyses. Based upon these chemicalcompositions, the cosmochemical behaviour and characteristics of the existing forms of themajor elements in the Qinzhen meteorite have been discussed. These characteristics show thatunder the S-rich, O-poor, and strongly reducing conditions, the light metal elements, such asCa, Mg, K, Na may form sulphide, and metal Fe-Ni may contain Si and P. However, we con-sider that the light metal-sulphide can be stable in the lower mantle and there are some Siand P in the Fe-Ni core. Finally, an earth core-mantle model is established, where the Fe-Ni core contains some Si and P; the lower mantle is composed of Mg-rich silicate, SiO_2 andsulphide; the upper mantle, of silicate and oxide.     

COMPLETENESS FOR H_q~p(D) SPACE

Abstract Let D be arbitrary simply connected domain with at least two boundary points.We have introduced a kind of analytic functions' space H_■~V (D) (p≥1, q>0)and shown that it is a complete linear space with respect to the norm ■·||_(H_q~p(D)).     

电子探针自动连续分析硅酸盐中存在问题的研究

目前,电子探针已成为分析硅酸盐样品的一种重要仪器,新型仪器都可以自动连续分析,大大提高了工作效率,可是定量分析的准确度往往不太高,尤其SiO_2经常偏低。我们以剖析SiO_2分析存在问题出发,讨论了造成误差较大的原因并提出克服的方法     

Eigenvalue approximation from below using non-conforming finite elements

This is a survey article about using non-conforming finite elements in solving eigenvalue problems of elliptic operators,with emphasis on obtaining lower bounds. In addition,this article also contains some new materials for eigenvalue approximations of the Laplace operator,which include:1) the proof of the fact that the non-conforming Crouzeix-Raviart element approximates eigenvalues associated with smooth eigenfunctions from below;2) the proof of the fact that the non-conforming EQ rot1 element approximates eigenvalues from below on polygonal domains that can be decomposed into rectangular elements;3) the explanation of the phenomena that numerical eigenvalues λ 1,h and λ 3,h of the non-conforming Q rot1 element approximate the true eigenvalues from below for the L-shaped domain. Finally,we list several unsolved problems.