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1.
M. G. Voronkov É. A. Zelbst A. A. Kashaev Yu. V. Katkevich V. S. Fundamensky Yu. I. Bolgova O. M. Trofimova N. F. Chernov 《Journal of Structural Chemistry》2005,46(6):1114-1117
The crystal and molecular structure of 1-(trimethylsilylmethyl)benzotriazole has been established by X-ray diffraction (XRD) analysis. The coordination polyhedron of the silicon atom in this molecule is a tetrahedron. The bond lengths and angles of the 1-(trimethylsilylmethyl)benzotriazole molecule were compared with those of related crystal structures. 相似文献
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Yu. A. Kondratenko T. A. Kochina V. S. Fundamensky Yu. G. Vlasov 《Russian Journal of General Chemistry》2015,85(12):2710-2714
Triethanolammonium salts (protatranes) of biologically active carboxylic acids (nicotinic, cinnamic, benzoic, salicylic, oxalic, malonic, succinic, malic, citric) were synthesized in yields exceeding 90%. The structure of the synthesized compounds was studied by IR spectroscopy and X-ray diffraction analysis. 相似文献
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Minyan Song S. M. Ramsh V. S. Fundamensky S. Yu. Solov’eva V. I. Zakharov 《Russian Journal of General Chemistry》2012,82(2):236-246
Aminomethylation of thiourea with aqueous formaldehyde and simple amino acids (glycine, β-alanine, γ-aminobutyric acid) have
resulted in the formation of (4-thioxo-1,3,5-triazinan-1-yl)-substituted acetic, propionic, and butyric acids, respectively.
By alkylation of these compounds corresponding S-methyl and S-ethyl iodides were obtained, and by the action of tert-butylamine, the corresponding salts. The same salts were obtained by the reaction of amine exchange between 5-tert-butyl-1,3,5-triazinan-2-thione and these amino acids in water. As a result of neutralization of S-methyl iodides with tert-butylamine in 2-propanol or aqueous 2-propanol zwitterionic [4-(methyl-sulfanyl)-3,6-dihydro-1,3,5-triazin-1(2H)-yl] derivatives of these acids were isolated. From aqueous solutions of S-methyl iodides and tert-butylamine ion associates of the corresponding zwitter-ions and tert-butylammonium iodide have crystallized. The same associates have formed at treating S-methyl iodides with tert-butylamine or diethylamine in the absence of a solvent. 相似文献
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M. G. Voronkov È. A. Zel’bst V. S. Fundamensky V. V. Gurzhiy Yu. I. Bolgova O. M. Trofimova 《Journal of Structural Chemistry》2014,55(2):370-373
By single crystal X-ray diffraction the crystal and molecular structure of 1-(3-ammoniopropyl)silatrane chloride (I) is determined. One of three cations in the asymmetric unit of the crystal of I differs from the other two by the length of the coordination N → Si bond. The opposite electronic effects in two geometrically similar cations are transferred inductively through a three-carbon chain. 相似文献
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Mammeri O. A. Hamoud F. Sobina A. A. Ramsh S. M. Fundamensky V. S. Gurzhiy V. V. Khrabrova E. S. 《Russian Journal of General Chemistry》2020,90(11):2043-2047
Russian Journal of General Chemistry - Condensation of 1,3-dialkylthiourea, formaldehyde, and terminal amino acids (C2, C3, or C4) taken in the 1 : 2 : 1 molar ratio has afforded the terminally... 相似文献
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M. G. Voronkov É. A. Zelbst V. S. Fundamensky Yu. V. Katkevich Yu. I. Bolgova O. M. Trofimova N. F. Chernov 《Journal of Structural Chemistry》2005,46(6):1122-1125
The crystal and molecular structure of N-(1-silatranylmethyl)benzimidazole was established by X-ray diffraction. The coordination polyhedron of the silicon atom in this molecule is a trigonal bipyramid. The bond lengths and angles of the N-(1-silatranylmethyl)benzimidazole (SMBI) molecule are compared with the corresponding values for other derivatives of this heterocycle. The silatranylmethyl group, having a high electron-donor inductive effect, does not increase the total aromaticity of the SMBI molecule. 相似文献
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Kondratenko Yu. A. Borisova A. A. Ugolkov V. L. Fundamensky V. S. Kochina T. A. 《Russian Journal of General Chemistry》2019,89(4):722-726
Russian Journal of General Chemistry - The reaction of tris(2-hydroxyethyl)amine with Fe(III) and Mn(II) carboxylates was studied for the first time. The complexes formation was confirmed by the IR... 相似文献
9.
Crystallography Reports - The crystal structure of new oxide PtLa6(La9Sr3)(Pt0.9Сu0.1)4O42 is a three-dimensional framework, formed by chains of regular octahedra Pt1 and nine-vertex... 相似文献
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Three Co(II) complexes of triethanolamine (TEA) namely [Co(N(CH2CH2OH)3)2](NO3)2 (1), [Co(N(CH2CH2OH)3)2](OOC(CH2)2COO) (2) and [Co2(N(CH2CH2OH)3)2(NO3)2(OOC(CH2)2COO)] (3) were synthesized and characterized by physicochemical and spectroscopic methods. The first two complexes are cationic and are formed by Co2+ cations coordinated by two TEA ligands plus nitrate or succinate anions, respectively. The equilibrium geometries of the [Co(TEA)2]2+ cations have been optimized at the B3LYP/cc-pVDZ level. Complex 3 is a product of the reaction between cationic complexes 1 and 2. 相似文献