全文获取类型
收费全文 | 871篇 |
免费 | 29篇 |
国内免费 | 4篇 |
专业分类
化学 | 575篇 |
晶体学 | 14篇 |
力学 | 18篇 |
数学 | 127篇 |
物理学 | 170篇 |
出版年
2024年 | 2篇 |
2023年 | 5篇 |
2022年 | 13篇 |
2021年 | 30篇 |
2020年 | 32篇 |
2019年 | 39篇 |
2018年 | 28篇 |
2017年 | 35篇 |
2016年 | 54篇 |
2015年 | 27篇 |
2014年 | 41篇 |
2013年 | 82篇 |
2012年 | 64篇 |
2011年 | 69篇 |
2010年 | 62篇 |
2009年 | 49篇 |
2008年 | 37篇 |
2007年 | 52篇 |
2006年 | 34篇 |
2005年 | 18篇 |
2004年 | 25篇 |
2003年 | 11篇 |
2002年 | 20篇 |
2001年 | 12篇 |
2000年 | 10篇 |
1999年 | 7篇 |
1998年 | 5篇 |
1997年 | 10篇 |
1996年 | 1篇 |
1995年 | 4篇 |
1994年 | 2篇 |
1993年 | 3篇 |
1992年 | 1篇 |
1991年 | 3篇 |
1990年 | 4篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1982年 | 1篇 |
1980年 | 1篇 |
1979年 | 3篇 |
1975年 | 1篇 |
1969年 | 1篇 |
1966年 | 1篇 |
排序方式: 共有904条查询结果,搜索用时 15 毫秒
1.
2.
D. N. Emel’yanov N. V. Volkova O. I. Sheronova Z. G. Chernorukova 《Russian Journal of Applied Chemistry》2006,79(8):1354-1359
The process of preservation of newspaper with aqueous solutions and dispersions of acrylic copolymers is considered from the instant of impregnation till removal of the polymeric preservative from paper. 相似文献
3.
E. G. Emel’yanov 《Journal of Mathematical Sciences》2007,143(3):3077-3089
The paper considers the problem on extremal decomposition of a multiply connected domain G ⊂ ℂ in the case where the associated
quadratic differential is a perfect square. It is shown that in the case considered, the value of the functional for this
extremal decomposition is the least one in a certain class of decompositions. Bibliography: 10 titles.
Dedicated to the 100th anniversary of G. M. Goluzin’s birthday
__________
Translated from Zapiski Nauchnykh Seminarov POMI, Vol. 337, 2006, pp. 113–133. 相似文献
4.
5.
A cooperative defect-deformation (DD) mechanism is developed for the nucleation of the quasi-monodisperse ensemble of nanoparticles in the low-temperature deposition of Ga atoms in the presence of laser radiation. A comparison with experiment is carried out, and a good agreement between the theoretical and experimental results has been obtained. In particular, in accordance with the DD model, it has been found that the arrangement of nanoparticles is characterized by a latent hexagonal order, and their shape is quasi-hexagonal. It has been shown that the characteristics of the deposited ensemble of nanoparticles can be controlled with the use of an anisotropic deformation. 相似文献
6.
E. E. Baranov A. M. Emel’yanov W. V. Lundin V. N. Petrov V. I. Sakharov I. T. Serenkov N. A. Sobolev A. N. Titkov E. I. Shek N. M. Shmidt 《Technical Physics》2006,51(12):1600-1603
The evolution of the structure organization of MOCVD-grown AlGaN/GaN superlattices subjected to erbium ion implantation with an energy of 1 MeV and dose of 3 × 1015 cm?2 and subsequent annealing is correlated with their photoluminescent properties. The structure organization is quantitatively estimated using parameter Δ (degree of violation of local symmetry), which is found via multifractal analysis of surface morphology patterns obtained with atomic force microscopy. It is shown that the implantation not only causes Ga segregation on the surface, but also changes the structure organization, which shows up in the finer grain structure compared with the starting one and disordering, as well as in an increase in Δ. As the annealing temperature rises from 700 to 800°C, Δ declines, indicating that the structure organization is improved, and the intensity of the dominating photoluminescence peak due to Er3+ ions (1.542 μm) grows. With a further increase in the annealing temperature to 1050°C, the structure organization degrades, domains get larger, voids 100–200 nm deep form, and the photoluminescence intensity drops. The formation of voids during high-temperature annealing is also substantiated by data for 230-keV proton scattering. It is thus established that the improvement of the superlattice structure organization activates erbium and causes the erbium-ion-related luminescence intensity to grow. 相似文献
7.
