全文获取类型
收费全文 | 830篇 |
免费 | 22篇 |
国内免费 | 1篇 |
专业分类
化学 | 494篇 |
晶体学 | 20篇 |
力学 | 23篇 |
数学 | 67篇 |
物理学 | 249篇 |
出版年
2023年 | 6篇 |
2022年 | 8篇 |
2021年 | 11篇 |
2020年 | 19篇 |
2019年 | 11篇 |
2018年 | 8篇 |
2017年 | 11篇 |
2016年 | 24篇 |
2015年 | 20篇 |
2014年 | 20篇 |
2013年 | 61篇 |
2012年 | 59篇 |
2011年 | 46篇 |
2010年 | 22篇 |
2009年 | 23篇 |
2008年 | 44篇 |
2007年 | 28篇 |
2006年 | 49篇 |
2005年 | 38篇 |
2004年 | 30篇 |
2003年 | 28篇 |
2002年 | 21篇 |
2001年 | 6篇 |
2000年 | 8篇 |
1996年 | 6篇 |
1995年 | 8篇 |
1994年 | 4篇 |
1993年 | 10篇 |
1992年 | 6篇 |
1991年 | 7篇 |
1990年 | 4篇 |
1989年 | 10篇 |
1988年 | 5篇 |
1987年 | 11篇 |
1986年 | 9篇 |
1985年 | 16篇 |
1984年 | 16篇 |
1983年 | 14篇 |
1982年 | 6篇 |
1981年 | 13篇 |
1980年 | 15篇 |
1979年 | 9篇 |
1978年 | 11篇 |
1977年 | 6篇 |
1976年 | 11篇 |
1975年 | 8篇 |
1974年 | 7篇 |
1973年 | 5篇 |
1958年 | 4篇 |
1957年 | 4篇 |
排序方式: 共有853条查询结果,搜索用时 46 毫秒
1.
Subodh R Shenoy 《Pramana》2002,58(2):385-397
We obtain the dynamics in number and phase difference, for Bose condensates that tunnel between two wells of a double-well
atomic trap, using the (nonlinear) Gross-Pitaevskii equation. The dynamical equations are of the canonical form for the two
conjugate variables, and the Hamiltonian corresponds to that of a momentum-shortened pendulum, supporting a richer set of tunneling oscillation modes than for a superconductor Josephson junction, that has a
fixed-length pendulum as a mechanical model. Novel modes include ‘inverted pendulum’ oscillations with an average angle of
π; and oscillations about a self-maintained population imbalance that we term ‘macroscopic quantum self-trapping’. Other systems
with this phase-number nonlinear dynamics include two-component (interconverting) condensates in a single harmonic trap, and
He3B superfluids in two containers connected by micropores. 相似文献
2.
G. K. Shenoy 《Hyperfine Interactions》2006,170(1-3):5-13
Stanley L. Ruby (1924–2004) made major contributions to Mössbauer spectroscopy and was the first to suggest the feasibility of observing the Mössbauer effect using synchrotron radiation. In this article we recall his scientific legacy that have inspired his scientific colleagues. 相似文献
3.
K. Vinay Kumar Reddy B. Sreenivasa Reddy M. Sreenath Reddy Ch. Gopal Reddy P. Yadagiri Reddy K. Rama Reddy 《Radiation measurements》2003,36(1-6):419-423
Studies conducted by Atomic Minerals Directorate of Exploration and Research (AMD) of Hyderabad, India had established the presence of higher concentrations of uranium in Lambapur and Peddagattu areas of Nalgonda district, AP, India and it was estimated that it could be a viable source for commercial extraction. The envisaged extraction process involves dispersion of radioactive particulate matter into atmosphere. Environmental radioactive studies in and around proposed mining areas at this point of time will be extremely useful for establishing base line data before a large scale uranium extraction process comes into existence. To this end, Solid State Nuclear Track Detectors were installed to evaluate indoor radon and thoron concentration levels in the dwellings of the area. The geometric means of radon and thoron concentration levels were found to be (7.1±0.2)×101 and (6.7±0.3)×101 Bq/m3, respectively. Simultaneously, natural background radiation measurements were also made and these levels are found to vary from 770 to 3995 μGy/y in the spatial distribution. 相似文献
4.
Designing an Immobilized Metal ion Affinity (IMA) chromatographic process on large scale demands a thorough understanding to be developed regarding the adsorption behaviour of proteins on metal loaded IMA (IMA-M(II)) gels and the characteristic adsorption parameters to be evaluated. This research investigation illustrates the significance of these aspects for the proposed fractionation of chicken egg-white proteins on these gels. Consequently, a systematic investigation of the adsorption characteristics of three chicken egg-white proteins viz., ovalbumin, conalbumin and lysozyme on Cu(II) and Ni(II) loaded IMA gels, iminodiacetate (IDA) and tris(2-aminoethyl)amine (TREN), has been undertaken. These gels differ in their selectivity towards the proteins of interest under the identical sets of experimental conditions. While TREN-Ni(II) was selective only for lysozyme, IDA-Cu(II), IDA-Ni(II) and TREN-Cu(II) showed varying affinities for all the three proteins. The equilibrium and kinetic data were analysed using various theoretical models and adsorption parameters were quantified. On the basis of these investigations, various strategies have been proposed for the efficient large-scale fractionation of chicken egg-white proteins on these gels. 相似文献
5.
