Textural analysis of extruded materials with rhombohedral structure

A textural analysis of extruded rods of material with tetradymite (Bi₂Te₃) structure is conducted by constructing the distribution of the pole density of the (0001) and (1120) planes. The distribution of the poles of the planes is represented by a solid of revolution, and the pole density, which is a function of the angle () of the deviation of the normals to h_i from the extrusion axis, is determined by the diffraction method of specimen inclination using the diffracted ray intensity. It proves possible to identify textural components, and to determine how many there are and the degree of perfection of this method. A technique is worked out for the quantitative estimate of the average values of the components of the conductivity tensor in the grains, and the contribution of the texture to the macroscopic properties of the material is analyzed. To investigate the thin layers (for example, the layerwise distribution of texture in rods of rectangular cross section) we used the method of inverse pole diagrams, where the probability of coincidence of the h_i plane with the working surface of the specimen is analyzed.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 12, pp. 33–39, December, 1989.     

Decomposition of ammonia on rhenium III. Interaction of ammonia with rhenium

The adsorption and steady-state decomposition of ammonia on rhenium has been studied. A mechanism for the interaction of ammonia with the Re surface is suggested.

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Chlorine Evolution on Highly Porous Metal Oxide Anodes and the Origin of the Low-Polarizability Portion in Polarization Curves at Large Currents

Experimental and theoretical data on the chlorine evolution in the region of large anodic currents, where a low-polarizability portion emerges in polarization curves, are exhaustively analyzed. It is shown that this practically horizontal portion must emerge upon reaching an overvoltage at which practically all macropores, rather than only the largest of them, are filled with gas. The dramatic increase in the current, observed in this case, is connected with the chlorine evolution reaction penetrating through the entire depth of the coating and results from the formation of a unified system of gas channels in the porous space of the coating. Chlorine evolved in micropores moves via these channels at a high speed to the front side of the electrode, moving away from it in the form of gas bubbles.     

Chemisorption and dissociation of carbon monoxide on rhodium surfaces

The adsorption, desorption and decomposition of CO on Rh surfaces have been investigated using field emission microscopy and thermal desorption spectroscopy. Thermal dissociation of CO cannot be detected on clean Rh surfaces at pressures up to 10^?1 Torr and temperatures below 1000 K. This holds also for atomically rough surfaces like (210). CO dissociation can be promoted under the influence of an electron beam directed to the surface, a high electric field in the presence of CO in the gas phase and by means of discharge techniques. The growth of crystallites formed by CO dissociation and the diffusion of carbon into the bulk has been followed as a function of temperature and surface structure. The tip regions around (110) are very active in these processes. Carbon crystallites on these surfaces disappear around 1000 K by diffusion into the lattice whereas crystallites present around (311) surfaces persist up to 1150 K. The results are discussed in relation to the activity of Rh in CO/H₂ reactions.     

Phase Behavior of Methane-Pentane Mixture in Bulk and in Porous Media

The adiabatic calorimetry method is used to measure the isochoric heat capacity and the dew-bubble curves for the methane-normal pentane mixtures in bulk for three different mixture compositions of n-pentane. The near-critical behavior of the mixture heat capacity indicates that at low n-pentane concentrations, this system is close to the special point of the critical locus. The effect of porous medium has been investigated for one of the mixtures studied in bulk. It has been shown that in porous medium the essential shift of the dew-bubble curve takes place. In our opinion this shift is caused by the formation of wetting film on the surface of porous medium. The estimation of film thickness resulting from the data obtained yields the value 7–8 nm.     

Transformations of hydrocarbon radicals moving along a stainless steel tube

Transport of exhausted thermonuclear fuel in the ITER divertor and pumping duct was modeled on a specially designed dc glow discharge setup using mass spectrometry, optical and electron microscopy, and electron probe microanalysis. Transport and deposition of hydrocarbon radicals transferred in an H₂/C _x H _yx mixture through a hollow stainless steel anode at a total mixture pressure of 8–212 Pa and a methane content to 15 mol % were considered. It was shown that deposition of radicals and ions (CH₃, C₂H₃, C₂H₅) with kinetic energies of 0.03–3 eV on the anode inner surface at 600 K was suppressed to a large extent. In the temperature range of 600–800 K, deposition of ions and radicals with kinetic energy of ~3 eV was partially restored with the formation of soft a-C:H films, while thermalized radicals were not condensed.