Mixed Amidohalotantalates [Ta(NMe2)3X3]– (X = F,Cl)

Russian Journal of Coordination Chemistry - The anionic tantalum complex (ItBuH)[Ta(NMe2)3Cl3] (I) is synthesized by the reaction of [Ta(NMe2)3Cl2]2 with N-heterocyclic carbene ItBu and is isolated...     

Triangular Clusters of Molybdenum Coordinated with Diethylthiocarbamate: Synthesis,Structure and Solution Behavior

Two novel clusters [Mo₃S₄(dtc)₃(μ-dtc)(L)] (where L = (CD₃)₂SO and tetrahydrothiophene, tht) were prepared and structurally characterized. The tht complex and its previously reported congener with L = py were studied by means of temperature-dependent ¹H NMR spectroscopy, indicating order of lability tht ? py.