全文获取类型
收费全文 | 1785篇 |
免费 | 55篇 |
国内免费 | 7篇 |
专业分类
化学 | 1321篇 |
晶体学 | 3篇 |
力学 | 20篇 |
数学 | 276篇 |
物理学 | 227篇 |
出版年
2023年 | 12篇 |
2022年 | 11篇 |
2021年 | 75篇 |
2020年 | 71篇 |
2019年 | 42篇 |
2018年 | 41篇 |
2017年 | 34篇 |
2016年 | 67篇 |
2015年 | 68篇 |
2014年 | 74篇 |
2013年 | 129篇 |
2012年 | 116篇 |
2011年 | 126篇 |
2010年 | 82篇 |
2009年 | 79篇 |
2008年 | 93篇 |
2007年 | 104篇 |
2006年 | 76篇 |
2005年 | 79篇 |
2004年 | 82篇 |
2003年 | 66篇 |
2002年 | 55篇 |
2001年 | 39篇 |
2000年 | 27篇 |
1999年 | 18篇 |
1998年 | 14篇 |
1997年 | 17篇 |
1996年 | 8篇 |
1995年 | 4篇 |
1994年 | 12篇 |
1993年 | 6篇 |
1992年 | 12篇 |
1991年 | 7篇 |
1990年 | 13篇 |
1989年 | 5篇 |
1988年 | 15篇 |
1987年 | 8篇 |
1986年 | 10篇 |
1985年 | 7篇 |
1984年 | 8篇 |
1983年 | 4篇 |
1982年 | 3篇 |
1979年 | 5篇 |
1978年 | 2篇 |
1977年 | 3篇 |
1976年 | 3篇 |
1968年 | 2篇 |
1936年 | 2篇 |
1927年 | 2篇 |
1924年 | 2篇 |
排序方式: 共有1847条查询结果,搜索用时 15 毫秒
1.
2.
Sajewicz Mieczysław Hauck Heinz-E. Drabik Gabriela Namysło Ewa Głód Bronisław Kowalska Teresa 《平面色谱法杂志一现代薄层色谱法》2006,19(4):278-281
JPC – Journal of Planar Chromatography – Modern TLC - We have previously described unexpected two-dimensionality in the thin-layer chromatographic separation of pairs of enantiomers of... 相似文献
3.
Rafael R. del Río Castillo 《Communications in Mathematical Physics》1991,142(2):421-431
In this work we study the behavior of embedded eigenvalues of Sturm-Liouville problems in the half axis under local perturbations. When the derivative of the spectral function is strictly positive, we prove that the embedded eigenvalues either disappear or remain fixed. In this case we show that local perturbations cannot add eigenvalues in the continuous spectrum. If the condition on the spectral function is removed then a local perturbation can add infinitely many eigenvalues. 相似文献
4.
Gabriela Jeronimo Teresa Krick Juan Sabia Martín Sombra 《Foundations of Computational Mathematics》2004,4(1):41-117
We present a bounded probability algorithm for the computation of the
Chowforms of the equidimensional components of an algebraic variety. In particular,
this gives an alternative procedure for the effective equidimensional decomposition
of the variety, since each equidimensional component is characterized by its Chow
form.
The expected complexity of the algorithm is polynomial in the size and the geometric
degree of the input equation system defining the variety. Hence it improves (or
meets in some special cases) the complexity of all previous algorithms for computing Chow forms. In addition to this, we clarify the probability and uniformity aspects,
which constitutes a further contribution of the paper.
The algorithm is based on elimination theory techniques, in line with the geometric
resolution algorithm due to M. Giusti, J. Heintz, L. M. Pardo, and their collaborators.
In fact, ours can be considered as an extension of their algorithm for zero-dimensional
systems to the case of positive-dimensional varieties. The key element for dealing
with positive-dimensional varieties is a new Poisson-type product formula. This
formula allows us to compute the Chow form of an equidimensional variety from a
suitable zero-dimensional fiber.
As an application, we obtain an algorithm to compute a subclass of sparse resultants,
whose complexity is polynomial in the dimension and the volume of the input
set of exponents. As another application, we derive an algorithm for the computation
of the (unique) solution of a generic overdetermined polynomial equation system. 相似文献
5.
6.
7.
Huseyin Bekir Yildiz Jaime Castillo Dmitrii A. Guschin Levent Toppare Wolfgang Schuhmann 《Mikrochimica acta》2007,159(1-2):27-34
An amperometric biosensor for the detection of phenolic compounds was developed based on the immobilization of tyrosinase
within an Os-complex functionalized electrodeposition polymer. Integration of tyrosinase within the redox polymer assures
efficient catechol recycling between the enzyme and the polymer bound redox sites. The non-manual immobilization procedure
improves the reproducibility of fabrication process, greatly reduces the desorption of the enzyme from the immobilization
layer, and, most importantly prevents fast inactivation of the enzyme by its substrate due to fast redox cycling.
A two-layer sensor architecture was developed involving ascorbic acid oxidase entrapped within an electrodeposition polymer
in a second layer on top of the redox polymer/tyrosinase layer. Using this sensor architecture it was possible to eliminate
the current interference arising from direct ascorbate oxidation up to a concentration of 630 μM ascorbic acid. The effects
of the polymer thickness, the enzyme/polymer ratio, and the applied potential were evaluated with respect to optimal sensor
properties. The sensitivity of the optimized sensors for catechol was 6.1 nA μM−1 with a detection limit of 10 nM, and for phenol 0.15 nA μM−1 with a detection limit of 100 nM. 相似文献
8.
The facility layout problem is concerned with finding the most efficient arrangement of a given number of departments with unequal area requirements within a facility. The facility layout problem is a hard problem, and therefore, exact solution methods are only feasible for small or greatly restricted problems. In this paper, we propose a spring-embedding approach that unlike previous approaches results in a model that is convex. Numerical results demonstrating the potential of our model and the efficiency of our solution procedure are presented. 相似文献
9.
We study a degenerate nonlinear variational inequality which can be reduced to a multivalued inclusion by an appropriate change
of the unknown function. We establish existence, uniqueness and regularity results. An application arising in the theory of
water diffusion in porous media is discussed as an example.
相似文献
10.
The purpose of this work was to investigate the effect of several factors (anion type in the copper salt, pH and concentration of the salt solution) on the structure and thermo-oxidative degradation of the polyacrylamidoxime-copper chelates, by using elemental analysis, IR spectroscopy and dynamic thermogravimetry. The chelates containing copper ions as sulphate exhibit a better initial thermal stability than the polyacrylamidoxime fibre presumably due to the crosslinking generated by the intermolecular complexation of the ions; the removal of the sulphate anions takes place concomitantly with the second step of polymeric chain decomposition. The initial thermal decomposition of the chelates formed by copper ions as nitrate begins at lower temperatures as compared to the polyacrylamidoxime fibre, probably by the nitrate anion release, which partly overlaps the initial decomposition of the copper ion-crosslinked polymeric chains. Copper ions as either sulphate or nitrate catalyse the reactions involved in the main step of polyacrylamidoxime fibre decomposition; the higher the copper amount, the stronger the catalytic effect. 相似文献