Tetrachloroferrate(III)-selective liquid membrane electrode based on crystal violet

An extract of crystal violet-tetrachloroferrate(III) in nitrobenzene was used to prepare a tetrachloroferrate(III)-selective liquid membrane electrode with a poly(vinyl chloride) support. The optimal conditions to determine 2.5 × 10^–5 – 5.0 × 10^–2 M iron(III) as tetrachloroferrate(III) (anionic slope 56 mV/decade, detection limit 7.9 × 10^–6 M) were found to be 4.0–5.5.M total chloride in 0.75–1.5M hydrochloric acid. The electrode was reliably applied to determine iron in human blood, haematite and mineralized vitamin syrup by direct potentiometry, standard and sample additions as well as standard subtraction techniques.     

On the Möbius Function of a Pointed Graded Lattice

In this paper, we compute the Möbius function of pointed integer partition and pointed ordered set partition using topological and analytic methods. We show that the associated order complex is a wedge of spheres and compute the associated reduced homology group for each subposet. In addition, we compute the Möbius function of pointed graded lattice and use our method to compute the Möbius function of pointed direct sum decomposition of vector spaces.