Organic Thin Film Transistors Based on 2,3‐Dimethylpentacene and 2,3‐Dimethyltetracene

2,3‐Dimethylpentacene (DMP) and 2,3‐dimethyltetracene (DMT) were synthesized, characterized and employed as the channel material in the fabrication of thin‐film transistors. The two methyl groups increase the chemical stability of the compounds versus the pristine acene analogues. The crystals maintain herringbone‐like molecular packing, whereas the weak dipole associated with the unsymmetrical molecule induces an anti‐parallel alignment among the neighbors. This structural motif favors layered film growth on SiO₂/Si surface. Thin film transistors prepared on SiO₂/Si and n‐nonyltrichlorosilane‐modified SiO₂/Si at different substrate temperatures were compared. DMP‐based transistors prepared on rubbed n‐nonyltrichlorosilane‐modified SiO₂/Si substrate gave the highest field‐effect mobility of 0.46 cm²/Vs, whereas DMT‐based transistor gave a mobility of 0.028 cm²/Vs.     

Design and synthesis of novel dinucleotide analogs

Syntheses of dinucleotide analogs, (S,R) cis-(4-((4-amino-2-oxopyrimidin-1(2H)-yl)methyl)-1,3-dioxolan-2-yl)methyl (2R,3R,5R)-2-(hydroxymethyl)-5-(5-methyl-2,4-dioxo-3,4-dihydropyrimidin-1(2H)-yl)-tetrahydrofuran-3-yl hydrogen phosphate (5a) and (S,R) cis-(5-((4-amino-2-oxopyrimidin-1(2H)-yl)methyl)-1,3-oxathiolan-2-yl)methyl (2R,3R,5R)-2-(hydroxymethyl)-5-(5-methyl-2,4-dioxo-3,4-dihydropyrimidin-1(2H)-yl)-tetrahydrofuran-3-yl hydrogen phosphate (5b), were accomplished by the use of a new strategy. The use of phenyldichlorophosphate (Method A) as the coupling reagent was shown to possess superiority relative to the reported use of di(1H-benzo[d][1,2,3]triazol-1-yl)phenyl phosphonate (Method B).     

Nonself-similar flow with a shock wave reflected from the center of symmetry and new self-similar solutions with two reflected shocks

In some problems concerning cylindrically and spherically symmetric unsteady ideal (inviscid and nonheat-conducting) gas flows at the axis and center of symmetry (hereafter, at the center of symmetry), the gas density vanishes and the speed of sound becomes infinite starting at some time. This situation occurs in the problem of a shock wave reflecting from the center of symmetry. For an ideal gas with constant heat capacities and their ratio γ (adiabatic exponent), the solution of this problem near the reflection point is self-similar with a self-similarity exponent determined in the course of the solution construction. Assuming that γ on the reflected shock wave decreases, if this decrease exceeds a threshold value, the flow changes substantially. Assuming that the type of the solution remains unchanged for such γ, self-similarity is preserved if a piston starts expanding from the center of symmetry at the reflection time preceded by a finite-intensity reflected shock wave propagating at the speed of sound. To answer some questions arising in this formulation, specifically, to find the solution in the absence of the piston, the evolution of a close-to-self-similar solution calculated by the method of characteristics is traced. The required modification of the method of characteristics and the results obtained with it are described. The numerical results reveal a number of unexpected features. As a result, new self-similar solutions are constructed in which two (rather than one) shock waves reflect from the center of symmetry in the absence of the piston.     

The reflection of a shock wave from a centre or axis of symmetry at adiabatic exponents from 1.2 to 3

The self-similar problem of the reflection of a shock wave from a centre or axis of symmetry for adiabatic exponents from 1.2 to 3 with a maximum step of 0.1 is solved. The distributions of the main parameters behind the reflected shock wave are obtained.     

1-Methyl-2-oxopyrrolidinium perchlorate ionic liquid in synthesis of 5-ethoxycarbonyl-3,4-dihydropyrimidin-2(1H)-ones

Russian Journal of General Chemistry - A multicomponent Biginelli reaction in a solvent-free conditions catalyzed by 1-methyl-2-oxopyrrolidinium perchlorate ionic liquid was studied. The...     

High performance single-crystal field-effect transistors based on twisted polyaromatic semiconductor pyreno[4,5-a]coronene

A novel p-channel semiconductor pyreno[4,5-a]coronene has been synthesized and characterized. The highly fused π-conjugated framework has a twisted geometry with an excellent on-top cofacial π-π stacking in the crystal structure and with a centroid-to-centroid distance of 3.808 ?. Single-crystal field effect transistors based on the molecule exhibit a high mobility of ~0.89 cm(2) V(-1) s(-1) and an on/off ratio of ~6 × 10(4).     

Self-similar time-varying flows of an ideal gas with a change in the adiabatic exponent in a “reflected” shock wave

Self-similar one-dimensional time-varying problems are considered under the assumption that there is a change in the adiabatic exponent in a shock wave (SW) running (“reflected”) from a centre or axis of symmetry (later from a centre of symmetry, CS) or from a plane. The medium is an ideal (inviscid and non-heat-conducting) perfect gas with constant heat capacities. In problems with strong SW, the change in the adiabatic exponent in a gas approximately simulates physicochemical processes such as dissociation and ionization and, in the problem of the collapse of a spherical cavity in a liquid, the conversion of liquid into vapour. In both cases, the adiabatic exponent decreases on passing across a reflected SW. Problems of the collapse of a spherical cavity, the reflection of a strong SW from a centre of symmetry and a simpler problem with a self-similarity index of one are examined. When it is assumed that there is an increase in the adiabatic exponent, the self-similar solutions of the first two problems are rejected due to the decrease in entropy from the instant when the SW is reflected. When it is assumed that there is a decrease in the adiabatic exponent, the solutions of these problems only become unsuitable after a finite time has elapsed for the same reason. Up to this time when the decrease in the adiabatic exponent has not reached a certain threshold, the structure of the self-similar solution does not undergo qualitative changes. When the above-mentioned threshold is exceeded, a self-similar solution is possible if a cylindrical or spherical piston expands according to a special law from the instant of SW reflection from the CS. When there is no piston, the flow behind the reflected wave becomes non-self- similar. In the case of the deceleration of a plane flow, conditions are possible with the joining of SW from different sides to a centred rarefaction wave.