I. I. Bardyshev A. D. Mokrushin A. A. Pribylov E. N. Samarov V. M. Masalov I. A. Karpov G. A. Emel’chenko 《Colloid Journal》2006,68(1):20-25
Some adsorption, structural, and annihilation characteristics of synthetic opals are measured. An analysis of these characteristics makes it possible to conclude that the total porosity in opals comprises macropores, which are in essence the voids between structure-forming spheres, and nanopores connected to the substructure of the spheres. The systems of macropores and nanopores are separated by narrow channels that collapse upon the thermal treatment of opals. The sizes of primary a-SiO2 particles and nanopores, which correspond to the voids between these particles, are estimated. 相似文献
8.
Fatma M. Abdel-Gawad Yousry M. Issa Hussein M. Fahmy Hanan M. Hussein 《Mikrochimica acta》1998,130(1-2):35-40
Three simple, quick and sensitive spectrophotometric methods are described for the determination of ciprofloxacin. The methods are based on the reaction of this drug as ann-electron donor with 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ), 7,7,8,8,-tetracyanoquinodimethane (TCNQ) andp-chloranil (CL) as -acceptors to give highly coloured complex species. The coloured products are quantitated spectrophotometrically at 460, 843 and 550 nm for DDQ, TCNQ and CL, respectively. Optimization of the different experimental conditions is described. Beer's law is obeyed in the concentration ranges 5–50, 1.5–15 and 20–200 g ml–1 ciprofloxacin, but the concentration ranges for best accuracy are 10–48, 2.5–15 and 35– 195 g ml–1 of drug for DDQ, TCNQ and CL, respectively. The relative standard deviations are less than 1.5%. Applications of the suggested methods to ciprofloxacin tablets are presented and compared with the USP method. The stability constants of the 11 DDQ and CL complexes were 1.086 × 104 and 2.581 × 104 lmol–1, respectively, whereas for the 12 TCNQ complex it was 3.62 × 1081. mol–1. 相似文献
9.
S. A. Gromilov T. V. Basova D. Yu. Emel’yanov A. V. Kuzmin S. A. Prokhorova 《Journal of Structural Chemistry》2004,45(3):471-475
Layers of [(CH3)3SiO]8(SiO1.5)8 and [(CH3)3SiO]12(SiO)6 organosilicon compounds obtained by chemical vapor deposition were investigated by X-ray diffraction (DRON-RM4, R = 192 mm, CuK
radiation) and Raman spectroscopy (Triplemate, SPEX). The layers were found to be ideally oriented polycrystalline films. The octakis-(trimethylsiloxy)octasilsesquioxane polycrystals are oriented in one crystallographic direction — [001], while the dodecakis-(trimethylsiloxy)cyclohexa-siloxane polycrystals are oriented in the
and
directions. Crystal structure analysis in these directions yielded the type of the planar lattice followed by the molecules and their orientation relative to the support.Original Russian Text Copyright © 2004 by S. A. Gromilov, T. V. Basova, D. Yu. Emelyanov, A. V. Kuzmin, and S. A. ProkhorovaTranslated from Zhurnal Strukturnoi Khimii, Vol. 45, No. 3, pp. 497–501, May–June 2004. 相似文献
10.
Mustafa Odabaolu idem Albayrak Reit
zkanca Fatma Zehra Aykan Peter Lonecke 《Journal of Molecular Structure》2007,840(1-3):71-89
Some new substituted polyhydroxy azo–azomethine compounds were prepared by reaction of tris(hydroxymethyl)aminomethane with (E)-2-hydroxy-5-(phenyldiazenyl) benzaldehyde and its substituted derivatives. The structures of azo and azo–azomethine compounds were determined by IR, UV–vis, 1H NMR and 13C NMR spectroscopic techniques, and/or X-ray diffraction studies. According to IR spectra, all azo–azomethine compounds adopt keto form in solid state. UV–vis analysis has shown the presence of keto–enol tautomerism in solution for all azo–azomethine compounds, except that for nitro substituted derivative, enol form is dominantly favored in solution. At the same time, above mentioned derivative compounds were studied in vitro for their antimicrobial properties. Among the phenylazosalicylaldehyde series compound tested, 4-phenylazosalicylaldehyde, 4-(3-chlorophenylazo)salicylaldehyde, 4-(2-chlorophenylazo)salicylaldehyde, 4-(4-fluorophenylazo)salicylaldehyde, 4-(3-chlorophenylazo)salicylaldehyde and 4-(4-ethylphenylazo)salicylaldehyde showed a weak antimicrobial activity only against gram positive bacteria. On the contrary, phenylazosalicylaldehyde series compounds were reacted tris(hydroxmethyl)aminomethane, that exhibited a strong antimicrobial activity against gram positive bacteria, yeast and mould. Moreover, while the 2-{[1,3-dihydroxy-2-(hydroxymethyl)propan-2-ylimino]methyl}phenol did not show an inhibition on tested microorganism, the addition of phenyldiazine groups to 2-{[1,3-dihydroxy-2-(hydroxymethyl)propan-2-ylimino]methyl}phenol resulted in a strong increases in antimicrobial activity. 相似文献