The Schiff base [1,2-bis(salicylidene amino)phenylene]cobalt(II) complex, chemically bonded to a carbamate-modified silica gel catalyst, has been prepared by a four step procedure. The oxidation of cyclohexane was studied in the presence of this catalyst under relatively mild conditions (150–200 °C, 15–20 atm) using molecular oxygen. The catalyst was found to be very selective for the production of cyclohexanol, with cyclohexanone formed in only a small amount (45:1). This is in contrast to the commercially available processes in which cyclohexanol and cyclohexanone are both formed in appreciable amounts. The t.g.a. analysis shows the catalyst to be stable up to 211 °C and atomic absorption spectroscopy indicated negligible metal loss during 50 h use of the catalyst up to 180 °C. 相似文献
6.
Stols Lucy Kulkarni Gopal Harris Ben G. Donnelly Mark I. 《Applied biochemistry and biotechnology》1997,63(1):153-158
Applied Biochemistry and Biotechnology - The malic enzyme gene ofAscaris suum was cloned into the vector pTRC99a in two forms encoding alternative arnino-termini. The resulting plasmids, pMEAl and... 相似文献
7.
Kalagouda?B.?GudasiEmail author Ramesh?S.?Vadavi Rashmi?V.?Shenoy Manjula?S.?Patil Siddappa?A.?Patil Munirathinam?Nethaji 《Transition Metal Chemistry》2005,30(6):661-668
The synthesis of cobalt(II), nickel(II) and zinc(II) complexes of 2-pyridine-2-yl-3(pyridine-2-carboxylideneamino)-1,2-dihydroquinazolin-4(3H)-one is described. The ligand and metal complexes were characterized by elemental analysis, conductivity measurements, spectral (u.v.–vis., i.r., 1D n.m.r., 2D hetcor and mass) and thermal studies. The cobalt(II) complex crystallizes as pink crystals in the monoclinic crystal system, space group P21/n with a = 10.066(6) Å, b = 15.929(9) Å, c = 12.624(7) Å, α = 90.00(9)°, β = 110.850 (8)°, γ = 90.00, V = 1891.5 (18) Å3 and Z = 4. The geometry around the cobalt atom is distorted trigonal bipyramidal with τ = 0.83 [structural parameter, τ = (β − α)/60; where α and β are the two basal angles in a five coordinate complex]. 相似文献
8.
Ruan C Paulose M Varghese OK Mor GK Grimes CA 《The journal of physical chemistry. B》2005,109(33):15754-15759
Anodization of titanium in a fluorinated dimethyl sulfoxide (DMSO) and ethanol mixture electrolyte is investigated. The prepared anodic film has a highly ordered nanotube-array surface architecture. Using a 20 V anodization potential (vs Pt) nanotube arrays having an inner diameter of 60 nm and 40 nm wall thickness are formed. The overall length of the nanotube arrays is controlled by the duration of the anodization, with nanotubes appearing only after approximately 48 h; a 72 h anodization results in a nanotube array approximately 2.3 mum in length. The photoelectrochemical response of the nanotube-array photoelectrodes is studied using a 1 M KOH solution under both UV and visible (AM 1.5) illumination. Enhanced photocurrent density is observed for samples obtained in the organic electrolyte, with an UV photoconversion efficiency of 10.7%. 相似文献
9.
Krishna Gopal Dongol M. Cristina Melo e Silva Kouki Matsubara Taisuke Matsumoto Shuntaro Mataka Thies Thiemann 《无机化学与普通化学杂志》2003,629(6):945-947
The preparation of two η6‐estra‐1, 3, 5(10), 6‐tetraene tricarbonylchromium complexes 4 and 6 are described. In both cases only one stereoisomer can be isolated, in contrast to other estrane‐tricarbonylchromium complexes, where complexations are non‐stereoselective. X‐ray crystal structural analysis of 4 discloses that only the more sterically hindered β‐facial isomer is formed. It is assumed that the 6, 7‐olefinic moiety exerts a directive influence on the complexation. 相似文献
10.
Fe(3+) ions in alkali lead tetraborate glasses--an electron paramagnetic resonance and optical study
Chakradhar RP Sivaramaiah G Rao JL Gopal NO 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2005,62(1-3):51-57
Glass systems of composition 90R(2)B(4)O(7)+9PbO+1Fe(2)O(3) (R=Li, Na and K) and 90Li(2)B(4)O(7)+(10-x)PbO+xFe(2)O(3) (x=0.5, 1, 3, 4, 5, 7 and 9 mol %) have been investigated by means of electron paramagnetic resonance (EPR) and optical absorption techniques. The EPR spectra exhibit three resonance signals at g approximately 6.0, 4.2 and 2.0. The resonances at g approximately 6.0 and 4.2 are attributed to Fe(3+) ions in rhombic and axial symmetry sites, respectively. The g approximately 2.0 resonance signal is due to two or more Fe(3+) ions coupled together with dipolar interaction. The EPR spectra of 1 mol % of Fe(2)O(3) doped in lithium lead tetraborate glass samples have been studied at different temperatures (123-433 K). The intensity of g approximately 4.2 resonance signal decreases and the intensity of g approximately 2.0 resonance signal increases with the increase of temperature. The line widths are found to be independent of temperature. The EPR spectra exhibit a marked concentration dependence on iron content. A decrease in intensity for the resonance signal at g approximately 4.2 with increase in iron content for more than 4 mol % has been observed in lithium lead tetraborate glass samples and this has been attributed to the formation of Fe(3+) ion clusters in the glass samples. The paramagnetic susceptibility (chi) is calculated from the EPR data at various temperatures and the Curie constant (C) has been evaluated from 1/chi versus T graph. The optical absorption spectrum of Fe(3+) ions in lithium lead tetraborate glasses exhibits three bands characteristic of Fe(3+) ions in an octahedral symmetry. The crystal field parameter D(q) and the Racah interelectronic repulsion parameters B and C have also been evaluated. The value of interelectronic repulsion parameter B (825 cm(-1)) obtained in the present work suggests that the bonding is moderately covalent. 相似文献